Citation: Ningkai Ding, Bin Chen, Liang Zhou, Lingzhi Wang, Yongdi Liu, Jinlong Zhang, Juying Lei. Fluorinated inverse opal carbon nitride combined with vanadium pentoxide as a Z-scheme photocatalyst with enhanced photocatalytic activity[J]. Chinese Chemical Letters, ;2022, 33(8): 3797-3801. doi: 10.1016/j.cclet.2021.11.042 shu

Fluorinated inverse opal carbon nitride combined with vanadium pentoxide as a Z-scheme photocatalyst with enhanced photocatalytic activity

Ningkai Ding ^a ,
Bin Chen ^a ,
Liang Zhou ^{a, *,} ,
Lingzhi Wang ^{c, d} ,
Yongdi Liu ^{a, b} ,
Jinlong Zhang ^{c, d} ,
Juying Lei ^{a, b, *,}

a.
State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process, East China University of Science and Technology, Shanghai 200237, China
b.
Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China
c.
Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China
d.
Shanghai Engineering Research Center for Multi-media Environmental Catalysis and Resource Utilization, East China University of Science and Technology, Shanghai 200237, China

zhouliang@ecust.edu.cn

leijuying@ecust.edu.cn

Received Date: 9 August 2021
Revised Date: 5 October 2021
Accepted Date: 13 November 2021
Available Online: 18 November 2021

Figures(4)

