Citation: Wenbin Xie, Kongyin Zhao, Lijing Xu, Ningning Gao, Hui Zhao, Zelong Gong, Linan Yu, Jun Jiang. Oxalic acid cross-linked sodium alginate and carboxymethyl chitosan hydrogel membrane for separation of dye/NaCl at high NaCl concentration[J]. Chinese Chemical Letters, ;2022, 33(4): 1951-1955. doi: 10.1016/j.cclet.2021.11.058 shu

Oxalic acid cross-linked sodium alginate and carboxymethyl chitosan hydrogel membrane for separation of dye/NaCl at high NaCl concentration

Wenbin Xie ^a ,
Kongyin Zhao ^{a, *,} ,
Lijing Xu ^a ,
Ningning Gao ^b ,
Hui Zhao ^a ,
Zelong Gong ^a ,
Linan Yu ^a ,
Jun Jiang ^a

a.
State Key Laboratory of Separation Membranes and Membrane Processes/National Centre for International Joint Research on Separation Membranes, Tiangong University, Tianjin 300387, China
b.
SINOPEC Research Institute of Petroleum Processing, Beijing 100083, China

zhaokongyin@tjpu.edu.cn

Received Date: 22 June 2021
Revised Date: 16 November 2021
Accepted Date: 16 November 2021
Available Online: 24 November 2021

Figures(4)

