Citation: Mengyuan Cheng, Haiying Wang, Yufeng Liu, Jingwen Shi, Mingqi Zhou, Weixin Du, Dongdi Zhang, Guoping Yang. Bouquet-like uranium-containing selenotungstate consisting of two different Keggin-/Anderson-type units with excellent photoluminescence quantum yield[J]. Chinese Chemical Letters, ;2023, 34(1): 107209. doi: 10.1016/j.cclet.2022.02.015 shu

Bouquet-like uranium-containing selenotungstate consisting of two different Keggin-/Anderson-type units with excellent photoluminescence quantum yield

Mengyuan Cheng ^a ,
Haiying Wang ^a ,
Yufeng Liu ^b ,
Jingwen Shi ^a ,
Mingqi Zhou ^a ,
Weixin Du ^a ,
Dongdi Zhang ^{a, *,} ,
Guoping Yang ^{b, *,}

a.
Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China
b.
Jiangxi Province Key Laboratory of Synthetic Chemistry, Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China University of Technology, Nanchang 330013, China

ddzhang@henu.edu.cn

erick@ecut.edu.cn

Received Date: 11 January 2022
Revised Date: 30 January 2022
Accepted Date: 8 February 2022
Available Online: 11 February 2022

Figures(6)

We present the synthesis, characterization and photoluminescence properties of uranium-containing selenotungstate, [(UO₂)₃(SeO₃)₃Na₅(H₂O)₆(SeW₆O₂₁)(SeW₉O₃₃)₃]^21–, which was isolated by a one-pot reaction of uranium nitrate with sodium tungstate and sodium selenite in a pH 5.2 aqueous solution at 90 ℃. In this study, the effect of the introduction of lone-electron pair containing heteroatoms on the structure is demonstrated, a three-layered heterometallic {Se₃U₃Na₅} cluster is encapsulated by two different anionic building block units: three trivacant Keggin {B-α-SeW₉O₃₃} and one Anderson {SeW₆O₂₁}. To our knowledge, the {Se₃U₃Na₅} cluster has never been observed in the polyoxometalate chemistry. The solid-state photoluminescence properties and lifetime decay behaviours of the title compound (1) have been measured at room temperature, and the photoluminescence spectrum displays the characteristic emission bands of corresponding uranyl cations. In addition, the photoluminescence quantum yield of 1 is 72%, which is almost three times that of starting material UO₂(NO₃)₂·6H₂O (27%). By using this strategy, we envision that an increasing number of assemblies with 'open' clusters may be designed and obtained, in which the exposed oxygen atoms show strong affinity towards metal ions, providing new opportunities to generate bigger clusters or to tune existing properties.
- Polyoxometalates,
- Selenotungstates,
- Uranium,
- Synthesis,
- Photoluminescence
1. [1]
  H. Zhang, W. Liu, A. Li, et al., Angew. Chem. Int. Ed. 58 (2019) 16110–16114. doi: 10.1002/anie.201909718
2. [2]
  N. Kaltsoyannis, Chem. Soc. Rev. 32 (2003) 9–16. doi: 10.1039/b204253n
3. [3]
  O. Renier, C. Falaise, H. Neal, et al., Angew. Chem. Int. Ed. 55 (2016) 13480–13484. doi: 10.1002/anie.201607151
4. [4]
  M.T. Pope, A. Müller, Angew. Chem. Int. Ed. 30 (1991) 34–48. doi: 10.1002/anie.199100341
5. [5]
  D.L. Long, R. Tsunashima, L. Cronin, Angew. Chem. Int. Ed. 49 (2010) 1736–1758. doi: 10.1002/anie.200902483
6. [6]
  S.T. Zheng, G.Y. Yang, Chem. Soc. Rev. 41 (2012) 7623–7646. doi: 10.1039/c2cs35133a
7. [7]
  P. Mialane, C. Mellot-Draznieks, P. Gairola, et al., Chem. Soc. Rev. 50 (2021) 6152–6220. doi: 10.1039/D0CS00323A
8. [8]
  J. Zhang, Y. Huang, G. Li, et al., Coord. Chem. Rev. 378 (2019) 395–414. doi: 10.1016/j.ccr.2017.10.025
9. [9]
  M.T. Pope, A. Muller, Polyoxometalate Chemistry from Topology via Self-assembly to Applications, Kluwer Academic Publishers, New York, 2002.
