Citation: Li-Fei Tian, Ming Liu, Li-Xia Chen, Chao Huang, Qian-Jiang Zhu, Kai Chen, Jiang-Lin Zhao, Zhu Tao. Q[8]/SC[6]A-based framework constructed via OSIQ for metal ion capture[J]. Chinese Chemical Letters, ;2022, 33(3): 1524-1528. doi: 10.1016/j.cclet.2021.08.106 shu

Q[8]/SC[6]A-based framework constructed via OSIQ for metal ion capture

Li-Fei Tian ^a ,
Ming Liu ^a ,
Li-Xia Chen ^a ,
Chao Huang ^a ,
Qian-Jiang Zhu ^a ,
Kai Chen ^{b, *,} ,
Jiang-Lin Zhao ^{c, *,} ,
Zhu Tao ^{a, *,}

a.
Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China
b.
Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, School of Environmental Science and Engineering, Nanjing University of Information Science & Technology, Nanjing 210044, China
c.
Institute of Biomedical & Health Engineering, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

kaichen85@nuist.edu.cn

jl.zhao@siat.ac.cn

gzutao@263.net

Received Date: 5 June 2021
Revised Date: 19 August 2021
Accepted Date: 24 August 2021
Available Online: 30 August 2021

Figures(4)

Since the outer surface interaction of Q[n]s (OSIQ, including self-, anion- and aromatic-induced OSIQs) was proposed in 2014, it has become the most important research area in our group to construct various Q[n]-based supramolecular frameworks via the OSIQ strategy. Herein, we report a novel supramolecular framework constructed using cucurbit[8]uril (Q[8]) and 4-sulfocalix[6]arene (SC[6]A). This Q[8]/SC[6]A-based supramolecular framework is a product via the perfect combination of self-, anion- and aromatic-induced OSIQs. This framework has the characteristics of easy preparation and high stability with the most important feature being the sequence selective capture of specific metal cations, such as common alkali- and alkaline earth metal ions, and renewability. Thus, this framework may be used in seawater desalination, potassium ion enrichment, radioactive cesium ion pollution source treatment, Gruinard's treatment or water softening and other applications.
- Cucurbit[8]uril,
- 4-Sulfocalix[6]arene,
- Outer surface interaction of Q[n]s,
- Supramolecular framework,
- Metal ion capture
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