Dye desalination is a challenge in the treatment of textile wastewater with high salt concentration. It is imperative to develop salt resistance membrane that is from sustainable materials to effectively treat dye/salt mixtures. And most polymer membrane materials are non-renewable petrochemical resources. In this paper, a green hydrogel membrane (CMCS-OA-NaAlg) was prepared by non-metallic ions of oxalic acid (OA) cross-linking of two natural macromolecules of sodium alginate (NaAlg) and carboxymethyl chitosan (CMCS). The membrane showed excellent anti-swelling at high salt concentration (swelling rate less than 8.0% in 10.0 wt% NaCl solution) and good anti-fouling performance. The membrane exhibited a rejection higher than 95.0% for dyes (bright blue, direct black, direct red, and Congo red) and lower than 7.0% for NaCl, which can achieve better dye/NaCl separation performance. This study provides a promising membrane material for high salt textile wastewater treatment only using water and carbohydrates as raw materials without any organic solvents.
- Hydrogel filtration membranes,
- Oxalic acid,
- Sodium alginate,
- High salt wastewater,
- Salt resistance
1. [1]
  G.C. de Oliveira Neto, J.M. Ferreira Correia, P.C. Silva, et al., J. Clean. Prod. 228 (2019) 1514-1525. doi: 10.1016/j.jclepro.2019.04.334
2. [2]
  M. Fathy, A.E. Shahawy, T.A. Moghny, et al., Mater. Express 10 (2020) 671-679. doi: 10.1166/mex.2020.1677
3. [3]
  A.N. Kulkarni, A.D. Watharkar, N.R. Rane, et al., Ecotoxicol. Environ. Saf. 148 (2017) 17-25.
4. [4]
  S. Zhao, Z. Wang. Membr. Sci. 524 (2016) 214-224.
5. [5]
  Y. Zhao, X. Zhuang, S. Ahmad, et al., World J. Microb. Biot. 36 (2020) 1-11. doi: 10.1007/s11274-019-2775-x
6. [6]
  X. Tao, S. Wang, Z.M. Li, J. Environ. Manage. 255 (2020) 109834. doi: 10.1016/j.jenvman.2019.109834
7. [7]
  W. Peng, Y. Fu, L.L. Wang, et al., Chin. Chem. Lett. 32 (2021) 2544-2550. doi: 10.1016/j.cclet.2021.01.028
8. [8]
  X.C. Yu, Y. Lin, H.Y. L, et al., J. Colloid Interface Sci. 561 (2020) 379-395. doi: 10.1016/j.jcis.2019.10.123
9. [9]
  Q.Y. Sheng, Z. Wei, H. Miao, et al., Chem. Eng. J. 370 (2019) 287-294. doi: 10.1016/j.cej.2019.03.197
10. [10]
  Y. Geng, H.N. Yu, A.M. Zhou, et al., Mater Express 10 (2020) 2160-2165.
11. [11]
  T.L. Ni, J.Y. Lin, L.X. Kong, et al., Chin. Chem. Lett. 32 (2021) 3298-3306. doi: 10.1016/j.cclet.2021.02.035
12. [12]
  Y.W. Yang, H.Y. Zhao, Z.Y. Yin, et al., Mater. Horiz. 5 (2018) 1143-1150. doi: 10.1039/C8MH00386F
13. [13]
  S. Li, J. Dai, X. Geng, et al., Sep. Purif. Technol. 235 (2020) 116206. doi: 10.1016/j.seppur.2019.116206
14. [14]
  K. Zhao, X. Zhang, J. Wei, et al., J. Membr. Sci. 492 (2015) 536-546. doi: 10.1016/j.memsci.2015.05.075
15. [15]
  T. Bai, K. Zhao, Z. Lu, et al., Chin. Chem. Lett. 32 (2020) 1051-1054.
16. [16]
  Y. Zhang, K. Zhao, Z. Yang, et al., Sep. Purif. Technol. 270 (2021) 118761. doi: 10.1016/j.seppur.2021.118761
17. [17]
  A. Lungu, A.I. Cernencu, S. Dinescu, et al., Mater. Des. 197 (2020) 109200.
18. [18]
  M.M. Pérez-Madrigal, J. Torras, J. Casanovas, et al., Biomacromolecules 18 (2017) 2967-2979. doi: 10.1021/acs.biomac.7b00934
19. [19]
  E.C. de Siqueira, J.S. Reboucas, I.O. Pinheiro, et al., Int. J. Pharm. 580 (2020) 119242. doi: 10.1016/j.ijpharm.2020.119242
20. [20]
  S.C. Chen, Y.C. Wu, F.L. Mi, et al., J. Control. Release 96 (2004) 285-300. doi: 10.1016/j.jconrel.2004.02.002
21. [21]
  J. Pérez-Calderóna, M. Victoria Santosb, N. Zaritzkyac, React. Funct. Polym. 155 (2020) 104699. doi: 10.1016/j.reactfunctpolym.2020.104699
22. [22]
  D. Rana, T. Matsuura, Chem. Rev. 110 (2010) 2448-2471. doi: 10.1021/cr800208y
23. [23]
  I.A. Fadzallah, S.R. Majid, M.A. Careem, et al., J. Membr. Sci. 463 (2014) 65-72. doi: 10.1016/j.memsci.2014.03.044
24. [24]
  E.J. Baran, Carbohydr. Polym. 74 (2008) 704-706. doi: 10.1016/j.carbpol.2008.04.031
25. [25]
  S. Yalçınkaya, C. Demetgül, M. Timur, et al., Carbohydr. Polym. 79 (2010) 908-913. doi: 10.1016/j.carbpol.2009.10.022
26. [26]