10. [10]
  M. Cheng, Y. Liu, W. Du, et al., Chin. Chem. Lett. 33 (2022) 3899–3902. doi: 10.1016/j.cclet.2021.11.059
11. [11]
  Y. Gu, Q. Li, D. Zang, et al., Angew. Chem. Int. Ed. 60 (2021) 13310–13316. doi: 10.1002/anie.202011164
12. [12]
  L. Qiao, M. Song, A. Geng, et al., Chin. Chem. Lett. 30 (2019) 1273–1276. doi: 10.1016/j.cclet.2019.01.024
13. [13]
  N. Zhang, L. Hong, A. Geng, et al., Chin. Chem. Lett. 29 (2018) 1409–1412. doi: 10.1016/j.cclet.2017.12.003
14. [14]
  Y. Song, Y. Peng, S. Yao, et al., Chin. Chem. Lett. 33 (2022) 1047–1050. doi: 10.1016/j.cclet.2021.08.045
15. [15]
  V. Das, R. Kaushik, F. Hussain, Coord. Chem. Rev. 413 (2020) 213271. doi: 10.1016/j.ccr.2020.213271
16. [16]
  S. Xie, D. Wang, Z. Wang, et al., Inorg. Chem. Front. 9 (2022) 350–362. doi: 10.1039/D1QI01246K
17. [17]
  Q. Han, Z. Li, X. Liang, et al., Inorg. Chem. 58 (2019) 12534–12537. doi: 10.1021/acs.inorgchem.9b02236
18. [18]
  J. Gao, J. Yan, S. Beeg, et al., J. Am. Chem. Soc. 135 (2013) 1796–1805. doi: 10.1021/ja309237x
19. [19]
  O. Oms, A. Dolbecq, P. Mialane, Chem. Soc. Rev. 41 (2012) 7497–7536. doi: 10.1039/c2cs35148j
20. [20]
  Q. Zheng, M. Kupper, W. Xuan, et al., J. Am. Chem. Soc. 141 (2019) 13479–13486. doi: 10.1021/jacs.9b04533
21. [21]
  J.C. Liu, J.F. Wang, Q. Han, et al., Angew. Chem. Int. Ed. 60 (2021) 11153–11257. doi: 10.1002/anie.202017318
22. [22]
  O. Sadeghi, M. Amiri, E.W. Reinheimer, et al., Angew. Chem. Int. Ed. 57 (2018) 6247–6250. doi: 10.1002/anie.201802915
23. [23]
  K. Wassermann, M.H. Dickman, M.T. Pope, Angew. Chem. Int. Ed. 36 (1997) 1445–1448. doi: 10.1002/anie.199714451
24. [24]
  W. Liu, J.S. Kinyon, B.S. Bassil, et al., Inorg. Chem. 60 (2021) 8267–8275. doi: 10.1021/acs.inorgchem.1c00965
25. [25]
  P.C. Burns, K.A. Kubatko, G. Sigmon, et al., Angew. Chem. Int. Ed. 44 (2005) 2135–2139. doi: 10.1002/anie.200462445
26. [26]
  M. Nyman, P.C. Burns, Chem. Soc. Rev. 41 (2012) 7354–7367. doi: 10.1039/c2cs35136f
27. [27]
  J. Qiu, P.C. Burns, Chem. Rev. 113 (2013) 1097–1120. doi: 10.1021/cr300159x
28. [28]
  P.C. Burns, M. Nyman, Dalton Trans. 47 (2018) 5916–5927. doi: 10.1039/C7DT04245K
29. [29]
