Citation: Li Song, Shichao Jing, Yixing Qiu, Fuqiang Liu, Aimin Li. Efficient removal of Cr(Ⅲ)-carboxyl complex from neutral and high-salinity wastewater by nitrogen doped biomass-based composites[J]. Chinese Chemical Letters, ;2023, 34(1): 107180. doi: 10.1016/j.cclet.2022.01.073 shu

Efficient removal of Cr(Ⅲ)-carboxyl complex from neutral and high-salinity wastewater by nitrogen doped biomass-based composites

State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210023, China

lfq@nju.edu.cn

Received Date: 17 November 2021
Revised Date: 27 December 2021
Accepted Date: 25 January 2022
Available Online: 1 February 2022

Figures(5)

Heavy metals usually exist stably as the species of organic complexes in high-salinity wastewater. Therefore, their effective removal is challenging, especially when the initial pH is neutral. Herein, a novel nitrogen doped biomass-based composite (N-CMCS) was synthesized to remove the complexed heavy metal of Cr(Ⅲ)-carboxyl. The maximum adsorption capacity of Cr(Ⅲ)-Citrate (Cr-Cit) by N-CMCS under neutral pH (7.0) and high-salinity (200 mmol/L NaCl) condition was up to 2.50 mmol/g. And the removal performance remained stable after 6 times of regeneration. Combined with species and characterizations analysis, electrostatic attraction and hydrogen bonding were the main mechanisms for N-CMCS to remove Cr(Ⅲ)-carboxyl complexes. Dynamic adsorption indicated N-CMCS column could treat about 1300 BV simulated wastewater and 350 BV actual wastewater with the concentration of effluent lower than 1.0 mg/L. Furthermore, N-CMCS could remove a variety of complexed heavy metal ions under neutral pH, indicating the great potential in practical application.
- Biomass-based,
- Nitrogen doping,
- Adsorption,
- Complexed heavy metals,
- High-salinity wastewater
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