Citation: Lei Xu, Xinyue Cui, Jianbo Liao, Yufeng Liu, Baoyi Jiang, Junfeng Niu. Synchronous mineralization of three aqueous non-steroidal anti-inflammatory drugs in electrochemical advanced oxidation process[J]. Chinese Chemical Letters, ;2022, 33(8): 3701-3704. doi: 10.1016/j.cclet.2021.10.065 shu

Synchronous mineralization of three aqueous non-steroidal anti-inflammatory drugs in electrochemical advanced oxidation process

Research Center for Eco-Environmental Engineering, Dongguan University of Technology, Dongguan 523808, China

niujf@dgut.edu.cn

Received Date: 10 September 2021
Revised Date: 3 October 2021
Accepted Date: 22 October 2021
Available Online: 29 October 2021

Figures(4)

Electrochemical degradation performances of three non-steroidal anti-inflammatory drugs (NSAIDs), acetaminophen (ACT), aspirin (ASP) and ibuprofen (IBP), were investigated and compared in their alone and mixture conditions using Ti/SnO₂-Sb/La-PbO₂. The pseudo-first-order degradation kinetics (k) order was k_IBP-A (0.110 min⁻¹) > k_ASP-A (0.092 min⁻¹) > k_ACT-A (0.066 min⁻¹) in their alone condition, while that was k_ACT_-_M (0.088 min⁻¹) > k_ASP_-_M (0.063 min⁻¹) > k_IBP_-_M (0.057 min⁻¹) in their mixture condition. The ^•OH apparent production rate constant of 5.23 mmol L⁻¹ min⁻¹ m⁻² and an electrical energy per order (E_EO) value of 6.55 Wh/L could ensure the synchronous degradation of the NSAIDs mixture. The mineralization efficiency of NSAIDs mixture was 86.9% at 240 min with a mineralization current efficiency of 1.67%. Acetic acid and oxalic acid were the main products in the mineralization process for the both conditions. In the mixture condition, there were higher k values at lower initial concentrations and higher current density, while the presence of carbonate and humic acid inhibited their degradation. The results indicated electrochemical advanced oxidation process can effectively and synchronously mineralize NSAIDs mixture in wastewater.
- Electrochemical advanced oxidation,
- Non-steroidal anti-inflammatory drugs,
- Degradation kinetics,
- Synchronous mineralization,
- Wastewater
1. [1]
  A. David, A. Lange, A. Abdul-Sada, C.R. Tyler, E.M. Hill, Environ. Sci. Technol.51 (2017) 616–624. doi: 10.1021/acs.est.6b04365
2. [2]
  Y. Yong, L. Wu, A.C. Chang, Sci. Total Environ. 442 (2013) 310–316. doi: 10.1016/j.scitotenv.2012.10.001
3. [3]
  E.D. Nelson, H. Do, R.S. Lewis, S.A. Ca Rr, Environ. Sci. Technol. 45 (2011) 1228–1234. doi: 10.1021/es102452f
4. [4]
  N. Veldhoen, R.C. Skirrow, L. Brown, G.V. Aggelen, C.C. Helbing, Environ. Sci. Technol. 48 (2014) 10439–10447. doi: 10.1021/es502539g
5. [5]
  W. Li, G.G. Ying, J.L. Zhao, et al., Sci. Total Environ. 408 (2010) 3139–3147. doi: 10.1016/j.scitotenv.2010.04.047
6. [6]
  M. Cleuvers, Ecotoxicol. Environ. Saf. 59 (2004) 309–315. doi: 10.1016/S0147-6513(03)00141-6
7. [7]
  C. Gadipelly, A. Pérez-González, G.D. Yadav, et al., Ind. Eng. Chem. Res. 53 (2014) 11571–11592. doi: 10.1021/ie501210j
8. [8]
  H. Liang, P. Hua, Y. Zhou, Z. Fu, J. Niu, Chin. Chem. Lett. 30 (2019) 2245–2248. doi: 10.1016/j.cclet.2019.05.046
9. [9]
  Y. Wang, C. Zhou, J. Wu, J. Niu, Chin. Chem. Lett. 31 (2020) 2673–2677. doi: 10.1016/j.cclet.2020.03.073
10. [10]
  Y.B. Liu, G.D. Gao, C.D. Vecitis, Acc. Chem. Res. 53 (2020) 2892–2902. doi: 10.1021/acs.accounts.0c00544
11. [11]
  J. Li, Y. Li, Z. Xiong, G. Yao, B. Lai, Chin. Chem. Lett. 30 (2019) 2139–2146. doi: 10.1016/j.cclet.2019.04.057
12. [12]
  M. Villanueva-Rodríguez, R. Bello-Mendoza, A. Hernández-Ramírez, E.J. Ruiz-Ruiz, Environ. Technol. 40 (2018) 1–35.
13. [13]
  W. Liu, W. Zhang, M.S. Du, et al., Chin. Chem. Lett. 30 (2019) 2177–2180. doi: 10.1016/j.cclet.2019.07.050
14. [14]
