Citation: Hao Wang. Recent advances on carborane-based ligands in low-valent group 13 and group 14 elements chemistry[J]. Chinese Chemical Letters, ;2022, 33(8): 3672-3680. doi: 10.1016/j.cclet.2021.12.016 shu

Recent advances on carborane-based ligands in low-valent group 13 and group 14 elements chemistry

Hao Wang

School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

whang@seu.edu.cn

Received Date: 8 September 2021
Revised Date: 3 December 2021
Accepted Date: 9 December 2021
Available Online: 12 December 2021

Figures(28)

Carboranes are a class of polyhedral boron-carbon molecular clusters, they can serve as versatile ligands in stabilizing low-valent main group element compounds, due to their exceptionally thermal and chemical stabilities, easy modifications at the cage carbon vertices, as well as large spherical steric effects. These carborane-based ligands provide interesting opportunities for the synthesis of low-valent main group element compounds with novel structure and reactivity, which indeed enrich the chemistry of low-valent element main group compounds. This review summarizes the recent advances in the chemistry of low-valent group 13 and group 14 element compounds supported by carborane-based ligands. Achievements and perspectives in this new and flourishing field are discussed in this review.
- Carborane,
- Borylene,
- Carbene,
- Silylene,
- Main group chemistry
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