Citation: Yu-Shen Zhu, Linlin Shi, Lianrong Fu, Xiran Chen, Xinju Zhu, Xin-Qi Hao, Mao-Ping Song. Iodine-catalyzed amination of benzothiazoles with KSeCN in water to access primary 2-aminobenzothiazoles[J]. Chinese Chemical Letters, ;2022, 33(3): 1497-1500. doi: 10.1016/j.cclet.2021.08.070 shu

Iodine-catalyzed amination of benzothiazoles with KSeCN in water to access primary 2-aminobenzothiazoles

College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

xqhao@zzu.edu.cn

mpsong@zzu.edu.cn

Received Date: 14 April 2021
Revised Date: 11 August 2021
Accepted Date: 13 August 2021
Available Online: 19 August 2021

Figures(6)

A facile and sustainable approach for the amination of benzothiazoles with KSeCN using iodine as the catalyst in water has been disclosed under transition-metal free conditions. The reaction proceeded smoothly to afford various primary 2-amino benzothiazoles in up to 96% yield. A series of control experiments were performed, suggesting a ring-opening mechanism was involved via a radical process. This protocol provides efficient synthesis of primary 2-aminobenzothiazoles
- Iodine-catalyzed,
- Benzothiazoles,
- KSeCN,
- Water,
- Primary 2-benzothiazolamines
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