Citation: Jian Yao, Jian Kong, Lingwei Kong, Xinrui Wang, Wenying Shi, Chao Lu. The phosphorescence nanocomposite thin film with rich oxygen vacancy: Towards sensitive oxygen sensor[J]. Chinese Chemical Letters, ;2022, 33(8): 3977-3980. doi: 10.1016/j.cclet.2021.11.003 shu

The phosphorescence nanocomposite thin film with rich oxygen vacancy: Towards sensitive oxygen sensor

Jian Yao ^a ,
Jian Kong ^a ,
Lingwei Kong ^a ,
Xinrui Wang ^b ,
Wenying Shi ^{a, *,} ,
Chao Lu ^a

a.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
b.
Key Laboratory of Cosmetic, China National Light Industry, Beijing Technology and Business University, Beijing 100048, China

shiwy@mail.buct.edu.cn

Received Date: 10 September 2021
Revised Date: 14 October 2021
Accepted Date: 1 November 2021
Available Online: 7 November 2021

Figures(3)

Organic room temperature phosphorescent (ORTP) materials provide an exciting research direction for phosphorescent oxygen (O₂) sensors due to their high sensitivity and rapid response to O₂. However, most pure ORTP materials are tightly-packed aromatic compound crystals in a face-to-face manner, which largely prohibits effective O₂ diffusion for sensing. Thus, how to solve this contradiction still faces huge challenges. Here, the use of organic phosphorescent indicator carbon dots (CDs), inorganic matrix layered double hydroxides (LDHs) and polymers (PVA) successfully prepared an ultra-long RTP composite film whose phosphorescence decay intensity is linearly related to O₂ concentration. More importantly, the use of the abundant O₂ defects (Vo) on the surface of the inorganic matrix LDHs to adsorb O₂, which further accelerates the phosphorescence quenching of the thin film and improves the O₂ response. This strategy will provide the possibility to develop high-sensitivity phosphorescent O₂ sensors from a new perspective.
- Layered double hydroxides,
- Carbon dots,
- Nanocomposite thin film,
- Phosphorescence,
- Oxygen vacancy,
- Oxygen-sensing
1. [1]
  P. Jasinski, T. Suzuki, H. U. A.nderson, Sens. Actuator. B: Chem.95 (2003) 73-77. doi: 10.1016/S0925-4005(03)00407-6
2. [2]
  M. A. S. toeckel, M. Gobbi, S. Bonacchi, et al., Adv. Mater. 29 (2017) 1702469. doi: 10.1002/adma.201702469
3. [3]
  S. P. X. u, H. X. F. u, Y. Tian, et al., Angew. Chem. Int. Ed. 59 (2020) 17938-17943. doi: 10.1002/anie.202006745
4. [4]
  D. B. P. apkovsky, R. I. D. mitriev, Chem. Soc. Rev. 42 (2013) 8700-8732. doi: 10.1039/c3cs60131e
5. [5]
  P. Lehner, C. Staudinger, S. M. B. orisov, I. Klimant, Nat. Commun. 5 (2014) 1-6.
6. [6]
  M. Baei, A. A. P. eyghan, Z. Bagheri, Chin. Chem. Lett. 23 (2012) 965-968. doi: 10.1016/j.cclet.2012.06.027
7. [7]
  D. T. B. owers, M. L. T. anes, A. Das, et al., ACS Nano 8 (2014) 12080-12091. doi: 10.1021/nn504332j
8. [8]
  E. G. E. rmolina, R. T. K. uznetsova, Y. V. A. ksenova, et al., Sens. Actuator. B: Chem. 197 (2014) 206-210. doi: 10.1016/j.snb.2014.02.085
9. [9]
  B. Zhou, D. Yan, Sci. China Chem. 64 (2021) 509-510. doi: 10.1007/s11426-021-9956-y
10. [10]
  R. Gao, M. S. K. odaimati, D. Yan, Chem. Soc. Rev. 50 (2021) 5564-5589. doi: 10.1039/d0cs01463j
11. [11]
  G. Xiao, B. Zhou, X. Fang, D. Yan, Research 2021 (2021) 9862327.
12. [12]
  Z. Yin, M. Gu, H. Ma, et al., Angew. Chem. Int. Ed. 60 (2021) 2058-2063. doi: 10.1002/anie.202011830
13. [13]
