Citation: Lixia Jia, Xin Tan, Yanfang Li, Yizhong Zhang, Shiqian Cao, Wei Zhou, Xiang Huang, Lequan Liu, Tao Yu. Design of BiOBr_0.25I_0.75 for synergy photoreduction Cr(Ⅵ) and capture Cr(Ⅲ) over wide pH range[J]. Chinese Chemical Letters, ;2022, 33(6): 3053-3060. doi: 10.1016/j.cclet.2021.09.043 shu

Design of BiOBr_0.25I_0.75 for synergy photoreduction Cr(Ⅵ) and capture Cr(Ⅲ) over wide pH range

Lixia Jia ^a ,
Xin Tan ^{a, d} ,
Yanfang Li ^a ,
Yizhong Zhang ^a ,
Shiqian Cao ^c ,
Wei Zhou ^{c, *,} ,
Xiang Huang ^d ,
Lequan Liu ^e ,
Tao Yu ^{b, *,}

a.
School of Environmental Science and Engineering, Tianjin University, Tianjin 300350, China
b.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China
c.
School of Science, Tianjin University, Tianjin 300350, China
d.
School of Science, Tibet University, Lhasa 850000, China
e.
School of Materials Science and Engineering, Tianjin University, Tianjin 300350, China

weizhou@tju.edu.cn

yutao@tju.edu.cn

Received Date: 12 July 2021
Revised Date: 12 August 2021
Accepted Date: 13 September 2021
Available Online: 17 September 2021

Figures(9)

Conversion of hexavalent chromium (Cr(Ⅵ)) to trivalent chromium (Cr(Ⅲ)) is an effective way to reduce its environmental risk, especially via photoreduction process. However, over a wide range of pH values, it is still a great challenge to achieve a high removal rate, and the disposal of produced Cr(Ⅲ) should be concerned. In this work, we implemented a high removal rate at 98% for Cr(Ⅵ) and total chromium (Cr(T)) over a wide pH range (4–10) through the synergistic effect of adsorption, photoreduction and immobilization on the surface of BiOBr_0.25I_0.75. The substitution of bromine by iodine reduced the adsorption energy of Cr(Ⅵ) on BiOBr_0.25I_0.75, promoting the adsorption of Cr(Ⅵ). Meanwhile, the introduced iodine upshifted the conduction band (CB), enhancing the reduction ability for Cr(Ⅵ) to Cr(Ⅲ). The negative surface of BiOBr_0.25I_0.75 can capture Cr(Ⅲ), achieving a high removal rate for Cr(T). The pH-independent feature for Cr(Ⅵ) and Cr(Ⅲ) removal make BiOBr_0.25I_0.75 a potential material for chromium-containing wastewater treatment. This work provides an effective strategy for removing chromium over a wide pH range.
- Adsorption,
- Photoreduction,
- BiOBr_0.25I_0.75,
- Chromium
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沈阳化工大学材料科学与工程学院沈阳 110142

Design of BiOBr0.25I0.75 for synergy photoreduction Cr(Ⅵ) and capture Cr(Ⅲ) over wide pH range

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通讯作者: 陈斌, bchen63@163.com

Design of BiOBr_0.25I_0.75 for synergy photoreduction Cr(Ⅵ) and capture Cr(Ⅲ) over wide pH range