In this work, Z-scheme V₂O₅ loaded fluorinated inverse opal carbon nitride (IO F-CN/V₂O₅) was synthesized as a product of ternary collaborative modification with heterostructure construction, element doping and inverse opal structure. The catalyst presented the highest photocatalytic activity and rate constant for degradation of typical organic pollutants Rhodamine B (RhB) and was also used for the efficient removal of antibiotics, represented by norfloxacin (NOR), sulfadiazine (SD) and levofloxacin (LVX). Characterizations confirmed its increased specific surface area, narrowed bandgap, and enhanced visible light utilization capacity. Further mechanism study including band structure study and electron paramagnetic resonance (EPR) proved the successful construction of Z-scheme heterojunction, which improved photo-generated charge carrier migration and provide sufficient free radicals for the degradation process. The combination of different modifications contributed to the synergetic improvement of removal efficiency towards different organic pollutants.
- Carbon nitride,
- Inverse opal structure,
- Vanadium pentoxide,
- Fluorinate,
- Organic pollutants degradation
1. [1]
  Y. Ye, Z. Zang, T. Zhou, et al., J. Catal. 357 (2018) 100-107. doi: 10.1016/j.jcat.2017.11.002
2. [2]
  D. Yuan, M. Sun, S. Tang, et al., Chin. Chem. Lett. 31 (2020) 547-550. doi: 10.1016/j.cclet.2019.09.051
3. [3]
  Y.C. Zhou, P. Wang, H. Fu, C. Zhao, C.C. Wang, Chin. Chem. Lett. 31 (2020) 2645-2650. doi: 10.31497/zrzyxb.20201107
4. [4]
  Q. Xu, L. Zhang, B. Cheng, J. Fan, J. Yu, Chem 6 (2020) 1543-1559. doi: 10.1016/j.chempr.2020.06.010
5. [5]
  Y. Xing, X. Wang, S. Hao, et al., Chin. Chem. Lett. 32 (2021) 13-20. doi: 10.1016/j.cclet.2020.11.011
6. [6]
  J. Fu, J. Yu, C. Jiang, C. Bei, Adv. Energy Mater. 8 (2018). 1701503. doi: 10.1002/aenm.201701503
7. [7]
  F. Wang, Y. Wang, Y. Feng, et al., Appl. Catal. B: Environ. 221 (2017) 510-520.
8. [8]
  J. Hu, W. Cheng, S. Huang, D. Wu, X. Zhi, Appl. Phys. Lett. 89 (2006) 841-853.
9. [9]
  A. Pisanu, A. Speltini, B. Vigani, et al., Dalton Trans. 47 (2018) 6772-6778. doi: 10.1039/c8dt00276b
10. [10]
  M. Ding, J. Zhou, H. Yang, et al., Chin. Chem. Lett. 31 (2020) 71-76. doi: 10.1016/j.cclet.2019.05.029
11. [11]
  B. Li, L.C. Nengzi, R. Guo, et al., Chin. Chem. Lett. 31 (2020) 2705-2711. doi: 10.1016/j.cclet.2020.04.026
12. [12]
  W. Ong, L. Tan, Y. Ng, S. Yong, S. Chai, Chem. Rev. 116 (2016) 7159-7329. doi: 10.1021/acs.chemrev.6b00075
13. [13]
  E.R. Brown, C.D. Parker, E. Yablonovitch, J. Opt. Soc. Am. B 10 (1993) 404-407. doi: 10.1364/JOSAB.10.000404
14. [14]
  M. Curti, C.B. Mendive, M.A. Grela, D.W. Bahnemann, Mater. Res. Bull. 91 (2017) 155-165. doi: 10.1016/j.materresbull.2017.03.061
15. [15]
  E. Cubukcu, K. Aydin, E. Ozbay, S. Foteinopoulou, C.M. Soukoulis, Nature 423 (2003) 604-605.
16. [16]
  M. Wu, J. Liu, J. Jin, et al., Appl. Catal. B-Environ. 150 (2014) 411-420.
17. [17]
  Y.Z. Dong, Y.S. Xue, W.W. Yang, H.M. You, Y. Su, Colloids Surf. A 561 (2019) 381-387. doi: 10.1016/j.colsurfa.2018.10.033
18. [18]
  X. Huang, W. Gu, S. Hu, et al., Catal. Sci. Technol. 10 (2020) 3694-3700. doi: 10.1039/d0cy00457j
19. [19]
  S. Lin, N. Zhang, F. Wang, et al., ACS Sustain. Chem. Eng. 9 (2021) 481-488. doi: 10.1021/acssuschemeng.0c07753
20. [20]
  Y. Tian, L. Zhou, Q. Zhu, et al., Nanoscale 11 (2019) 20638-20647. doi: 10.1039/c9nr06802c
21. [21]
  S. Hu, F. Li, Z. Fan, et al., Dalton Trans. 44 (2015) 1084-1092. doi: 10.1039/C4DT02658F
22. [22]
  J. Zhang, S. Hu, Y. Wang, RSC Adv. 4 (2014) 62912-62919. doi: 10.1039/C4RA11377B
23. [23]
  D.H. Lan, H.T. Wang, L. Chen, C.T. Au, S.F. Yin, Carbon 100 (2016) 81-89. doi: 10.1016/j.carbon.2015.12.098
24. [24]
  G. Liu, P. Niu, C. Sun, et al., J. Am. Chem. Soc. 132 (2010) 11642-11648. doi: 10.1021/ja103798k
25. [25]
  M. Xue, G. Tan, T. Liu, et al., Appl. Catal. A 578 (2019) 89-97. doi: 10.1016/j.apcata.2019.04.004
26. [26]
  F. Ma, C. Sun, Y. Shao, et al., New J. Chem. 41 (2017) 3061-3067. doi: 10.1039/C7NJ00035A
27. [27]
  A.D. Raj, T. Pazhanivel, P.S. Kumar, D. Mangalaraj, N. Ponpandian, Curr. Appl. Phys. 10 (2010) 531-537. doi: 10.1016/j.cap.2009.07.015
28. [28]
  C. Wang, L. Zhang, M. Al-Mamun, et al., Adv. Energy Mater. 9 (2019) 1900909. doi: 10.1002/aenm.201900909
29. [29]
  J. Su, X.X. Zou, G.D. Li, et al., J. Phys. Chem. C 115 (2011) 8064-8071. doi: 10.1021/jp200274k
30. [30]
  Y. Hong, Y. Jiang, C. Li, et al., Appl. Catal. B-Environ. 180 (2016) 663-673. doi: 10.1016/j.apcatb.2015.06.057
31. [31]
  S.C. Yan, Z.S. Li, Z.G. Zou, Langmuir 26 (2010) 3894-3901. doi: 10.1021/la904023j
32. [32]
  A.P. Dementjev, A.D. Graaf, M.C. M van de Sanden, et al., Diamond Relat. Mater. 9 (2000) 1904-1907. doi: 10.1016/S0925-9635(00)00345-9
33. [33]
  A. Vinu, Adv. Funct. Mater. 18 (2008) 816-827. doi: 10.1002/adfm.200700783
34. [34]
  J. Xu, L. Zhang, R. Shi, Y. Zhu, J. Mater. Chem. A 1 (2013) 14766-14772. doi: 10.1039/c3ta13188b
35. [35]
  L. Zeng, X. Ding, Z. Sun, et al., Appl. Catal. B: Environ. 227 (2018) 276-284. doi: 10.1016/j.apcatb.2018.01.040
36. [36]
  L. Jiang, X. Yuan, Y. Pan, et al., Appl. Catal. B: Environ. 217 (2017) 388-406.
37. [37]
  H. Lei, Q. He, M. Wu, et al., J. Hazard. Mater. 421 (2022) 126696. doi: 10.1016/j.jhazmat.2021.126696
38. [38]
  H. Lei, M. Wu, F. Mo, et al., Nano Energy 78 (2020) 105290. doi: 10.1016/j.nanoen.2020.105290
39. [39]
  Y. Wang, Y. Di, M. Antonietti, et al., Chem. Mater. 22 (2010) 5119-5121. doi: 10.1021/cm1019102
40. [40]
  C. Yao, R. Wang, Z. Wang, et al., J. Mater. Chem. A 7 (2019) 27547-27559. doi: 10.1039/c9ta09201c
41. [41]
  C. Yao, A. Yuan, Z. Wang, et al., J. Mater. Chem. A 7 (2019) 13071-13079. doi: 10.1039/c9ta03253c
42. [42]
  A. Yuan, H. Lei, Z. Wang, X. Dong, J. Colloid Interface Sci. 560 (2020) 40-49. doi: 10.1016/j.jcis.2019.10.060
43. [43]
  Y. Liu, A. Yuan, Y. Xiao, H. Yu, X. Dong, Ceram. Int. 46 (2020) 16157-16165.
44. [44]
  H. Lei, M. Wu, Y. Liu, et al., Chin. Chem. Lett. 32 (2021) 2317-2321.
45. [45]
  H. Lei, M. Wu, F. Mo, et al., Environ. Sci. : Nano 8 (2021) 1398-1407. doi: 10.1039/d0en01028f
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