Citation: Xiaogang Yang, Jiejia Han, Wei Ruan, Yanqiang Hu, Zhengyan He, Xiangrui Jia, Shufang Zhang, Dehua Wang. Low temperature fabrication for high-performance semitransparent CsPbI₂Br perovskite solar cells[J]. Chinese Chemical Letters, ;2022, 33(3): 1425-1429. doi: 10.1016/j.cclet.2021.08.039 shu

Low temperature fabrication for high-performance semitransparent CsPbI₂Br perovskite solar cells

Xiaogang Yang ^a ,
Jiejia Han ^{a, b} ,
Wei Ruan ^c ,
Yanqiang Hu ^{b, c, d, *,} ,
Zhengyan He ^b ,
Xiangrui Jia ^b ,
Shufang Zhang ^{b, *,} ,
Dehua Wang ^{b, *,}

a.
College of Environment and Safety Engineering, Qingdao University of Science & Technology, Qingdao 266042, China
b.
School of Physics and Photoelectronic Engineering, Ludong University, Yantai 264025, China
c.
College of Materials Science and Engineering, Nanjing University of Science & Technology, Nanjing 210094, China
d.
College of Chemistry and Chemical Engineer, Nantong University, Nantong 226001, China

huyqntu@ntu.edu.cn

ZSF2013CPO@163.com

lduwdh@163.com

Received Date: 30 June 2021
Revised Date: 7 August 2021
Accepted Date: 9 August 2021
Available Online: 12 August 2021

Figures(5)