  P. Baidala, V.S. Smurova, E.A. Torchenkova, Dokl. Chem. (1971) 202.
30. [30]
  M. Dufaye, S. Duval, T. Loiseau, CrystEngComm 22 (2020) 3549–3562. doi: 10.1039/D0CE00088D
31. [31]
  T. Auvray, E.M. Matson, Dalton Trans. 49 (2020) 13917–13927. doi: 10.1039/D0DT02755C
32. [32]
  T. Deb, L. Zakharov, C. Falaise, M. Nyman, Inorg. Chem. 55 (2016) 755–761. doi: 10.1021/acs.inorgchem.5b02229
33. [33]
  N.P. Martin, E. Petrus, M. Segado, et al., Chem. Eur. J. 25 (2019) 10580–10584. doi: 10.1002/chem.201902770
34. [34]
  K. Li, X.L. Lin, K. Zeng, et al., Tungsten 4 (2022) 149–157. doi: 10.1007/s42864-021-00119-0
35. [35]
  H.Y. Wang, X.Y. Zheng, L.S. Long, et al., Inorg. Chem. 60 (2021) 6790–6795. doi: 10.1021/acs.inorgchem.1c00622
36. [36]
  G.P. Yang, X.L. Zhang, Y.F. Liu, et al., Inorg. Chem. Front. 8 (2021) 4650–4656. doi: 10.1039/D1QI00485A
37. [37]
  S. Duval, S. Sobanska, P. Roussel, T. Loiseau, Dalton Trans. 44 (2015) 19772–19776. doi: 10.1039/C5DT02932E
38. [38]
  M. Mohadeszadeh, J. Cluster Sci. 22 (2011) 183–192. doi: 10.1007/s10876-011-0372-8
39. [39]
  M. Dufaye, S. Duval, G. Stoclet, et al., Inorg. Chem. 58 (2019) 1091–1099. doi: 10.1021/acs.inorgchem.8b02210
40. [40]
  J. Goura, A. Sundar, B.S. Bassil, et al., Inorg. Chem. 59 (2020) 16789–16794. doi: 10.1021/acs.inorgchem.0c02858
41. [41]
  R. Khoshnavazi, H. Eshtiagh-hossieni, M.H. Alizadeh, et al., Polyhedron 25 (2006) 1921–1926. doi: 10.1016/j.poly.2005.12.019
42. [42]
  D. Zhao, Z. Liang, H. Wang, et al., Eur. J. Inorg. Chem. 2019 (2019) 523– 528. doi: 10.1002/ejic.201800556
43. [43]
  D. Zhang, Z. Liang, S. Liu, et al., Inorg. Chem. 56 (2017) 5537–5543. doi: 10.1021/acs.inorgchem.6b02524
44. [44]
  H. Wang, J. Sun, Y. Ma, et al., Dalton Trans. 49 (2020) 4078–4083. doi: 10.1039/C9DT04828F
45. [45]
  Z. Yang, Q. Mu, Z. Liang, et al., Dalton Trans. 48 (2019) 13135–13138. doi: 10.1039/C9DT02860A
46. [46]
  U. Kortz, N.K. Al-Kassem, M.G. Savelieff, et al., Inorg. Chem. 40 (2001) 4742–4749. doi: 10.1021/ic0101477
47. [47]
  J. Yan, D.L. Long, L. Cronin, Angew. Chem. Int. Ed. 49 (2010) 4117–4120. doi: 10.1002/anie.201000076
48. [48]
  J. Yan, J. Gao, D.L. Long, et al., J. Am. Chem. Soc. 132 (2010) 11410–11411. doi: 10.1021/ja104043s
49. [49]
  J.M. Cameron, J. Gao, D.L. Long, et al., Inorg. Chem. Front. 1 (2014) 178–185. doi: 10.1039/C3QI00075C
50. [50]
  L. Liu, J. Jiang, X. Liu, et al., Inorg. Chem. Front. 7 (2020) 4640–4651. doi: 10.1039/D0QI01031F
51. [51]
  I.D. Brown, D. Altermatt, Sect. B: Struct. Sci. 41 (1985) 244–247.
