Citation: Yubin Ma, Fan Gao, Wanru Xiao, Na Li, Shujun Li, Bing Yu, Xuenian Chen. Two transition-metal-modified Nb/W mixed-addendum polyoxometalates for visible-light-mediated aerobic benzylic C–H oxidations[J]. Chinese Chemical Letters, ;2022, 33(9): 4395-4399. doi: 10.1016/j.cclet.2021.12.023 shu

Two transition-metal-modified Nb/W mixed-addendum polyoxometalates for visible-light-mediated aerobic benzylic C–H oxidations

Yubin Ma ^{a, 1} ,
Fan Gao ^{b, 1} ,
Wanru Xiao ^a ,
Na Li ^a ,
Shujun Li ^{a, *,} ,
Bing Yu ^{b, *,} ,
Xuenian Chen ^{a, b, *,}

a.
School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang 453007, China
b.
College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

lisj@htu.edu.cn

bingyu@zzu.edu.cn

xnchen@htu.edu.cn

Received Date: 14 November 2021
Revised Date: 5 December 2021
Accepted Date: 10 December 2021
Available Online: 17 December 2021

Figures(7)

The visible-light-induced selective oxidation of ubiquitous C–H bonds into valuable C=O bonds under aerobic conditions is one of the most attractive approaches for the construction of carbonyl-containing molecules. In this work, two transition metal-containing Nb/W mixed-addendum POMs dimers with the formula of K₂Na₂H₅[(Fe(H₂O)₄)₃(P₂W₁₅Nb₃O₆₂)₂]·24H₂O (POM[Fe]) and K₂Na₃H₄[(Cr(H₂O)₄)₃(P₂W₁₅Nb₃O₆₂)₂]·32H₂O (POM[Cr]) have been synthesized and characterized by various analytical and spectral techniques. POM[Fe] was proved to be an efficient photocatalyst for benzylic C–H oxidation under visible light and using oxygen as an oxidant to produce the corresponding carbonyl complex in good yields. A plausible mechanism involving superoxide radical was proposed for the catalytic reaction. POM[Fe] showed good reusability in the recycling experiments. IR spectroscopy and XRD analysis indicate that POM[Fe] can retain its integrity after catalysis.
- Polyoxometalates,
- Mixed-addendum POMs,
- Visible-light-induced catalysis,
- Photocatalysis,
- C–H bonds oxidation
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