Citation: Qingqing Guo, Nanzhu Li, Qian Zou, Jiage Jia, Yifan Wei, Songsong Bao, Limin Zheng. In situ thermal-induced generation of {Ag⁰Ag^Ⅰ} dimer within Co-Ag phosphonates[J]. Chinese Chemical Letters, ;2022, 33(6): 3259-3262. doi: 10.1016/j.cclet.2021.10.091 shu

In situ thermal-induced generation of {Ag⁰Ag^Ⅰ} dimer within Co-Ag phosphonates

State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China

baososo@nju.edu.cn

Received Date: 4 August 2021
Revised Date: 21 October 2021
Accepted Date: 31 October 2021
Available Online: 6 November 2021

Figures(4)

The thermal decomposition of AgNO₃ is known to produce metallic Ag, but single-atomic dispersion is hard to achieve instead of the aggregation state of nanoparticles. Herein, we develop an efficient approach to thermally generate and stabilize single Ag atoms via the coordination effect. Two desired Co-Ag phosphonates [Ag₂^ⅠCo₂^Ⅲ(notpH₃)₂(NO₃)]X [X = NO₃⁻ (1) or ClO₄⁻ (2)] were synthesized by solid-phase grinding method or solution crystallization. Both crystal structures reveal slightly different packing arrangements of various lattice anions and identical one-dimensional (1-D) coordination chains, formed in each case by the coordination of Ag(Ⅰ) to the metalloligand Co(notpH₃) and NO₃⁻ anion. The number of Ag(Ⅰ) ions connected to each NO₃⁻ anion reduces from 5 in bulk AgNO₃ to 2 in compounds 1 and 2, leading to the AgNO₃ component stepwise decomposition at a lower temperature (< 300 ℃). During the thermal decomposition, the changes of supermolecular structures and Ag oxidation states were monitored by PXRD, IR and XAFS measurements. The most interesting finding is that 1 and 2 can retain chain structures and harvest Ag(0) atoms in the chain by controlling decomposition temperatures (220 ℃ for 1 and 254 ℃ for 2).
- Metallic silver,
- Thermal decomposition,
- Metal phosphonate,
- Atomic dispersion,
- Magnetism
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沈阳化工大学材料科学与工程学院沈阳 110142

In situ thermal-induced generation of {Ag0AgⅠ} dimer within Co-Ag phosphonates

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通讯作者: 陈斌, bchen63@163.com

In situ thermal-induced generation of {Ag⁰Ag^Ⅰ} dimer within Co-Ag phosphonates