Citation: Yongle Guo, Lu Feng, Yuefeng Liu, Zhongkui Zhao. Cu-embedded porous Al₂O₃ bifunctional catalyst derived from metal-organic framework for syngas-to-dimethyl ether[J]. Chinese Chemical Letters, ;2022, 33(6): 2906-2910. doi: 10.1016/j.cclet.2021.10.031 shu

Cu-embedded porous Al₂O₃ bifunctional catalyst derived from metal-organic framework for syngas-to-dimethyl ether

Yongle Guo ^{a, 1} ,
Lu Feng ^{b, c, 1} ,
Yuefeng Liu ^b ,
Zhongkui Zhao ^{a, *,}

a.
State Key Laboratory of Fine Chemicals, Department of Catalysis Chemistry and Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China
b.
Dalian National Laboratory for Clean Energy (DNL), Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian 116023, China
c.
Zhang Dayu School of Chemistry, Dalian University of Technology, Dalian 116024, China

zkzhao@dlut.edu.cn

Received Date: 11 August 2021
Revised Date: 19 September 2021
Accepted Date: 14 October 2021
Available Online: 22 October 2021

Figures(2)

Dimethyl ether (DME), as a promising alternative to diesel fuel and liquefied petroleum gas, has attracted considerable attention in catalysis domain. The catalytic direct synthesis of DME from syngas is an up-and-coming route but remains a challenge. In this work, we firstly prepared a Cu-embedded porous Al₂O₃ bifunctional catalyst (Cu@Al₂O₃-dp) by filling Cu-1, 3, 5-benzenetricarboxylate metal-organic framework (Cu-BTC MOF) with Al(OH)₃ followed by a two-step calcination process (400 ℃ for 4 h and 600 ℃ for 1 h), exhibiting excellent catalytic performance for direct synthesis of DME from syngas. Cu@Al₂O₃-dp catalyst demonstrates much higher CO conversion (25.7% vs. 15.4%) and extremely higher DME selectivity (90.4% vs. 63.9%) with the increased catalytic stability compared to the supported Cu catalyst on MOF-derived porous Al₂O₃ (Cu/Al₂O₃) prepared by incipient wetness impregnation method, ascribed to the unique embedding-type structure, promoted Cu dispersion and stronger metal-support interaction. This work not only provides an efficient syngas-to-DME catalyst, but also paves a new way for designing highly-efficient core-shell bifunctional catalysts for diverse consecutive reactions.
- Dimethyl ether,
- CO hydrogenation,
- Bifunctional catalyst,
- Embedding-type structure,
- Metal-organic framework
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沈阳化工大学材料科学与工程学院沈阳 110142

Cu-embedded porous Al2O3 bifunctional catalyst derived from metal-organic framework for syngas-to-dimethyl ether

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通讯作者: 陈斌, bchen63@163.com

Cu-embedded porous Al₂O₃ bifunctional catalyst derived from metal-organic framework for syngas-to-dimethyl ether