Citation: Xi Yan, Yixin Yang, Guorong Li, Jianhua Zhang, Yu He, Ran Wang, Zian Lin, Zongwei Cai. Thiophene-based covalent organic frameworks for highly efficient iodine capture[J]. Chinese Chemical Letters, ;2023, 34(1): 107201. doi: 10.1016/j.cclet.2022.02.007 shu

Thiophene-based covalent organic frameworks for highly efficient iodine capture

Xi Yan ^a ,
Yixin Yang ^a ,
Guorong Li ^a ,
Jianhua Zhang ^c ,
Yu He ^a ,
Ran Wang ^a ,
Zian Lin ^{a, *,} ,
Zongwei Cai ^b

a.
Ministry of Education Key Laboratory of Analytical Science for Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou 350108, China
b.
State Key Laboratory of Environmental and Biological Analysis, Department of Chemistry, Hong Kong Baptist University, Hong Kong, China
c.
Radiation Environment Supervision Station of Fujian Province, Fuzhou 350001, China

zianlin@fzu.edu.cn

Received Date: 14 November 2021
Revised Date: 19 December 2021
Accepted Date: 3 February 2022
Available Online: 6 February 2022

Figures(4)

Development of adsorbent materials for highly efficient iodine capture is high demand from the perspective of ecological environment and human health. Herein, the two kinds of thiophene-based covalent organic frameworks (COFs) with different morphologies were synthesized by solvothermal reaction using thieno[3, 2-b]thiophene-2, 5-dicarbaldehyde (TT) as the aldehyde monomer and tri(4-aminophenyl)benzene (PB) or tris(4-aminophenyl)amine (PA) as the amino monomer (denoted as PB-TT COF and PA-TT COF) and the as-prepared two heteroatoms-rich COFs possessed many excellent properties, including high thermal stability and abundant binding sites. Among them, PB-TT COF exhibited ultra-high iodine uptake up to 5.97 g/g in vapor, surpassing most of adsorbents previously reported, which was ascribed to its high specific surface (1305.3 m²/g). Interestingly, PA-TT COF with low specific surface (48.6 m²/g) showed good adsorption ability for iodine in cyclohexane solution with uptake value of 750 mg/g, which was 2.38 times higher than that obtained with PB-TT COF due to its unique sheet-like morphology. Besides, the two COFs possessed good reusability, high selectivity and iodine retention ability. Based on experimental results, the adsorption mechanisms of both COFs were studied, revealing that iodine was captured by the physical-chemical adsorption. Furthermore, the both COFs showed excellent adsorption ability in real radioactive seawater treated safely, demonstrating their great potential in real environment.
- Thiophene-based covalent organic frameworks,
- Iodine,
- Morphology,
- Adsorption mechanisms,
- Radioactive seawater
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