52. [52]
  R.P. Bontchev, M. Nyman, Angew. Chem. Int. Ed. 45 (2006) 6670–6672. doi: 10.1002/anie.200602200
53. [53]
  S.-.T. Zheng, J. Zhang, J.M. Clemente-Juan, et al., Angew. Chem. Int. Ed. 48 (2009) 7176–7179. doi: 10.1002/anie.200901653
54. [54]
  D. Zhang, F. Cao, P. Ma, et al., Chem. Eur. J. 21 (2015) 17683–17690. doi: 10.1002/chem.201502892
55. [55]
  M. Cheng, Y. Liu, N. Li, Chem. Commun. 58 (2022) 1167–1170. doi: 10.1039/D1CC06781H
56. [56]
  W. Yang, F.Y. Yi, T. Tian, et al., Cryst. Growth Des. 14 (2014) 1366–1374. doi: 10.1021/cg401850v
57. [57]
  A. Brachmann, G. Geipel, G. Bernhard k, H. Nitsche, Radiochim. Acta 90 (2002) 147–153. doi: 10.1524/ract.2002.90.3_2002.147
58. [58]
  A.N. Radhakrishnan, P.P. Rao, K.S. Linsa, et al., Dalton Trans. 40 (2011) 3839–3848. doi: 10.1039/c0dt01688h
59. [59]
  C.K. Duan, A. Meijerink, R.J. Reeves, M.F. Reid, J. Alloys Compd. (2006) 784–787 408–412.
60. [60]
  D. Gu, W. Yang, H. Chen, et al., Inorg. Chem. Front. 8 (2021) 3514–3521. doi: 10.1039/D1QI00580D
1. [1]
  Tiantian Gong , Yanan Chen , Shuo Wang , Miao Wang , Junwei Zhao . Rigid-flexible-ligand-ornamented lanthanide-incorporated selenotungstates and photoluminescence properties. Chinese Journal of Structural Chemistry, 2024, 43(9): 100370-100370. doi: 10.1016/j.cjsc.2024.100370
2. [2]
  Xuan Zhu , Lin Zhou , Xiao-Yun Huang , Yan-Ling Luo , Xin Deng , Xin Yan , Yan-Juan Wang , Yan Qin , Yuan-Yuan Tang . (Benzimidazolium)2GeI4: A layered two-dimensional perovskite with dielectric switching and broadband near-infrared photoluminescence. Chinese Journal of Structural Chemistry, 2024, 43(6): 100272-100272. doi: 10.1016/j.cjsc.2024.100272
3. [3]
  Xiao-Tong Sun , Hao-Fei Ni , Yi Zhang , Da-Wei Fu . Hybrid perovskite shows temperature-dependent photoluminescence and dielectric response triggered by halogen substitution. Chinese Journal of Structural Chemistry, 2024, 43(6): 100212-100212. doi: 10.1016/j.cjsc.2024.100212
4. [4]
  Chen Lian , Si-Han Zhao , Hai-Lou Li , Xinhua Cao . A giant Ce-containing poly(tungstobismuthate): Synthesis, structure and catalytic performance for the decontamination of a sulfur mustard simulant. Chinese Chemical Letters, 2024, 35(10): 109343-. doi: 10.1016/j.cclet.2023.109343
5. [5]
  Guoping Yang , Zhoufu Lin , Xize Zhang , Jiawei Cao , Xuejiao Chen , Yufeng Liu , Xiaoling Lin , Ke Li . Assembly of Y(Ⅲ)-containing antimonotungstates induced by malic acid with catalytic activity for the synthesis of imidazoles. Chinese Chemical Letters, 2024, 35(12): 110274-. doi: 10.1016/j.cclet.2024.110274
6. [6]
  Bohan Zhang , Bingzhe Wang , Guichuan Xing , Zikang Tang , Songnan Qu . Regulation of the multi-emission centers in carbon dots via a bottom-up synthesis approach. Chinese Chemical Letters, 2024, 35(9): 109358-. doi: 10.1016/j.cclet.2023.109358
7. [7]
  Yulong Shi , Fenbei Chen , Mengyuan Wu , Xin Zhang , Runze Meng , Kun Wang , Yan Wang , Yuheng Mei , Qionglu Duan , Yinghong Li , Rongmei Gao , Yuhuan Li , Hongbin Deng , Jiandong Jiang , Yanxiang Wang , Danqing Song . Chemical construction and anti-HCoV-OC43 evaluation of novel 10,12-disubstituted aloperine derivatives as dual cofactor inhibitors of TMPRSS2 and SR-B1. Chinese Chemical Letters, 2024, 35(5): 108792-. doi: 10.1016/j.cclet.2023.108792
