Citation: Xin Ren, Jianyou Shi, Ruihuan Duan, Jun Di, Chao Xue, Xiao Luo, Qing Liu, Mengyang Xia, Bo Lin, Wu Tang. Construction of high-efficiency CoS@Nb₂O₅ heterojunctions accelerating charge transfer for boosting photocatalytic hydrogen evolution[J]. Chinese Chemical Letters, ;2022, 33(10): 4700-4704. doi: 10.1016/j.cclet.2021.12.076 shu

Construction of high-efficiency CoS@Nb₂O₅ heterojunctions accelerating charge transfer for boosting photocatalytic hydrogen evolution

Xin Ren ^{a, b} ,
Jianyou Shi ^c ,
Ruihuan Duan ^d ,
Jun Di ^d ,
Chao Xue ^e ,
Xiao Luo ^f ,
Qing Liu ^f ,
Mengyang Xia ^{b, *,} ,
Bo Lin ^{b, *,} ,
Wu Tang ^{a, *,}

a.
School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, China
b.
XJTU-Oxford International Joint Laboratory for Catalysis, School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an 710049, China
c.
Personalized Drug Therapy Key Laboratory of Sichuan Province, Sichuan Academy of Medical Science & Sichuan Provincial People's Hospital, School of Medicine, University of Electronic Science and Technology of China, Chengdu 610072, China
d.
School of Materials Science and Engineering, Nanyang Technological University, 639798, Singapore
e.
State Centre for International Cooperation on Designer Low-carbon and Environmental Materials (CDLCEM), School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China
f.
School of Optoelectronic Science and Engineering, University of Electronic Science and Technology of China, Chengdu 611731, China

nearsoul@stu.xjtu.edu.cn

bolinscet@xjtu.edu.cn

tang@uestc.edu.cn

Received Date: 18 October 2021
Revised Date: 12 November 2021
Accepted Date: 27 December 2021
Available Online: 2 January 2022

Figures(5)

The random movement and easy recombination of photoinduced charges lead to a low conversion efficiency for photocatalytic hydrogen evolution. The cocatalyst design is a promising route to address such problem through introducing an appropriate cocatalyst on the semiconductor photocatalysts to construct the high-efficiency heterojunctions. Herein, novel CoS/Nb₂O₅ heterojunctions were constructed via in-situ loading CoS cocatalyst on the surface of Nb₂O₅ nanosheets. Through the femtosecond-resolved transient absorption spectroscopy, the average lifetime of charge carriers for 10 wt% CoS/Nb₂O₅ (159.6 ps) is drastically shortened by contrast with that of Nb₂O₅ (5531.9 ps), strongly suggesting the rapid charge transfer from Nb₂O₅ to CoS. The significantly improved charge-transfer capacity contributes to a high photocatalytic hydrogen evolution rate of 355 μmol/h, up to 17.5 times compared with pristine Nb₂O₅. This work would provide a new design platform in the construction of photocatalytic heterojunctions with high charge-transfer efficiency.
- Transition metal chalcogenides,
- CoS cocatalyst,
- Nb₂O₅ nanosheets,
- Charge transfer,
- Photocatalytic H₂ evolution
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Construction of high-efficiency CoS@Nb2O5 heterojunctions accelerating charge transfer for boosting photocatalytic hydrogen evolution

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Construction of high-efficiency CoS@Nb₂O₅ heterojunctions accelerating charge transfer for boosting photocatalytic hydrogen evolution