Citation: Jingwei Huang, Kai Li, Lei Wang, Houde She, Qizhao Wang. In situ conversion builds MIL-101@NiFe-LDH heterojunction structures to enhance the oxygen evolution reaction[J]. Chinese Chemical Letters, ;2022, 33(8): 3787-3791. doi: 10.1016/j.cclet.2021.11.028 shu

In situ conversion builds MIL-101@NiFe-LDH heterojunction structures to enhance the oxygen evolution reaction

Jingwei Huang ^a ,
Kai Li ^a ,
Lei Wang ^a ,
Houde She ^a ,
Qizhao Wang ^{a, b, c, *,}

a.
College of Chemistry and Chemical Engineering, Gansu International Scientific and Technological Cooperation Base of Water-Retention Chemical Functional Materials, Northwest Normal University, Lanzhou 730070, China
b.
School of Environmental Science and Engineering, Chang'an University, Xi'an 710054, China
c.
Tianjin Key Laboratory of Building Green Functional Materials, Tianjin Chengjian University, Tianjin 300384, China

wangqizhao@163.com

Received Date: 1 September 2021
Revised Date: 3 October 2021
Accepted Date: 4 November 2021
Available Online: 11 November 2021

Figures(5)

The construction of rich phase interfaces to increase active reaction area in hybrid materials is an excellent strategy to improve electrochemical performance. Under this guideline, MIL-101@OX-metal organic framework (MOF) is constructed by the "MOF on MOF" method, then converts to MIL-101@NiFe-layered double hydroxides (LDH) by in situ transformation in alkaline solution. MIL-101@NiFe-LDH shows excellent electrochemical water oxidation performance. It needs only an overpotential of 215 mV to drive 10 mA/cm² of oxygen evolution reaction (OER), which is less than that of NiFe-LDH, MIL-101. In addition, MIL-101@NiFe-LDH has the smallest Tafel slope (55.1 mV/dec) compared with NiFe-LDH (61.1 mV/dec), MIL-101 (150.8 mV/dec). The excellent water oxidation activity is due to the high phase interfaces derived from high specific surface area of MOF. This work offers an alternative method for making MOF/LDH heterostructures with an optimized phase interfaces and provides new insights for OER.
- Mil-101@NiFe-LDH,
- OER,
- Electrocatalysis,
- Alkalize
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