Citation: Wenbin Xie, Kongyin Zhao, Lijing Xu, Ningning Gao, Hui Zhao, Zelong Gong, Linan Yu, Jun Jiang. Oxalic acid cross-linked sodium alginate and carboxymethyl chitosan hydrogel membrane for separation of dye/NaCl at high NaCl concentration[J]. Chinese Chemical Letters, ;2022, 33(4): 1951-1955. doi: 10.1016/j.cclet.2021.11.058 shu

Oxalic acid cross-linked sodium alginate and carboxymethyl chitosan hydrogel membrane for separation of dye/NaCl at high NaCl concentration

Wenbin Xie ^a ,
Kongyin Zhao ^{a, *,} ,
Lijing Xu ^a ,
Ningning Gao ^b ,
Hui Zhao ^a ,
Zelong Gong ^a ,
Linan Yu ^a ,
Jun Jiang ^a

a.
State Key Laboratory of Separation Membranes and Membrane Processes/National Centre for International Joint Research on Separation Membranes, Tiangong University, Tianjin 300387, China
b.
SINOPEC Research Institute of Petroleum Processing, Beijing 100083, China

zhaokongyin@tjpu.edu.cn

Received Date: 22 June 2021
Revised Date: 16 November 2021
Accepted Date: 16 November 2021
Available Online: 24 November 2021

Figures(4)

Dye desalination is a challenge in the treatment of textile wastewater with high salt concentration. It is imperative to develop salt resistance membrane that is from sustainable materials to effectively treat dye/salt mixtures. And most polymer membrane materials are non-renewable petrochemical resources. In this paper, a green hydrogel membrane (CMCS-OA-NaAlg) was prepared by non-metallic ions of oxalic acid (OA) cross-linking of two natural macromolecules of sodium alginate (NaAlg) and carboxymethyl chitosan (CMCS). The membrane showed excellent anti-swelling at high salt concentration (swelling rate less than 8.0% in 10.0 wt% NaCl solution) and good anti-fouling performance. The membrane exhibited a rejection higher than 95.0% for dyes (bright blue, direct black, direct red, and Congo red) and lower than 7.0% for NaCl, which can achieve better dye/NaCl separation performance. This study provides a promising membrane material for high salt textile wastewater treatment only using water and carbohydrates as raw materials without any organic solvents.
- Hydrogel filtration membranes,
- Oxalic acid,
- Sodium alginate,
- High salt wastewater,
- Salt resistance
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