Citation: Huimin Wu, Peibo Gao, Jinglin Mu, Zhichao Miao, Pengfei Zhou, Tong Zhou, Jin Zhou. Matryoshka-type carbon-stabilized hollow Si spheres as an advanced anode material for lithium-ion batteries[J]. Chinese Chemical Letters, ;2022, 33(6): 3236-3240. doi: 10.1016/j.cclet.2021.10.039 shu

Matryoshka-type carbon-stabilized hollow Si spheres as an advanced anode material for lithium-ion batteries

Huimin Wu ^a ,
Peibo Gao ^{b, *,} ,
Jinglin Mu ^a ,
Zhichao Miao ^a ,
Pengfei Zhou ^a ,
Tong Zhou ^b ,
Jin Zhou ^{a, *,}

a.
School of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo 255049, China
b.
School of Physics and Optoelectronic Engineering, Shandong University of Technology, Zibo 255049, China

pbgao@sdut.edu.cn

zhoujin@sdut.edu.cn

Received Date: 22 August 2021
Revised Date: 26 September 2021
Accepted Date: 15 October 2021
Available Online: 22 October 2021

Figures(5)

Silicon (Si) is regarded as the potential anode for lithium-ion batteries (LIBs), due to the remarkable theoretical specific capacity and low voltage plateau. However, the rapid capacity decay resulting from volume variation and slow electron/ion transportation of Si limit its practical application. Here, matryoshka-type carbon-stabilized hollow silicon spheres (Si/C/Si/C) are synthesized by an aluminothermic reduction and calcination process. The Si/C/Si/C anode materials prepared at 500 ℃ (Si/C/Si/C-500) exhibit unique structures, in which amorphous region and porous structure are preserved in the Si layers. The anode based on Si/C/Si/C-500 displays an initial specific capacity of 2792 mAh/g at a current density of 100 mA/g. At 1000 mA/g, this anode retains a reversible capacity of 1673 mAh/g, 86.9% of the initial capacity after 200 cycles. Such synthetic strategy can be employed to fabricate other high-capacity anode materials with large volume variation during charge/discharge process
- Lithiun-ion battery,
- Hollow Si,
- Matryoshka structure,
- Anode,
- Molten salts
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