8. [8]
  Boyuan Hu , Jian Zhang , Yulin Yang , Yayu Dong , Jiaqi Wang , Wei Wang , Kaifeng Lin , Debin Xia . Dual-functional POM@IL complex modulate hole transport layer properties and interfacial charge dynamics for highly efficient and stable perovskite solar cells. Chinese Chemical Letters, 2024, 35(7): 108933-. doi: 10.1016/j.cclet.2023.108933
9. [9]
  Pingping Wang , Huixian Miao , Kechuan Sheng , Bin Wang , Fan Feng , Xuankun Cai , Wei Huang , Dayu Wu . Efficient blue-light-excitable copper(Ⅰ) coordination network phosphors for high-performance white LEDs. Chinese Chemical Letters, 2024, 35(4): 108600-. doi: 10.1016/j.cclet.2023.108600
10. [10]
  Jun-Jie Fang , Zheng Liu , Yun-Peng Xie , Xing Lu . Superatomic Ag₅₈ nanoclusters incorporating a [MS₄@Ag₁₂]²⁺ (M = Mo or W) kernel show aggregation-induced emission. Chinese Chemical Letters, 2024, 35(10): 109345-. doi: 10.1016/j.cclet.2023.109345
11. [11]
  Yan Wang , Si-Meng Zhai , Peng Luo , Xi-Yan Dong , Jia-Yin Wang , Zhen Han , Shuang-Quan Zang . Vapor- and temperature-triggered reversible optical switching for multi-response Cu₈ cluster supercrystals. Chinese Chemical Letters, 2024, 35(11): 109493-. doi: 10.1016/j.cclet.2024.109493
12. [12]
  Yanting Yang , Guorong Wang , Kangjing Li , Wen Yang , Jing Zhang , Jian Zhang , Shili Li , Xianming Zhang . Tuning up of chromism, luminescence in cadmium-viologen complexes through polymorphism strategy: Inkless erasable printing application. Chinese Chemical Letters, 2025, 36(1): 110123-. doi: 10.1016/j.cclet.2024.110123
13. [13]
  Huanyu Liu , Gang Yu , Ruoyao Guo , Hao Qi , Jiayin Zheng , Tong Jin , Zifeng Zhao , Zuqiang Bian , Zhiwei Liu . Direct identification of energy transfer mechanism in Ce^Ⅲ-Mn^Ⅱ system by constructing molecular heteronuclear complexes. Chinese Chemical Letters, 2025, 36(2): 110296-. doi: 10.1016/j.cclet.2024.110296
14. [14]
  Peipei CUI , Xin LI , Yilin CHEN , Zhilin CHENG , Feiyan GAO , Xu GUO , Wenning YAN , Yuchen DENG . Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234
15. [15]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
16. [16]
  Huipeng Zhao , Xiaoqiang Du . Polyoxometalates as the redox anolyte for efficient conversion of biomass to formic acid. Chinese Journal of Structural Chemistry, 2024, 43(2): 100246-100246. doi: 10.1016/j.cjsc.2024.100246
17. [17]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
18. [18]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
19. [19]
  Jianjun Liu , Xue Yang , Chi Zhang , Xueyu Zhao , Zhiwei Zhang , Yongmei Chen , Qinghong Xu , Shao Jin . Preparation and Fluorescence Characterization of CdTe Semiconductor Quantum Dots. University Chemistry, 2024, 39(7): 307-315. doi: 10.3866/PKU.DXHX202311031
20. [20]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(384)
HTML views(9)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142