  X.J. Lv, W.C. Zhang, Y.N. Liu, et al., Carbohydr. Polym. 198 (2018) 86-93. doi: 10.1016/j.carbpol.2018.06.058
27. [27]
  O. Ismail, A.S. Kipcak, S.J. Piskin, Rev. Roum. Chim. 39 (2013) 907-919.
28. [28]
  R. Choudhury, J.M. Gohil, S. Mohanty, et al., J. Mater. Chem. A 6 (2018) 313-333. doi: 10.1039/C7TA08627J
29. [29]
  X. Zhao, R. Zhang, Y. Liu, et al., J. Membr. Sci. 551 (2018) 145-171. doi: 10.1016/j.memsci.2018.01.039
1. [1]
  Feng Cao , Chunxiang Xian , Tianqi Yang , Yue Zhang , Haifeng Chen , Xinping He , Xukun Qian , Shenghui Shen , Yang Xia , Wenkui Zhang , Xinhui Xia . Gelation-pyrolysis strategy for fabrication of advanced carbon/sulfur cathodes for lithium-sulfur batteries. Chinese Chemical Letters, 2025, 36(3): 110575-. doi: 10.1016/j.cclet.2024.110575
2. [2]
  Ningning Gao , Yue Zhang , Zhenhao Yang , Lijing Xu , Kongyin Zhao , Qingping Xin , Junkui Gao , Junjun Shi , Jin Zhong , Huiguo Wang . Ba²⁺/Ca²⁺ co-crosslinked alginate hydrogel filtration membrane with high strength, high flux and stability for dye/salt separation. Chinese Chemical Letters, 2024, 35(5): 108820-. doi: 10.1016/j.cclet.2023.108820
3. [3]
  Feng Xu , Yuqiu Liu , Shujiao Xu , Jinxin Zhang , Lei Liao , Jiguang Guo , Weiyu Jiang , Hongzhe Dong , Qinxue Wen , Zhiqiang Chen . Enhanced removal of methylisothiazolinone from high-salt wastewater by Sn-Sb-Ce/GAC particle electrode: Reactive species and efficiency. Chinese Chemical Letters, 2025, 36(10): 111332-. doi: 10.1016/j.cclet.2025.111332
4. [4]
  Xianxin Luo , Jianhao Xu , Qi Luo , Yan Xiao , Feng Wei , Meitong Li , Wenjiao Yuan , Penghui Shao , Shenglian Luo . Efficient copper sorption from saline wastewater using citrate-modified biochar with robust anti-salt interferences. Chinese Chemical Letters, 2026, 37(5): 111914-. doi: 10.1016/j.cclet.2025.111914
5. [5]
  Qiangwei Wang , Huijiao Liu , Mengjie Wang , Haojie Zhang , Jianda Xie , Xuanwei Hu , Shiming Zhou , Weitai Wu . Observation of high ionic conductivity of polyelectrolyte microgels in salt-free solutions. Chinese Chemical Letters, 2024, 35(4): 108743-. doi: 10.1016/j.cclet.2023.108743
6. [6]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
7. [7]
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8. [8]
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9. [9]
  Yuhao Zhou , Siyuan Wu , Xiaozhe Ren , Hongjin Li , Shu Li , Tianying Yan . Effects of salt fraction on the Na⁺ transport in salt-in-ionic liquid electrolytes. Chinese Chemical Letters, 2025, 36(6): 110048-. doi: 10.1016/j.cclet.2024.110048
10. [10]
  Jing LIANG , Qian WANG , Junfeng BAI . Synthesis and structures of cdq-topological quaternary and (4, 4, 8)-c topological quinary Zn-MOFs with both oxalic acid and triazole ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2186-2192. doi: 10.11862/CJIC.20240177
11. [11]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
12. [12]
  Junhan Luo , Qi Qing , Liqin Huang , Zhe Wang , Shuang Liu , Jing Chen , Yuexiang Lu . Non-contact gaseous microplasma electrode as anode for electrodeposition of metal and metal alloy in molten salt. Chinese Chemical Letters, 2024, 35(4): 108483-. doi: 10.1016/j.cclet.2023.108483
13. [13]
  Kuan Deng , Fei Yang , Zhi-Qi Cheng , Bi-Wen Ren , Hua Liu , Jiao Chen , Meng-Yao She , Le Yu , Xiao-Gang Liu , Hai-Tao Feng , Jian-Li Li . Construction of wavelength-tunable DSE quinoline salt derivatives by regulating the hybridization form of the nitrogen atom and intramolecular torsion angle. Chinese Chemical Letters, 2024, 35(10): 109464-. doi: 10.1016/j.cclet.2023.109464
14. [14]
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15. [15]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
  Xue Du , Ze-Hua Sun , Penglei Zhang , Li-Ping Xu , Xiaodong Xiong . Asymmetric chloro– and selenocyclization of 2-alkenyl anilides enabled by tertiary ammonium salt catalysis. Chinese Chemical Letters, 2026, 37(4): 111259-. doi: 10.1016/j.cclet.2025.111259
20. [20]
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