  L. Chen, H.D. Ji, J.J. Qi, et al., Chem. Eng. J. 406 (2021) 126877. doi: 10.1016/j.cej.2020.126877
15. [15]
  F.Q. Liu, Y.B. Liu, Q.F. Yao, et al., Environ. Sci. Technol. 54 (2020) 5913–5921. doi: 10.1021/acs.est.0c00427
16. [16]
  C. Wang, Y. Yu, L. Yin, J. Niu, L.A. Hou, Chemosphere 163 (2016) 584–591. doi: 10.1016/j.chemosphere.2016.08.057
17. [17]
  L. Xu, X. Ma, J. Niu, J. Chen, C. Zhou, J. Hazard. Mater. 379 (2019) 120692. doi: 10.1016/j.jhazmat.2019.05.085
18. [18]
  L. Xu, S. Tang, D. Li, X. Ma, J. Niu, Sep. Purif. Technol. 265 (2021) 118489. doi: 10.1016/j.seppur.2021.118489
19. [19]
  L. Xu, J. Niu, H. Xie, et al., J. Hazard. Mater. 402 (2021) 123530. doi: 10.1016/j.jhazmat.2020.123530
20. [20]
  J.J. Qi, J.Z. Liu, F.B. Sun, et al., Chin. Chem. Lett. 32 (2021) 1814–1818. doi: 10.1016/j.cclet.2020.11.026
21. [21]
  Y.B. Liu, F.Q. Liu, N. Ding, et al., Chin. Chem. Lett. 31 (2021) 2539–2548.
22. [22]
  T. Liu, K. Yin, C. Liu, et al., Water Res. 147 (2018) 204–213.
23. [23]
  F.L. Liu, Z.B. Guo, Y.F. Zhao, H. Cao, S.N. Zhu, Environ. Sci. Pollut. Res. 22 (2015) 15772–15780. doi: 10.1007/s11356-015-4715-0
24. [24]
  M. Sayed, M. Ismail, S. Khan, S. Tabassum, H.M. Khan, Environ. Technol. 37 (2016) 590–602. doi: 10.1080/09593330.2015.1075597
1. [1]
  Huijuan Li , Zhu Wang , Jiagen Geng , Ruiping Song , Xiaoyin Liu , Chaochen Fu , Si Li . Current advances in UV-based advanced oxidation processes for the abatement of fluoroquinolone antibiotics in wastewater. Chinese Chemical Letters, 2025, 36(4): 110138-. doi: 10.1016/j.cclet.2024.110138
2. [2]
  Fengrui Yang , Debing Wang , Xinying Zhang , Jie Zhang , Zhichao Wu , Qiaoying Wang . Synergistic effects of peroxydisulfate on UV/O₃ process for tetracycline degradation: Mechanism and pathways. Chinese Chemical Letters, 2024, 35(10): 109599-. doi: 10.1016/j.cclet.2024.109599
3. [3]
  Jinshuai Zheng , Junfeng Niu , Crispin Halsall , Yadi Guo , Peng Zhang , Linke Ge . New insights into transformation mechanisms for sulfate and chlorine radical-mediated degradation of sulfonamide and fluoroquinolone antibiotics. Chinese Chemical Letters, 2025, 36(5): 110202-. doi: 10.1016/j.cclet.2024.110202
4. [4]
  Jiqing Liu , Qi Dang , Liting Wang , Dejin Wang , Liang Tang . Applications of flexible electrochemical electrodes in wastewater treatment: A review. Chinese Chemical Letters, 2024, 35(8): 109277-. doi: 10.1016/j.cclet.2023.109277
5. [5]
  Dan Shao , Yujing Lyu , Chengyuan Liu , Hao Wang , Ning Ma , Hao Xu , Wei Yan , Xiaohua Jia , Haojie Song . Attracting magnetic BDD particles onto Ti/RuO₂-IrO₂ by using a magnet: A novel 2.5-dimensional electrode for electrochemical oxidation wastewater treatment. Chinese Chemical Letters, 2025, 36(6): 110641-. doi: 10.1016/j.cclet.2024.110641
6. [6]
  Yi Zhang , Biao Wang , Chao Hu , Muhammad Humayun , Yaping Huang , Yulin Cao , Mosaad Negem , Yigang Ding , Chundong Wang . Fe–Ni–F electrocatalyst for enhancing reaction kinetics of water oxidation. Chinese Journal of Structural Chemistry, 2024, 43(2): 100243-100243. doi: 10.1016/j.cjsc.2024.100243
7. [7]
  Liangbo Zhang , Jun Cheng , Yahui Shi , Kunjie Hou , Qi An , Jingyi Li , Baohui Cui , Fei Chen . Efficient removal of tetracycline hydrochloride by ZnO/HNTs composites under visible light: Kinetics, degradation pathways and mechanism. Chinese Chemical Letters, 2025, 36(7): 110400-. doi: 10.1016/j.cclet.2024.110400
8. [8]
  Xue Zhao , Mengshan Chen , Dan Wang , Haoran Zhang , Guangzhi Hu , Yingtang Zhou . Ultrafine nano-copper derived from dopamine polymerization & synchronous adsorption achieve electrochemical purification of nitrate to ammonia in complex water environments. Chinese Chemical Letters, 2024, 35(8): 109327-. doi: 10.1016/j.cclet.2023.109327
9. [9]
