Citation: Ping Yan, Qin Ren, Fengyi Zhong, Jieyuan Li, Fusheng Wei, Jianjun Li, Xian Shi, Fan Dong. Self-doped Br in Bi₅O₇Br ultrathin nanotubes: Efficient photocatalytic NO purification and mechanism investigation[J]. Chinese Chemical Letters, ;2022, 33(6): 3161-3166. doi: 10.1016/j.cclet.2021.10.082 shu

Self-doped Br in Bi₅O₇Br ultrathin nanotubes: Efficient photocatalytic NO purification and mechanism investigation

Ping Yan ^{a, b} ,
Qin Ren ^b ,
Fengyi Zhong ^b ,
Jieyuan Li ^b ,
Fusheng Wei ^a ,
Jianjun Li ^{a, *,} ,
Xian Shi ^{b, *,} ,
Fan Dong ^{b, c}

a.
College of Architecture and Environment, Sichuan University, Chengdu 610065, China
b.
Yangtze Delta Region Institute (Huzhou) & Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Huzhou 313001, China
c.
State Centre for International Cooperation on Designer Low carbon and Environmental Materials (CDLCEM), School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China

jjli@scu.edu.cn

shixian930501@163.com

Received Date: 28 June 2021
Revised Date: 17 September 2021
Accepted Date: 27 October 2021
Available Online: 2 November 2021

Figures(6)

Bismuth-rich Bi₅O₇Br is a promising photocatalyst for pollutant removal owing to its stability and appropriate band structure in comparison with bismuth oxybromide. However, bulk-phase Bi₅O₇Br suffers from poor light absorption and high charge recombination rates resulting in poor activity. Elemental doping is a powerful strategy to enhance photocatalytic activity. In this study, we prepared a series of Br auto-doped ultrathin Bi₅O₇Br nanotubes and explored the effect of Br doping on photocatalytic NO removal. The optimal doping content was determined via a photocatalytic NO removal experiment, which revealed the optimal ratio of Bi and Br was approximately 3:1. In situ diffuse reflectance infrared Fourier transform spectroscopy (In situ DRIFT) and density functional theory (DFT) studies revealed that NO removal mechanism catalyzed by Br doped Bi₅O₇Br. Our work presents a new strategy for the enhancement of photocatalytic pollutant degradation by bismuth oxyhalide photocatalysts.
- Bi₅O₇Br,
- Br auto-doped,
- Photocatalytic no removal,
- DFT,
- In situ DRIFT
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Self-doped Br in Bi₅O₇Br ultrathin nanotubes: Efficient photocatalytic NO purification and mechanism investigation