Citation: Linqing Wang, Haiyong Zhu, Tianyu Peng, Yingfan Xu, Yanzhe Hou, Shixin Li, Shiming Pang, Hailong Zhang, Dongxu Yang. A tandem asymmetric oxidation-oxa-Michael sequence for dearomatization of β-naphthols[J]. Chinese Chemical Letters, ;2022, 33(9): 4273-4276. doi: 10.1016/j.cclet.2021.12.075 shu

A tandem asymmetric oxidation-oxa-Michael sequence for dearomatization of β-naphthols

Key Laboratory of Preclinical Study for New Drugs of Gansu Province, Institute of Drug Design & Synthesis, School of Basic Medical Sciences, Lanzhou University, Lanzhou 730000, China

zhanghl@lzu.edu.cn

yangdx@lzu.edu.cn

Received Date: 3 November 2021
Revised Date: 26 December 2021
Accepted Date: 28 December 2021
Available Online: 2 January 2022

Figures(5)

A catalytic asymmetric hydroxylative dearomatization reaction has been disclosed, and the products can smoothly transform into spiroannulation adducts by simply treated with a base under mild conditions. Novel in-situ generated magnesium catalytic methods are developed by application of combinational ligands. Related concise transformaitons of the spiroannulation adducts have been carried out.
- Oxidative dearomatization,
- Oxa-Michael reaction,
- Asymmetric reaction,
- Chiral ligands,
- Magnesium catalyst
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