Citation: Yingjie Miao, Yufan Zheng, Feng Tao, Zhijun Chen, Yi Xiong, Fengzhang Ren, Yong Liu. Synthesis and application of single-atom catalysts in sulfur cathode for high-performance lithium–sulfur batteries[J]. Chinese Chemical Letters, ;2023, 34(1): 107121. doi: 10.1016/j.cclet.2022.01.014 shu

Synthesis and application of single-atom catalysts in sulfur cathode for high-performance lithium–sulfur batteries

Yingjie Miao ^a ,
Yufan Zheng ^b ,
Feng Tao ^a ,
Zhijun Chen ^c ,
Yi Xiong ^a ,
Fengzhang Ren ^{a, *,} ,
Yong Liu ^{a, *,}

a.
Provincial and Ministerial Co-Construction of Collaborative Innovation Center for Non-Ferrous Metal New Materials and Advanced Processing Technology, Henan Key Laboratory of Non-Ferrous Materials Science and Processing Technology, School of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023, China
b.
School of Intelligent Manufacturing Ecosystem, Xi'an Jiaotong – Liverpool University, Suzhou 215123, China
c.
Luoyang Bearing Research Institute Co., Ltd., Luoyang 471039, China

renfz@haust.edu.cn

liuyong209@haust.edu.cn

Received Date: 3 December 2021
Revised Date: 27 December 2021
Accepted Date: 6 January 2022
Available Online: 13 January 2022

Figures(10)

Lithium–sulfur (Li-S) batteries are regarded as one of the most promising energy storage devices because of their low cost, high energy density, and environmental friendliness. However, Li-S batteries suffer from sluggish reaction kinetics and serious "shuttle effect" of lithium polysulfides (LiPSs), which causes rapid decay of battery capacity and prevent their practical application. To address these problems, introducing single-atom catalysts (SACs) is an effective method to improve the electrochemical performance of Li-S batteries, due to their high catalytic efficiency and definite active sites for LiPSs. In this paper, we summarized the latest developments in enhancing the electrochemical performance of cathode for Li-S batteries through introducing different SACs. Furthermore, we briefly introduced the catalytic mechanism of SACs and discussed the strategies of synthesizing SACs, including the spatial confinement strategy and the coordination design strategy. Finally, the challenges and prospects in this field are proposed. We believe that this review would help to design and fabricate high-performance Li-S batteries via introducing SACs and boost their practical application.
- Single-atom catalysts,
- Lithium–sulfur batteries,
- Sulfur cathode,
- Synthesis and application,
- Polysulfide conversion,
- Shuttle effect
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