Citation: Sai-Sai Yan, Jin-Yun Wang, Zi-You Pan, Da-Sheng Zheng, Qian-Chong Zhang, Zhong-Ning Chen. Freezing the conductance of platinum(Ⅱ) complexes by quantum interference effect[J]. Chinese Chemical Letters, ;2022, 33(6): 3263-3266. doi: 10.1016/j.cclet.2021.10.092 shu

Freezing the conductance of platinum(Ⅱ) complexes by quantum interference effect

Sai-Sai Yan ^{a, b} ,
Jin-Yun Wang ^b ,
Zi-You Pan ^b ,
Da-Sheng Zheng ^{a, b} ,
Qian-Chong Zhang ^{b, c, *,} ,
Zhong-Ning Chen ^{b, c, *,}

a.
Fujian Normal University, Fuzhou 350007, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China

zhangqianchong@fjirsm.ac.cn

czn@fjirsm.ac.cn

Received Date: 8 October 2021
Revised Date: 23 October 2021
Accepted Date: 31 October 2021
Available Online: 7 November 2021

Figures(4)

Understanding the impact of substituents on the quantum interference effect at single molecule scale is of great importance for the design of molecular devices. In this work, three platinum(Ⅱ) complexes with –H, –NH₂ and –NO₂ groups on conductive backbones were designed and synthesized. Single-molecule conductance, which was measured using scanning tunnelling microscope break junction (STM-BJ) technique, demonstrated a conductance freeze phenomenon under the variation of substituents. Theoretical study revealed that, despite the electronic effect of the substituents shifting the energy level of molecular orbital, the quantum interference effect vanished the influence of electronic effect on the conductance and eventually leaded to the conductance freeze.
- Platinum(Ⅱ) complex,
- Electronic effect,
- Single-molecule conductance,
- Quantum interference,
- Magic ratio rule
1. [1]
  J. Liu, X. Huang, F. Wang, W. Hong, Acc. Chem. Res.52 (2019) 151-160. doi: 10.1021/acs.accounts.8b00429
2. [2]
  D. Xiang, X. Wang, C. Jia, T. Lee, X. Guo, Chem. Rev. 116 (2016) 4318-4440. doi: 10.1021/acs.chemrev.5b00680
3. [3]
  T.A. Su, M. Neupane, M.L. Steigerwald, L. Venkataraman, C. Nuckolls, Nat. Rev. Mater. 1 (2016) 16002. doi: 10.1038/natrevmats.2016.2
4. [4]
  M.H. Garner, H. Li, Y. Chen, et al., Nature558 (2018) 415-419. doi: 10.1038/s41586-018-0197-9
5. [5]
  S.J. Higgins, R.J. Nichols, Polyhedron140 (2018) 25-34. doi: 10.1016/j.poly.2017.10.022
6. [6]
  D.C. Milan, A. Vezzoli, I.J. Planje, P.J. Low, Dalton Trans. 47 (2018) 14125-14138. doi: 10.1039/c8dt02103a
7. [7]
  S. Rigaut, Dalton Trans. 42 (2013) 15859-15863. doi: 10.1039/c3dt51487k
8. [8]
  P. Duan, J. Liu, J.Y. Wang, et al., Sci. China Chem. 63 (2020) 467-474. doi: 10.1007/s11426-019-9692-3
9. [9]
  S. Sangtarash, C. Huang, H. Sadeghi, et al., J. Am. Chem. Soc. 137 (2015) 11425-11431. doi: 10.1021/jacs.5b06558
10. [10]
  Y. Geng, S. Sangtarash, C. Huang, et al., J. Am. Chem. Soc. 137 (2015) 4469-4476. doi: 10.1021/jacs.5b00335
11. [11]
  C.J. Lambert, S.X. Liu, Chem. Eur. J. 24 (2018) 4193-4201. doi: 10.1002/chem.201704488
12. [12]
  T. Markussen, R. Stadler, K.S. Thygesen, Nano Lett. 10 (2010) 4260-4265. doi: 10.1021/nl101688a
13. [13]
  T. Stuyver, S. Fias, F. De Proft, P. Geerlings, J. Phys. Chem. C119 (2015) 26390-26400. doi: 10.1021/acs.jpcc.5b10395
14. [14]
  F. Jiang, D.I. Trupp, N. Algethami, et al., Angew. Chem. Int. Ed. 58 (2019) 18987-18993. doi: 10.1002/anie.201909461
15. [15]
  X.S. Liu, S. Sangtarash, D. Reber, et al., Angew. Chem. Int. Ed. 56 (2017) 173-176. doi: 10.1002/anie.201609051
16. [16]
  R.L. Starr, T. Fu, E.A. Doud, et al., J. Am. Chem. Soc. 142 (2020) 7128-7133. doi: 10.1021/jacs.0c01466
17. [17]
  C. Wu, X. Qiao, C.M. Robertson, et al., Angew. Chem. Int. Ed. 59 (2020) 12029-12034. doi: 10.1002/anie.202002174
18. [18]
  H. Chen, Y. Chen, H. Zhang, et al., Chin. Chem. Lett. 33 (2022) 523–526. doi: 10.1016/j.cclet.2021.06.052
