Citation: Qian-Qian Wang, Rong Hu, Zheng-Qi Fang, Guoyue Shi, Shengqiang Zhang, Min Zhang. A multifunctional upconversion nanoparticles probe for Cu²⁺ sensing and pattern recognition of biothiols[J]. Chinese Chemical Letters, ;2022, 33(8): 3782-3786. doi: 10.1016/j.cclet.2021.11.012 shu

A multifunctional upconversion nanoparticles probe for Cu²⁺ sensing and pattern recognition of biothiols

Qian-Qian Wang ^{a, 1} ,
Rong Hu ^{a, 1} ,
Zheng-Qi Fang ^a ,
Guoyue Shi ^a ,
Shengqiang Zhang ^{b, *,} ,
Min Zhang ^{a, *,}

a.
School of Chemistry and Molecular Engineering, Shanghai Key Laboratory for Urban Ecological Processes and Eco-Restoration, East China Normal University, Shanghai 200241, China
b.
Fujian Provincial Key Laboratory of Resources and Environment Monitoring & Sustainable Management and Utilization, College of resource and chemical engineering, Sanming University, Sanming 365004, China

shengqiang.zhang@vip.163.com

mzhang@chem.ecnu.edu.cn

Received Date: 24 August 2021
Revised Date: 15 September 2021
Accepted Date: 3 November 2021
Available Online: 10 November 2021

Figures(7)

Lanthanide-doped upconversion nanoparticles (Ln-UCNPs) are a new type of nanomaterials with excellent fluorescence properties, which are well applied in fluorescent biosensing. Herein we developed a multifunctional probe based on the surface engineering of core-shell structure UCNPs with polyacrylic acid (PAA). The developed PAA/UCNPs probe could be highly selective to detect and respond to Cu²⁺ at different pH. Cu²⁺ could easily combine with the carboxylate anion of PAA to quench the fluorescence of UCNPs. Therefore, we creatively proposed a fluorescent array sensor (PAA/UCNPs-Cu²⁺), in which the same material acted as the sensing element by coupled with pH regulation for pattern recognition of 5 thiols. It could also easily identify the chiral enantiomer of cystine (L-Cys-and D-Cys), and distinguish their mixed samples with different concentrations, and more importantly, it could be combined with urine samples to detect actual level of homocysteine (Hcys) to provide a new solution for judging whether the human body suffers from homocystinuria.
- Upconversion nanomaterials,
- Polyacrylic acid,
- Copper ion,
- Pattern recognition sensor array,
- Biothiols
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沈阳化工大学材料科学与工程学院沈阳 110142

A multifunctional upconversion nanoparticles probe for Cu2+ sensing and pattern recognition of biothiols

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通讯作者: 陈斌, bchen63@163.com

A multifunctional upconversion nanoparticles probe for Cu²⁺ sensing and pattern recognition of biothiols