Citation: Zhibin Zhang, Zifan Li, Zhimin Dong, Fengtao Yu, Yingcai Wang, Youqun Wang, Xiaohong Cao, Yuhui Liu, Yunhai Liu. Synergy of photocatalytic reduction and adsorption for boosting uranium removal with PMo₁₂/UiO-66 heterojunction[J]. Chinese Chemical Letters, ;2022, 33(7): 3577-3580. doi: 10.1016/j.cclet.2022.01.062 shu

Synergy of photocatalytic reduction and adsorption for boosting uranium removal with PMo₁₂/UiO-66 heterojunction

Zhibin Zhang ^{a, b, 1} ,
Zifan Li ^{a, b, 1} ,
Zhimin Dong ^{a, b} ,
Fengtao Yu ^{a, b} ,
Yingcai Wang ^{a, b} ,
Youqun Wang ^{a, b} ,
Xiaohong Cao ^{a, b} ,
Yuhui Liu ^{a, b, *,} ,
Yunhai Liu ^{a, b, *,}

a.
Jiangxi Province Key Laboratory of Synthetic Chemistry, East China University of Technology, Nanchang 330013, China
b.
State Key Laboratory of Nuclear Resources and Environment, East China University of Technology, Nanchang 330013, China

liuyuhui@ecut.edu.cn

yhliu@ecut.edu.cn

Received Date: 21 November 2021
Revised Date: 21 January 2022
Accepted Date: 24 January 2022
Available Online: 31 January 2022

Figures(6)

In this work, we proposed a new U(Ⅵ) removal strategy combining adsorption and photocatalytic reduction by the PMo₁₂/UiO-66 heterojunctions. The PMo₁₂ has been encapsulated in the cavities of UiO-66 by a one-step hydrothermal method, and the PMo₁₂/UiO-66 exhibited high adsorption capacity and photocatalytic activity. The maximal theoretical sorption capacity of U(Ⅵ) on 15% PMo₁₂/UiO-66 reached 225.36 mg/g and the photoreduction rate of 15% PMo₁₂/UiO-66 is about thirty times as much as UiO-66. Under the light irradiation, the photogenerated electrons rapidly transport from UiO-66 to PMo₁₂, and the photo-generated electrons could efficiently reduce the pre-enriched U(Ⅵ) to U(Ⅳ). This work provides new insights into remediation of the radioactive environment.
- UiO-66,
- PMo12,
- Uranium,
- Adsorption,
- Photocatalytic reduction
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synergy of photocatalytic reduction and adsorption for boosting uranium removal with PMo12/UiO-66 heterojunction

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通讯作者: 陈斌, bchen63@163.com

Synergy of photocatalytic reduction and adsorption for boosting uranium removal with PMo₁₂/UiO-66 heterojunction