  Mengyu Chen , Qinglin Zhou , Tianyun Qin , Ningyao Sun , Yuxi Chen , Yuwei Gong , Xingyi Li , Jinsong Liu . An ionic liquid-reinforced gelatin hydrogel with strong adhesion, antibacterial and anti-inflammatory properties for treating oral ulcers. Chinese Chemical Letters, 2025, 36(7): 110441-. doi: 10.1016/j.cclet.2024.110441
10. [10]
  Chenshi Lin , Chao Teng , Bingbing Li , Wei He . Anti-inflammatory drug-assisted microRNA gene therapy for effectively improving pulmonary hemodynamics. Chinese Chemical Letters, 2025, 36(7): 110450-. doi: 10.1016/j.cclet.2024.110450
11. [11]
  Juan He , Jiao-Xian Du , Meng Wang , Xiao-Dong Luo , Tao Feng . Irpexlactones A and B, a pair of ring-rearranged tremulane sesquiterpenoids from the basidiomycete Irpex lacteus and their anti-inflammatory activity. Chinese Chemical Letters, 2025, 36(10): 110769-. doi: 10.1016/j.cclet.2024.110769
12. [12]
  Chong Liu , Nanthi Bolan , Anushka Upamali Rajapaksha , Hailong Wang , Paramasivan Balasubramanian , Pengyan Zhang , Xuan Cuong Nguyen , Fayong Li . Critical review of biochar for the removal of emerging inorganic pollutants from wastewater. Chinese Chemical Letters, 2025, 36(2): 109960-. doi: 10.1016/j.cclet.2024.109960
13. [13]
  Ping Wang , Chunmao Chen , Hongwei Ren , Erhong Duan . A review of carbon dots in synthesis strategies, photoluminescence mechanisms, and applications in wastewater treatment. Chinese Chemical Letters, 2025, 36(9): 110725-. doi: 10.1016/j.cclet.2024.110725
14. [14]
  Xiaoyao Ma , Jinling Zhang , Ge Fang , He Gao , Jie Gao , Li Fu , Yuanyuan Hou , Gang Bai . Förster resonance energy transfer reveals phillygenin and swertiamarin concurrently target AKT on different binding domains to increase the anti-inflammatory effect. Chinese Chemical Letters, 2024, 35(5): 108823-. doi: 10.1016/j.cclet.2023.108823
15. [15]
  Wenjia Wang , Xingyue He , Xiaojie Wang , Tiantian Zhao , Osamu Muraoka , Genzoh Tanabe , Weijia Xie , Tianjiao Zhou , Lei Xing , Qingri Jin , Hulin Jiang . Glutathione-depleted cyclodextrin pseudo-polyrotaxane nanoparticles for anti-inflammatory oxaliplatin (Ⅳ) prodrug delivery and enhanced colorectal cancer therapy. Chinese Chemical Letters, 2024, 35(4): 108656-. doi: 10.1016/j.cclet.2023.108656
16. [16]
  Xiongbo Song , Jinwen Xiao , Juan Wu , Li Sun , Long Chen . Decellularized amniotic membrane promotes the anti-inflammatory response of macrophages via PI3K/AKT/HIF-1α pathway. Chinese Chemical Letters, 2025, 36(1): 109844-. doi: 10.1016/j.cclet.2024.109844
17. [17]
  Yang Yang , Jing-Li Luo , Xian-Zhu Fu . Water-oxidation intermediates enabling electrochemical propylene epoxidation. Chinese Journal of Structural Chemistry, 2024, 43(5): 100269-100269. doi: 10.1016/j.cjsc.2024.100269
18. [18]
  Zonglin Li , Shihua Zou , Zining Wang , Georgeta Postole , Liang Hu , Hongying Zhao . Machine learning in electrochemical oxidation process: A mini-review. Chinese Chemical Letters, 2025, 36(8): 110526-. doi: 10.1016/j.cclet.2024.110526
19. [19]
  Jian Peng , Yue Jiang , Shuangyu Wu , Yanran Cheng , Jingyu Liang , Yixin Wang , Zhuo Li , Sijie Lin . A nonradical oxidation process initiated by Ti-peroxo complex showed high specificity toward the degradation of tetracycline antibiotics. Chinese Chemical Letters, 2024, 35(5): 108903-. doi: 10.1016/j.cclet.2023.108903
20. [20]
  Ruonan Guo , Heng Zhang , Changsheng Guo , Ningqing Lv , Beidou Xi , Jian Xu . Degradation of neonicotinoids with different molecular structures in heterogeneous peroxymonosulfate activation system through different oxidation pathways. Chinese Chemical Letters, 2024, 35(9): 109413-. doi: 10.1016/j.cclet.2023.109413

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(1362)
HTML views(51)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142