  L. Q. B. ai, N. Xue, X. R. W. ang, W. Y. S. hi, C. Lu, Nanoscale 9 (2017) 6658-6664. doi: 10.1039/C6NR09648D
14. [14]
  C. R. W. ang, Y. Y. G. ong, W. Z. Y. uan, Y. M. Z. hang, Chin. Chem. Lett. 27 (2016) 1184-1192. doi: 10.1016/j.cclet.2016.05.026
15. [15]
  J. Yang, X. Zhen, B. Wang, et al., Nat. Commun. 9 (2018) 840. doi: 10.1071/mf17375
16. [16]
  Y. J. X. ie, Y. W. G. e, Q. Peng, et al., Adv. Mater. 29 (2017) 1606829. doi: 10.1002/adma.201606829
17. [17]
  Y. Wang, H. Gao, J. Yang, et al., Adv. Mater. 33 (2021) 2007811. doi: 10.1002/adma.202007811
18. [18]
  W. J. G. uo, Y. Z. C. hen, C. H. T. ung, L. Z. Wu, CCS Chem. 3 (2021) 1384-1392.
19. [19]
  P. Hartmann, W. Trettnak, Anal. Chem. 68 (1996) 2615-2620. doi: 10.1021/ac960008k
20. [20]
  M. S. K. won, D. Lee, S. Seo, J. Jung, J. Kim, Angew. Chem. Int. Ed. 53 (2014) 11177-11181. doi: 10.1002/anie.201404490
21. [21]
  S. Hirata, K. Totani, T. Yamashita, C. Adachi, M. Vacha, Nat. Mater. 13 (2014) 938. doi: 10.1038/nmat4081
22. [22]
  G. Zhang, G. M. P. almer, M. W. D. ewhirst, C. L. F. raser, Nat. Mater. 8 (2009) 747. doi: 10.1038/nmat2509
23. [23]
  S. Scypinski, L. C. L. ove, Anal. Chem. 56 (1984) 322-327. doi: 10.1021/ac00267a005
24. [24]
  C. A. M. itchell, R. W. G. urney, S. H. J. ang, B. Kahr, J. Am. Chem. Soc. 120 (1998) 9726-9727. doi: 10.1021/ja981963p
25. [25]
  G. J. Q. u, Y. P. Z. hang, X. Ma, Chin. Chem. Lett. 30 (2019) 1809-1814. doi: 10.1016/j.cclet.2019.07.042
26. [26]
  X. Wu, A. Selloni, M. Lazzeri, S. K. N. ayak, Phys. Rev. B 68 (2013) 241402.
27. [27]
  X. R. W. ang, H. M. C. heng, X. W. G. ao, et al., Chin. Chem. Lett. 30 (2019) 919-923. doi: 10.1016/j.cclet.2019.03.050
28. [28]
  H. Ma, R. Gao, D. Yan, J. Zhao, M. Wei, J. Mater. Chem. C 1 (2013) 4128-4137.
29. [29]
  D. Yan, J. Lu, L. Chen, et al., Chem. Commun. 46 (2010) 5912-5914. doi: 10.1039/c0cc00522c
30. [30]
  Y. H. D. eng, D. X. Z. hao, X. Chen, et al., Chem. Commun. 49 (2013) 5751-5753. doi: 10.1039/c3cc42600a
31. [31]
  J. Li, H. Z. C. ui, X. J. S. ong, et al., RSC Adv. 6 (2016) 92402-92410. doi: 10.1039/C6RA18783H
32. [32]
  T. Q. N. guyen, J. J. W. u, V. Doan, B. J. S. chwartz, S. H. T. olbert, Science 288 (2000) 652-656. doi: 10.1126/science.288.5466.652
33. [33]
  P. Ogilby, Chem. Soc. Rev. 39 (2010) 3181-3209. doi: 10.1039/b926014p
34. [34]
  Y. Feng, J. H. C. heng, L. Zhou, X. Zhou, H. Xiang, Analyst 137 (2012) 4885-4901. doi: 10.1039/c2an35907c
35. [35]
  L. Q. J. ing, B. F. X. in, F. L. Y. uan, et al., J. Phys. Chem. B 110 (2006) 17860-17865. doi: 10.1021/jp063148z
36. [36]
  L. Arda, J. Magn. Magn. Mater. 475 (2019) 493-501. doi: 10.1016/j.jmmm.2018.11.121
37. [37]
  M. Kong, Y. Z. L. i, X. Chen, et al., J. Am. Chem. Soc. 133 (2011) 16414-16417. doi: 10.1021/ja207826q
38. [38]
  Y. Nakaoka, Y. Nosaka, J. Photochem. Photobiol. A 110 (1997) 299-305. doi: 10.1016/S1010-6030(97)00208-6
39. [39]
  G. Qi, J. Xu, J. Su, et al., J. Am. Chem. Soc. 135 (2013) 6762-6765. doi: 10.1021/ja400757c
40. [40]
  W. Känzig, M. H. C. ohen, Phys. Rev. Lett. 3 (1959) 509-510.
41. [41]
  X. Ning, X. Cao, C. Li, et al., Nucl. Instrum. Meth. B 397 (2017) 75-81. doi: 10.1016/j.nimb.2017.02.038
42. [42]
  Y. Zhao, C. Z. L. i, X. H. L. iu, et al., Appl. Catal. B: Environ. 79 (2008) 208-215.
43. [43]
  J. M. C. osta-Fernández, A. Sanz-Medel, Anal. Chim. Acta 407 (2000) 61-69.
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