Citation: Zongping Wang, Fan Bai, Lisan Cao, Siyang Yue, Jingwen Wang, Songlin Wang, Jun Ma, Pengchao Xie. Activation of sulfite by ferric ion for the degradation of 2,4,6-tribromophenol with the addition of sulfite in batches[J]. Chinese Chemical Letters, ;2022, 33(11): 4766-4770. doi: 10.1016/j.cclet.2022.01.003 shu

Activation of sulfite by ferric ion for the degradation of 2,4,6-tribromophenol with the addition of sulfite in batches

Zongping Wang ^a ,
Fan Bai ^a ,
Lisan Cao ^a ,
Siyang Yue ^b ,
Jingwen Wang ^a ,
Songlin Wang ^a ,
Jun Ma ^c ,
Pengchao Xie ^{a, *,}

a.
School of Environmental Science and Engineering, Key Laboratory of Water & Wastewater Treatment (MOHURD), Hubei Provincial Engineering Research Center for Water Quality Safety and Pollution Control, Huazhong University of Science and Technology, Wuhan 430074, China
b.
School of Architecture & Urban Planning, Huazhong University of Science and Technology, Wuhan 430074, China
c.
State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, China

pengchao_xie@hust.edu.cn

Received Date: 25 September 2021
Revised Date: 14 November 2021
Accepted Date: 4 January 2022
Available Online: 8 January 2022

Figures(4)

In this work, the removal of 2,4,6-tribromophenol (TBP) by ferric ion-activated sulfite [Fe(III)/S(IV)] process was systematically investigated with determining the intermediate products and evaluating the influences of some operational conditions and water matrices. Our results show that batching addition of S(IV) benefits the S(IV) utilization efficiency and TBP removal, with SO₄^•‒ being the primary reactive radical accounting for TBA degradation. The maximum TBP removal in the Fe(III)/S(IV) process was observed at pH 4.0 and oxygen is essential in this process. With increasing Fe(III) and S(IV) dosages from 0.05 and 0.1 mmol/L to 0.2 and 2.0 mmol/L, respectively, TBP removal followed trends of first increase then decrease. As the acute toxicity of the TBP solution was significantly reduced, the Fe(III)/S(IV) process was believed to be a good choice in the treatment of TBP.
- Fe(III)/S(IV),
- 2,4,6-Tribromophenol (TBP),
- Sulfate radical (SO₄^•‒),
- Batches,
- Acute toxicity
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