Citation: Zhongning Yu, Lu Huang, Zhuomin Zhang, Gongke Li. Magnetic Ti₃C₂T_x/Fe₃O₄/Ag substrate for rapid quantification of trace sulfonamides in aquatic products by surface enhanced Raman spectroscopy[J]. Chinese Chemical Letters, ;2022, 33(8): 3853-3858. doi: 10.1016/j.cclet.2021.10.045 shu

Magnetic Ti₃C₂T_x/Fe₃O₄/Ag substrate for rapid quantification of trace sulfonamides in aquatic products by surface enhanced Raman spectroscopy

School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China

zzm@mail.sysu.edu.cn

cesgkl@mail.sysu.edu.cn

Received Date: 15 August 2021
Revised Date: 5 September 2021
Accepted Date: 17 October 2021
Available Online: 23 October 2021

Figures(3)

Surface-enhanced Raman scattering (SERS) spectroscopy has been employed as a rapid analysis technology for food security inspection recently. Nowadays, it is still a great challenge to rapidly quantify multiple trace antibiotics potentially abused in aquaculture industry. In this work, a magnetic Ti₃C₂T_x/Fe₃O₄/Ag substrate was prepared for the development of a reliable rapid SERS quantification method for multiple trace sulfonamides in aquatic products. This magnetic substrate had good uniformity, reproducibility, stability and SERS activity. Moreover, this substrate could integrate the magnetic separation-enrichment and matrix clean-up without cross contamination, which endowed it with good selectivity and anti-interference capability during real sample analysis. The electromagnetic enhancement and chemical enhancement mechanism of this magnetic substrate were studied in detail to reveal its good separation-enrichment performance and SERS activity. Finally, a rapid SERS quantification method was established and practically applied for trace phthalic sulfathiazole (PST) and silver sulfadiazine (SSD) in aquatic products by using Ti₃C₂T_x/Fe₃O₄/Ag magnetic substrates. Trace PST and SSD could be actually detected and quantified as 55.9 µg/kg and 64.0 µg/kg in aquatic products, respectively. Good recoveries of 83.9%–116% with relative standard deviations (RSDs) of 0.5%–3.2% for PST and 80.2%–102% with RSDs of 1.3%–5.8% for SSD were obtained. This work proposed an efficient and reliable method for rapid quantification of trace multiple sulfonamides in complex aquatic samples during food security inspection.
- Magnetic substrate,
- Ti₃C₂T_x/Fe₃O₄/Ag,
- Rapid SERS quantification,
- Trace sulfonamides,
- Aquatic samples
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Magnetic Ti3C2Tx/Fe3O4/Ag substrate for rapid quantification of trace sulfonamides in aquatic products by surface enhanced Raman spectroscopy

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通讯作者: 陈斌, bchen63@163.com

Magnetic Ti₃C₂T_x/Fe₃O₄/Ag substrate for rapid quantification of trace sulfonamides in aquatic products by surface enhanced Raman spectroscopy