Citation: Wei Gao, Min Li, Yun Fa, Zongshan Zhao, Yaqi Cai, Xiangfeng Liang, Yongliang Yu, Guibin Jiang. Porous covalent organic frameworks-improved solid phase microextraction ambient mass spectrometry for ultrasensitive analysis of tetrabromobisphenol-A analogs[J]. Chinese Chemical Letters, ;2022, 33(8): 3849-3852. doi: 10.1016/j.cclet.2021.10.030 shu

Porous covalent organic frameworks-improved solid phase microextraction ambient mass spectrometry for ultrasensitive analysis of tetrabromobisphenol-A analogs

Wei Gao ^{a, b} ,
Min Li ^b ,
Yun Fa ^{b, *,} ,
Zongshan Zhao ^{b, c, **,} ,
Yaqi Cai ^d ,
Xiangfeng Liang ^{b, e} ,
Yongliang Yu ^{a, *,} ,
Guibin Jiang ^d

a.
Research Center for Analytical Sciences, Department of Chemistry, College of Sciences, Northeastern University, Shenyang 110819, China
b.
CAS Key Laboratory of Biobased Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China
c.
College of Environmental Science and Engineering, Qingdao University, Qingdao 266071, China
d.
State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
e.
Innovation Academy for Green Manufacture, Chinese Academy of Sciences, Beijing 100190, China

^**

fayun@qibebt.ac.cn

zhaozs@qdu.edu.cn

yuyl@mail.neu.edu.cn

Received Date: 25 June 2021
Revised Date: 23 August 2021
Accepted Date: 13 October 2021
Available Online: 21 October 2021

Figures(4)

Owing to frequent environmental monitoring of tetrabromobisphenol-A (TBBPA) analogs and their potential ecotoxicological effects on organisms, analysis of trace levels of TBBPA analogs with more non-polar and less water-soluble characteristics is of great significance for studying their environmental behaviors and toxic effects. Herein, a fast and sensitive technique is developed for directly detecting aqueous TBBPA analogs, including TBBPA mono(allyl ether) (TBBPA-MAE), TBBPA mono(2,3-dibromopropyl ether) (TBBPA-MDBPE), TBBPA mono(2-hydroxyethyl ether) (TBBPA-MHEE) and TBBPA mono(glycidyl ether) (TBBPA-MGE), by combining solid phase microextraction (SPME) based on porous covalent organic frameworks (Porous-COFs) with constant flow desorption ionization-mass spectrometry (CFDI-MS). As chromatographic separation is replaced by constant flow desorption, each sample can be analyzed within 7 min. The hierarchical porous structures (microporous, mesoporous and macroporous) of COFs lead to the enhanced mass transfer and the easier accessibility of active sites to TBBPA analogs, so that the extraction efficiency is 2.3–3.6 times higher than pure microporous COFs, and far superior to commercial coatings. The detection limit and quantification limit of this method are 0.1–1 and 0.4–3.2 ng/L, respectively. Ultra-trace levels of TBBPA analogs from 5.0 ng/L to 66 ng/L have been successfully detected in river and sea water samples, showing great potential for subsequent studies of their environmental behaviors and toxicological effects
- Environmental analysis,
- Covalent organic frameworks,
- Solid phase microextraction,
- Ambient mass spectrometry,
- TBBPA analogs
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