Citation: Weilu Wang, Xiangke Zeng, Yanliu Dang, Ping Ouyang, Haidong Zhang, Guangming Jiang, Fan Dong, Tao Yang, Steven L. Suib, Yang He. Fe doped aluminoborate PKU-1 catalysts for the ketalization of glycerol to solketal: Unveiling the effects of iron composition and boron[J]. Chinese Chemical Letters, ;2022, 33(3): 1346-1352. doi: 10.1016/j.cclet.2021.08.056 shu

Fe doped aluminoborate PKU-1 catalysts for the ketalization of glycerol to solketal: Unveiling the effects of iron composition and boron

Weilu Wang ^{a, *,} ,
Xiangke Zeng ^a ,
Yanliu Dang ^b ,
Ping Ouyang ^a ,
Haidong Zhang ^a ,
Guangming Jiang ^a ,
Fan Dong ^{a, c} ,
Tao Yang ^d ,
Steven L. Suib ^b ,
Yang He ^{e, *,}

a.
Engineering Research Center for Waste Oil Recovery Technology and Equipment, Ministry of Education, Chongqing Technology and Business University, Chongqing 400067, China
b.
Institute of Materials Science, University of Connecticut, Storrs, CT 06269, United States
c.
Yangtze Delta Region Institute (Huzhou) & Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Huzhou 313001, China
d.
College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 401331, China
e.
Department of Chemical, Biological and Materials Engineering, University of South Florida, Tampa, FL 33620, United States

weiluwang@ctbu.edu.cn

yangh1@usf.edu

Received Date: 8 May 2021
Revised Date: 30 July 2021
Accepted Date: 11 August 2021
Available Online: 16 August 2021

Figures(4)

An inexpensive Fe doped aluminoborate consisted of 18% Fe in PKU-1 material that exhibits high selectivity of 4-hydroxymethy-2,2-dimethyl-1,3-dioxolane (Solketal, 98.3%), considerable activity (TOF 51.7 h^-1), and recyclable ability in the ketalization of glycerol to Solketal with acetone at 318 K has been developed. Our study demonstrated that the structure of Fe (less agglomerated iron species vs. FeO_x clusters) can be tuned by changing Fe loading in the PKU-1 material, which correlated well with experimental observations. Furthermore, the surface boron sites were promoted by iron loading and behaved as Lewis-acid sites to facilitate the reaction process of glycerol ketalization, while the Solketal selectivity was closely related with the structure of iron species in PKU-1, which was proved by kinetic studies, density function theory (DFT) calculations, and a series of spectroscopy studies. This investigation demonstrates that the surface B sites can play important roles in the reaction instead of being spectators.
- Fe doping aluminoborate,
- Glycerol recycling,
- Ketalization,
- Boron reaction sites,
- Lewis-acid dominating catalyst
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