Citation: Ning-Na Guo, Zhao-Lei Liu, Yan-Fei Mu, Meng-Ran Zhang, Yuan Yao, Min Zhang, Tong-Bu Lu. In-situ growth of PbI₂ on ligand-free FAPbBr₃ nanocrystals to significantly ameliorate the stability of CO₂ photoreduction[J]. Chinese Chemical Letters, ;2022, 33(6): 3039-3042. doi: 10.1016/j.cclet.2021.09.033 shu

In-situ growth of PbI₂ on ligand-free FAPbBr₃ nanocrystals to significantly ameliorate the stability of CO₂ photoreduction

Ning-Na Guo ^a ,
Zhao-Lei Liu ^a ,
Yan-Fei Mu ^a ,
Meng-Ran Zhang ^a ,
Yuan Yao ^{b, *,} ,
Min Zhang ^{a, *,} ,
Tong-Bu Lu ^a

a.
MOE International Joint Laboratory of Materials Microstructure, Institute for New Energy Materials and Low Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China
b.
MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China

yyuan@hit.edu.cn

zm2016@email.tjut.edu.cn

Received Date: 27 June 2021
Revised Date: 6 August 2021
Accepted Date: 7 September 2021
Available Online: 11 September 2021

Figures(4)

Excellent optical properties involving strong visible light response and superior carrier transport endow metal halide perovskites (MHP) with a fascinating prospect in the field of photocatalysis. Nevertheless, the poor stability of MHP nanocrystals (NCs) in water-contained system, especially without the protection of long alkyl chain ligands, severely restricts their photocatalytic performance. In this context, we report an effortless strategy for the generation of ligand-free MHP NCs based photocatalyst with high water tolerance, by coating PbI₂ on the surface of ligand-free formamidinium lead bromide (FAPbBr₃) NCs via the facile procedure of in-situ conversion with the aid of ZnI₂. Under the protection of PbI₂ layer, the resultant FAPbBr₃/PbI₂ composite exhibits significantly ameliorated stability in an artificial photosynthesis system with CO₂ and H₂O vapor as feedstocks. Moreover, the formation of compact PbI₂ layer can accelerate the separation of photogenerated carriers in FAPbBr₃ NCs, bringing forth a remarkable improvement of CO₂ photoreduction efficiency with an impressive electron consumption yield of 2053 µmol/g in the absence of organic sacrificial agents, which is 7-fold over that of pristine FAPbBr₃ NCs.
- CO₂ reduction,
- Halide perovskite,
- Photocatalysis,
- Stability,
- Charge transfer
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沈阳化工大学材料科学与工程学院沈阳 110142

In-situ growth of PbI2 on ligand-free FAPbBr3 nanocrystals to significantly ameliorate the stability of CO2 photoreduction

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通讯作者: 陈斌, bchen63@163.com

In-situ growth of PbI₂ on ligand-free FAPbBr₃ nanocrystals to significantly ameliorate the stability of CO₂ photoreduction