19. [19]
  Y. Tang, Y. Zhou, D. Zhou, et al., J. Am. Chem. Soc. 142 (2020) 19101-19109. doi: 10.1021/jacs.0c07348
20. [20]
  S. Zhen, P. Shen, J. Li, Z. Zhao, B.Z. Tang, Cell Rep. Phys. Sci. 2 (2021) 100364. doi: 10.1016/j.xcrp.2021.100364
21. [21]
  C. Tang, J. Zheng, Y. Ye, et al., iScience23 (2020) 100770. doi: 10.1016/j.isci.2019.100770
22. [22]
  P. Duan, K. Qu, J.Y. Wang, et al., Cell Rep. Phys. Sci. 2 (2021) 100342. doi: 10.1016/j.xcrp.2021.100342
23. [23]
  T.L. Schull, J.G. Kushmerick, C.H. Patterson, et al., J. Am. Chem. Soc. 125 (2003) 3202-3203. doi: 10.1021/ja029564o
24. [24]
  P. Duan, J. Liu, J.Y. Wang, et al., J. Mater. Chem. C7 (2019) 7259-7266. doi: 10.1039/c9tc02100k
25. [25]
  J. Liu, X. Zhao, J. Zheng, et al., Chem5 (2019) 390-401. doi: 10.1016/j.chempr.2018.11.002
26. [26]
  P. Moreno-García, M. Gulcur, D.Z. Manrique, et al., J. Am. Chem. Soc. 135 (2013) 12228-12240. doi: 10.1021/ja4015293
27. [27]
  C. Untiedt, A.I. Yanson, R. Grande, et al., Phys. Rev. B66 (2002) 085418. doi: 10.1103/PhysRevB.66.085418
28. [28]
  L.C. Chen, J. Zheng, J. Liu, et al., Small16 (2020) 2002808. doi: 10.1002/smll.202002808
29. [29]
  J.M. Soler, E. Artacho, J.D. Gale, et al., J. Phys. Condens. Matter14 (2002) 2745-2779. doi: 10.1088/0953-8984/14/11/302
30. [30]
  J. Taylor, H. Guo, J. Wang, Phys. Rev. B63 (2001) 245407. doi: 10.1103/PhysRevB.63.245407
31. [31]
  K. Stokbro, J. Taylor, M. Brandbyge, H. Guo, Ab-initio based Non-equiblibrium Green's Function Formalism for Calculating Electron Transport in Molecular Devices, Springer, Berlin, Heidelberg, 2005.
32. [32]
  C.J. Lambert, Chem. Soc. Rev. 44 (2015) 875-888. doi: 10.1039/C4CS00203B
33. [33]
  C.S. Wang, M.R. Bryce, J. Gigon, et al., J. Org. Chem. 73 (2008) 4810-4818. doi: 10.1021/jo800120n
34. [34]
  T.F. Zeng, Y. He, J. Appl. Phys. 124 (2018) 044305. doi: 10.1063/1.5026612
35. [35]
  D.Z. Manrique, C. Huang, M. Baghernejad, et al., Nat. Commun. 6 (2015) 6389. doi: 10.1038/ncomms7389
36. [36]
  H. Ozawa, M. Baghernejad, O.A. Al-Owaedi, et al., Chem. Eur. J. 22 (2016) 12732-12740. doi: 10.1002/chem.201600616
1. [1]
  Siwei Wang , Wei-Lei Zhou , Yong Chen . Cucurbituril and cyclodextrin co-confinement-based multilevel assembly for single-molecule phosphorescence resonance energy transfer behavior. Chinese Chemical Letters, 2024, 35(12): 110261-. doi: 10.1016/j.cclet.2024.110261
2. [2]
  Xinyi Luo , Ke Wang , Yingying Xue , Xiaobao Cao , Jianhua Zhou , Jiasi Wang . Digital PCR-free technologies for absolute quantitation of nucleic acids at single-molecule level. Chinese Chemical Letters, 2025, 36(2): 109924-. doi: 10.1016/j.cclet.2024.109924
3. [3]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
4. [4]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
5. [5]
  Junchen Peng , Xue Yin , Dandan Dong , Zhongyuan Guo , Qinqin Wang , Minmin Liu , Fei He , Bin Dai , Chaofeng Huang . Promotion effect of epoxy group neighboring single-atom Cu site on acetylene hydrochlorination. Chinese Chemical Letters, 2024, 35(6): 109508-. doi: 10.1016/j.cclet.2024.109508
6. [6]
  Min Chen , Boyu Peng , Xuyun Guo , Ye Zhu , Hanying Li . Polyethylene interfacial dielectric layer for organic semiconductor single crystal based field-effect transistors. Chinese Chemical Letters, 2024, 35(4): 109051-. doi: 10.1016/j.cclet.2023.109051
7. [7]
  Jianing He , Xiao Wang , Zijian Wang , Ruize Jiang , Ke Wang , Rui Zhang , Huilin Wang , Baokang Geng , Hongyi Gao , Shuyan Song , Hongjie Zhang . Investigation on Cu promotion effect on Ce-based solid solution-anchored Rh single atoms for three-way catalysis. Chinese Chemical Letters, 2025, 36(2): 109640-. doi: 10.1016/j.cclet.2024.109640
