Citation: Tiantian Si, Xiaofeng Lu, Haixia Zhang, Shuai Wang, Xiaojing Liang, Yong Guo. Two-dimensional MOF Cu-BDC nanosheets/ILs@silica core-shell composites as mixed-mode stationary phase for high performance liquid chromatography[J]. Chinese Chemical Letters, ;2022, 33(8): 3869-3872. doi: 10.1016/j.cclet.2021.10.048 shu

Two-dimensional MOF Cu-BDC nanosheets/ILs@silica core-shell composites as mixed-mode stationary phase for high performance liquid chromatography

Tiantian Si ^{a, c} ,
Xiaofeng Lu ^a ,
Haixia Zhang ^b ,
Shuai Wang ^a ,
Xiaojing Liang ^{a, *,} ,
Yong Guo ^{a, *,}

a.
CAS Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
b.
State Key Laboratory of Applied Organic Chemistry and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China

xjliang@licp.cas.cn

guoyong@licp.cas.cn

Received Date: 21 July 2021
Revised Date: 8 September 2021
Accepted Date: 17 October 2021
Available Online: 23 October 2021

Figures(4)

Here, silica microspheres were decorated with two-dimensional metal–organic frameworks (2D MOFs) nanosheets and ionic liquids, and evaluated as the mixed-mode stationary phase for chromatographic separation. The ionic liquids were used to assist the synthesis of 2D MOFs nanosheets, and also acted as adhesives among the nanosheets and silica. In contrast with the 2D MOFs-based column without ionic liquids and commercial columns, the prepared column exhibited enhanced chromatographic separation performance for partially hydrophilic compounds such as alkaloids, sulfonamides and antibiotics, etc. In addition to excellent chromatographic repeatability and stability, it has also been verified that the composites could be easily and repeatedly prepared. The relative standard deviation of the retention time of the same type of analyte between the three batches of materials was ranging from 0.21% to 1.7%. In short, these results indicated that the synthesized composites were promising separation material for liquid chromatography, which made it possible to broaden the application of 2D MOFs in the field of chromatography.
- 2D MOF composites,
- Chromatographic separation,
- Liquid chromatography,
- Mixed-mode,
- Stationary phase
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