Citation: Huan Xue, Haolin Zhu, Jiarun Huang, Peiqin Liao, Xiaoming Chen. Ultrathin two-dimensional triptycence-based metal-organic framework for highly selective CO₂ electroreduction to CO[J]. Chinese Chemical Letters, ;2023, 34(1): 107134. doi: 10.1016/j.cclet.2022.01.027 shu

Ultrathin two-dimensional triptycence-based metal-organic framework for highly selective CO₂ electroreduction to CO

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China

liaopq3@mail.sysu.edu.cn

Received Date: 30 November 2021
Revised Date: 3 January 2022
Accepted Date: 10 January 2022
Available Online: 16 January 2022

Figures(4)

Efficient CO₂ reduction reaction (CO₂RR) is one of the important topics in energy and environment field, but improving the electrochemical selectivity of specific product is a great challenge. Herein, we reported a unprecedented two-dimensional (2D) metal−organic framework with CuO₄ unit (denoted as Cu-HHTT, HHTT = 9, 10-dihydro-9, 10-[1,2]benzenoanthracene-2, 3, 6, 7, 14, 15-hexaol) as the electrocatalyst for CO₂RR. Cu-HHTT exhibits high performance for CO₂RR to produce CO, namely Faradaic efficiency of 96.6% toward CO with a current density of 18 mA/cm² at the potential of −0.6 V vs. RHE. Density function theory reveals that the desorption of CO species exhibits a lower energy barrier than that of hydrogenation of *CO intermediate, resulting in CO as the main product instead of alcohols or hydrocarbons.
- Triptycence,
- Metal organic framework,
- Nanosheet,
- Electrochemical CO₂ reduction,
- Carbon monoxide production
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沈阳化工大学材料科学与工程学院沈阳 110142

Ultrathin two-dimensional triptycence-based metal-organic framework for highly selective CO2 electroreduction to CO

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通讯作者: 陈斌, bchen63@163.com

Ultrathin two-dimensional triptycence-based metal-organic framework for highly selective CO₂ electroreduction to CO