8. [8]
  Kexin Yin , Jingren Yang , Yanwei Li , Qian Li , Xing Xu . Metal-free diatomaceous carbon-based catalyst for ultrafast and anti-interference Fenton-like oxidation. Chinese Chemical Letters, 2024, 35(12): 109847-. doi: 10.1016/j.cclet.2024.109847
9. [9]
  Bingbing Shi , Yuchun Wang , Yi Zhou , Xing-Xing Zhao , Yizhou Li , Nuoqian Yan , Wen-Juan Qu , Qi Lin , Tai-Bao Wei . A supramolecular oligo[2]rotaxane constructed by orthogonal platinum(Ⅱ) metallacycle and pillar[5]arene-based host–guest interactions. Chinese Chemical Letters, 2024, 35(10): 109540-. doi: 10.1016/j.cclet.2024.109540
10. [10]
  Pingping HAO , Fangfang LI , Yawen WANG , Houfen LI , Xiao ZHANG , Rui LI , Lei WANG , Jianxin LIU . Hydrogen production performance of the non-platinum-based MoS₂/CuS cathode in microbial electrolytic cells. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1811-1824. doi: 10.11862/CJIC.20240054
11. [11]
  Zhenyang Lin . A classification scheme for inorganic cluster compounds based on their electronic structures and bonding characteristics. Chinese Journal of Structural Chemistry, 2024, 43(5): 100254-100254. doi: 10.1016/j.cjsc.2024.100254
12. [12]
  Hanqing Zhang , Xiaoxia Wang , Chen Chen , Xianfeng Yang , Chungli Dong , Yucheng Huang , Xiaoliang Zhao , Dongjiang Yang . Selective CO2-to-formic acid electrochemical conversion by modulating electronic environment of copper phthalocyanine with defective graphene. Chinese Journal of Structural Chemistry, 2023, 42(10): 100089-100089. doi: 10.1016/j.cjsc.2023.100089
13. [13]
  Jianmei Han , Peng Wang , Hua Zhang , Ning Song , Xuguang An , Baojuan Xi , Shenglin Xiong . Performance optimization of chalcogenide catalytic materials in lithium-sulfur batteries: Structural and electronic engineering. Chinese Chemical Letters, 2024, 35(7): 109543-. doi: 10.1016/j.cclet.2024.109543
14. [14]
  Saadullah Khattak , Hong-Tao Xu , Jianliang Shen . Bio-electronic bandage: Self-powered performances to accelerate intestinal wound healing. Chinese Chemical Letters, 2024, 35(12): 110210-. doi: 10.1016/j.cclet.2024.110210
15. [15]
  Xinyu Tian , Jiaxiang Guo , Zeyi Li , Shihou Sheng , Tianyu Zhang , Xianfei Li , Chuandong Dou . Control over electronic structures of organic diradicaloids via precise B/O-heterocycle fusion. Chinese Chemical Letters, 2025, 36(1): 110174-. doi: 10.1016/j.cclet.2024.110174
16. [16]
  Hao Deng , Yuxin Hui , Chao Zhang , Qi Zhou , Qiang Li , Hao Du , Derek Hao , Guoxiang Yang , Qi Wang . MXene−derived quantum dots based photocatalysts: Synthesis, application, prospects, and challenges. Chinese Chemical Letters, 2024, 35(6): 109078-. doi: 10.1016/j.cclet.2023.109078
17. [17]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
18. [18]
  Chao Ma , Cong Lin , Jian Li . MicroED as a powerful technique for the structure determination of complex porous materials. Chinese Journal of Structural Chemistry, 2024, 43(3): 100209-100209. doi: 10.1016/j.cjsc.2023.100209
19. [19]
  Mengjuan Sun , Muye Zhou , Yifang Xiao , Hailei Tang , Jinhua Chen , Ruitao Zhang , Chunjiayu Li , Qi Ya , Qian Chen , Jiasheng Tu , Qiyue Wang , Chunmeng Sun . Reversibly size-switchable polyion complex micelles for antiangiogenic cancer therapy. Chinese Chemical Letters, 2024, 35(7): 109110-. doi: 10.1016/j.cclet.2023.109110
20. [20]
  Yuanjin Chen , Xianghui Shi , Dajiang Huang , Junnian Wei , Zhenfeng Xi . Synthesis and reactivity of cobalt dinitrogen complex supported by nonsymmetrical pincer ligand. Chinese Chemical Letters, 2024, 35(7): 109292-. doi: 10.1016/j.cclet.2023.109292

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(506)
HTML views(38)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142