Citation: Mengyuan Cheng, Yufeng Liu, Weixin Du, Jingwen Shi, Junhua Li, Haiying Wang, Ke Li, Guoping Yang, Dongdi Zhang. Two Dawson-type U(Ⅵ)-containing selenotungstates with sandwich structure and its high-efficiency catalysis for pyrazoles[J]. Chinese Chemical Letters, ;2022, 33(8): 3899-3902. doi: 10.1016/j.cclet.2021.11.059 shu

Two Dawson-type U(Ⅵ)-containing selenotungstates with sandwich structure and its high-efficiency catalysis for pyrazoles

Mengyuan Cheng ^{a, 1} ,
Yufeng Liu ^{b, 1} ,
Weixin Du ^a ,
Jingwen Shi ^a ,
Junhua Li ^a ,
Haiying Wang ^a ,
Ke Li ^b ,
Guoping Yang ^{b, *,} ,
Dongdi Zhang ^{a, *,}

a.
Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China
b.
Jiangxi Province Key Laboratory of Synthetic Chemistry, Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China University of Technology, Nanchang 330013, China

erick@ecut.edu.cn

ddzhang@henu.edu.cn

Received Date: 1 November 2021
Revised Date: 16 November 2021
Accepted Date: 17 November 2021
Available Online: 24 November 2021

Figures(5)

Two novel uranium-containing selenotungstates Na₃[H₁₉(UO₂)₂(μ_2-O)(Se₂W₁₄O₅₂)₂]·41H₂O (U₂) and (NH₄)₁₀[H₄(SeO)₂(UO₂)₂(H₂O)₂(H₂Se₂W₁₄O₅₂)(Se₂W₁₄O₅₂)]·66H₂O (Se₂U₂) based on the {Se₂W₁₄O₅₂} unit were successfully prepared and fully characterized. To our knowledge, the uranium is firstly introduced into the selenotungstates. Moreover, it is notable that U₂ exhibits excellent Lewis acid-base catalytic activities in the condensation cyclization of sulfonyl hydrazides with diketones to synthesize polysubstituted pyrazoles. All the desired products were obtained in moderate to good yields (up to 99%).
- Selenotungstates,
- Uranium,
- Dawson-type,
- Condensation reaction,
- Pyrazoles
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