Citation: Jieying Hu, Hu Zhang, Zihao Feng, Qian-Ru Luo, Can-Min Wu, Yuan-Hui Zhong, Jian-Rong Li, Lai-Hon Chung, Wei-Ming Liao, Jun He. Flexible side arms of ditopic linker as effective tools to boost proton conductivity of Ni₈-pyrazolate metal-organic framework[J]. Chinese Chemical Letters, ;2022, 33(6): 3227-3230. doi: 10.1016/j.cclet.2021.10.042 shu

Flexible side arms of ditopic linker as effective tools to boost proton conductivity of Ni₈-pyrazolate metal-organic framework

School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China

laihonchung@gdut.edu.cn

junhe@gdut.edu.cn

Received Date: 18 September 2021
Revised Date: 9 October 2021
Accepted Date: 15 October 2021
Available Online: 22 October 2021

Figures(4)

Two primitive metal-organic frameworks (MOFs), NiL1 and NiL2, based on Ni₈O₆-cluster and ditopic pyrazolate linkers, L1 (with rigid alkyne arms) and L2 (with flexible alkyne chains), were prepared. The proton conductivities of these MOFs in pristine form and imidazole-encapsulated forms, Im@NiL1 and Im@NiL2, were measured and compared. Upon introduction of imidazole molecules, the proton conductivity could be increased by 3 to 5 orders of magnitude and reached as high as 1.72 × 10⁻² S/cm (at 98% RH and 80 ℃). Also, whether imidazole molecules were introduced or not, Ni₈O₆-based MOFs with L2 in general gave better proton conductivity than those with L1 signifying that flexible side arms indeed assist proton conduction probably via establishment of efficient proton-conducting channels along with formation of highly ordered domains of water/imidazole molecules within the network cavities. Beyond the active Ni₈O₆-cluster, tuning flexibility of linker pendants serves as an alternative approach to regulate/modulate the proton conductivity of MOFs.
- Proton conductivity,
- Metal-organic framework,
- Pyrazolate linkers,
- Nickel-oxide cluster,
- Imidazole encapsulation
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Flexible side arms of ditopic linker as effective tools to boost proton conductivity of Ni8-pyrazolate metal-organic framework

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通讯作者: 陈斌, bchen63@163.com

Flexible side arms of ditopic linker as effective tools to boost proton conductivity of Ni₈-pyrazolate metal-organic framework