All-inorganic CsPbI₂Br perovskite with suitable bandgap and excellent thermal stability has been reported as the most promising candidate for efficient perovskite solar cells (PSCs). However, the high annealing temperature (> 250 ℃) and poor stability of α-CsPbI₂Br greatly limit the future application in photovoltaic field. Herein, a facile method is reported to prepare α-CsPbI₂Br perovskite film with high stability at low temperature (70 ℃) by incorporating a small amount of γ-aminobutyric acid (GABA) in the precursor solutions. The devices exhibit reproducible photovoltaic performance with a champion efficiency up to 15.16%, along with the excellent stability, maintaining more than 80% of its initial efficiency after stored in ambient condition for 600 h without any encapsulation. Most importantly, the method enables fabrication of semitransparent CsPbI₂Br PSCs with a PCE of 6.76%, as well as an average visible transparency (AVT) of 25.38%. To the best of our knowledge, this is the first attempt to apply CsPbI₂Br to the semitransparent solar cells.
- CsPbI₂Br perovskite,
- γ-Aminobutyric acid,
- Stability,
- Low-temperature fabrication,
- Semitransparent solar cells
1. [1]
  L.J. Zhu, Q.P. Lu, C.H. Li, Y. Wang, Z.B. Deng, Chin. Chem. Lett. 32(2021) 2259-2262. doi: 10.1016/j.cclet.2020.12.052
2. [2]
  T. Zhu, Y.R. Yang, S.Y. Zhou, et al., Chin. Chem. Lett. 31(2020) 2249-2253. doi: 10.1016/j.cclet.2020.02.004
3. [3]
  W.L. Xu, N.S. Niu, X.Y. Yang, et al., Chin. Chem. Lett. 32(2021) 489-492. doi: 10.1016/j.cclet.2020.05.017
4. [4]
  W.D. Zhu, W.M. Chai, D.D. Chen, et al., ACS. Energy. Lett. 6(2021) 1500-1510. doi: 10.1021/acsenergylett.1c00325
5. [5]
  M.H. Li, J.Y. Shao, Y. Jiang, et al., Angew. Chem. 133(2021) 16524-16529. doi: 10.1002/ange.202105176
6. [6]
  T. Ozturk, E. Akman, A.E. Shalan, S. Akin, Nano. Energy 87(2021) 106157. doi: 10.1016/j.nanoen.2021.106157
7. [7]
  NREL Chart. https://www.nrel.gov/pv/assets/pdfs/best-research-cellefficiencies.20200922.pdf.
8. [8]
  Z.X. Wei, Y.H. Zhao, J. Jiang, et al., Chin. Chem. Lett. 31(2020) 3055-3064. doi: 10.1016/j.cclet.2020.05.016
9. [9]
  Y.H. Liu, S. Akin, L.F. Pan, et al., Sci. Adv. 5(2019) eaaw2543. doi: 10.1126/sciadv.aaw2543
10. [10]
  W.C. Xiang, W. Tress, Adv. Mater. 31(2019) 1902851. doi: 10.1002/adma.201902851
11. [11]
  M.B. Faheem, B. Khan, C. Feng, et al., ACS. Energy Lett. 5(2020) 290-320. doi: 10.1021/acsenergylett.9b02338
12. [12]
  J.R. Zhang, G. Hodes, Z.W. Jin, S.Z. Liu, Angew. Chem. Int. Ed. 58(2019) 15596-15618. doi: 10.1002/anie.201901081
13. [13]
  W.C. Xiang, Z.W. Wang, D.J. Kubicki, et al., Joule 3(2019) 205-214. doi: 10.1016/j.joule.2018.10.008
14. [14]
  S.S. Mail, J.V. Patil, P.S. Shinde, G.D. Miguel, C.K. Hong, Matter 4(2021) 635-653. doi: 10.1016/j.matt.2020.11.008
15. [15]
  J. K Nam, M.S. Jung, S.U. Chai, et al., J. Phys. Chem. Lett. 8(2017) 2936-2940. doi: 10.1021/acs.jpclett.7b01067
16. [16]
  D.L. Bai, H. Bian, Z.W. Jin, et al., Nano Energy 52(2018) 408-415. doi: 10.1016/j.nanoen.2018.08.012
17. [17]
  Z.B. Zeng, J. Zhang, X.L. Gan, et al., Adv. Energy. Mater. 8(2018) 1801050. doi: 10.1002/aenm.201801050
18. [18]
  C.F.J. Lau, M. Zhang, X.F. Deng, et al., ACS. Energy. Lett. 2(2017) 2319-2325. doi: 10.1021/acsenergylett.7b00751
19. [19]
  S.M. Yang, H. Zhao, Y. Han, et al., Small 15(2019) 1904387. doi: 10.1002/smll.201904387
20. [20]
  J.S. Zhang, C. Wang, H. Fu, et al., J. Alloys. Compd. 862(2021) 158454. doi: 10.1016/j.jallcom.2020.158454
21. [21]
  Y. Wang, T.Y. Zhang, F. Xu, Y.H. Li, Y.X. Zhao, Sol. RRL 2(2018) 1700180. doi: 10.1002/solr.201700180
22. [22]
  H. Jiang, J.S. Feng, H. Zhao, et al., Adv. Sci. 5(2018) 1801117. doi: 10.1002/advs.201801117
23. [23]
  G.E. Eperon, V.M. Burlakov, A. Goriely, H.J. Snaith, Adv. Sci. Lett. 8(2014) 591-598.
24. [24]
  F. Guo, H. Azimi, Y. Hou, et al., Nanoscale 7(2015) 1642-1649. doi: 10.1039/C4NR06033D
25. [25]
  J. Lin, M.L. Lai, L.T. Dou, et al., Nat. Mater. 17(2018) 261-267. doi: 10.1038/s41563-017-0006-0
26. [26]
  Q. Wang, X.P. Zheng, Y.H. Deng, et al., Joule 1(2017) 371-382. doi: 10.1016/j.joule.2017.07.017
27. [27]
  G.N. Yin, H. Zhao, H. Jiang, et al., Adv. Funct. Mater. 28(2018) 1803269. doi: 10.1002/adfm.201803269
28. [28]
  T. Qiu, Y.Q. Hu, F. Bai, X.L. Miao, S.F. Zhang, J. Mater. Chem. A 6(2018) 12370-12379. doi: 10.1039/C8TA00948A
29. [29]
  C.M. Zhang, S.F. Zhang, X.L. Miao, et al., Part. Part. Syst. Char. 34(2017) 1600298. doi: 10.1002/ppsc.201600298
30. [30]
  B. Li, Y.N. Zhang, L. Fu, et al., Nat. Commun. 9(2018) 1076. doi: 10.1038/s41467-018-03169-0
31. [31]
  H.X. Rao, S.Y. Ye, F.D. Gu, et al., Adv. Energy Mater. 8(2018) 1800758. doi: 10.1002/aenm.201800758
32. [32]
  K.Y. Yan, M.Z. Long, T.K. Zhang, et al., J. Am. Chem. Soc. 137(2015) 4460-4468. doi: 10.1021/jacs.5b00321
33. [33]
  W.Z. Li, J.D. Fan, J.W. Li, Y.H. Mai, L.D. Wang, J. Am. Chem. Soc. 137(2015) 10399-10405. doi: 10.1021/jacs.5b06444
34. [34]
  A. Swarnkar, W.J. Mir, A. Nag, ACS. Energy Lett. 3(2018) 286-289. doi: 10.1021/acsenergylett.7b01197
35. [35]
  C. Liu, W.Z. Li, C.L. Zhang, et al., J. Am. Chem. Soc. 140(2018) 3825-3828. doi: 10.1021/jacs.7b13229
36. [36]
  T. Zhang, H. Li, S.S. Liu, et al., J. Phys. Chem. Lett. 10(2019) 200-205. doi: 10.1021/acs.jpclett.8b03481
37. [37]
  X.J. Feng, L. Jiang, Adv. Mater. 18(2006) 3063-3078. doi: 10.1002/adma.200501961
38. [38]
  S.P. Cho, S.I. Na, S.S. Kim, Sol. Energy Mater. Sol. Cells 196(2019) 1-8. doi: 10.1016/j.solmat.2019.03.002
39. [39]
  P. You, Z.K. Liu, Q.D. Tai, S.H. Liu, F. Yan, Adv. Mater. 27(2015) 3632-3638. doi: 10.1002/adma.201501145
40. [40]
  J.W. Jung, C.C. Chueh, A.K.Y. Jen, Adv. Energy Mater. 5(2015) 1500486. doi: 10.1002/aenm.201500486
1. [1]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
2. [2]
  Xinpin Pan , Yongjian Cui , Zhe Wang , Bowen Li , Hailong Wang , Jian Hao , Feng Li , Jing Li . Robust chemo-mechanical stability of additives-free SiO₂ anode realized by honeycomb nanolattice for high performance Li-ion batteries. Chinese Chemical Letters, 2024, 35(10): 109567-. doi: 10.1016/j.cclet.2024.109567
3. [3]
  Rongjun Zhao , Tai Wu , Yong Hua , Yude Wang . Improving performance of perovskite solar cells enabled by defects passivation and carrier transport dynamics regulation via organic additive. Chinese Chemical Letters, 2025, 36(2): 109587-. doi: 10.1016/j.cclet.2024.109587
4. [4]
  Rui Liu , Yue Yu , Lu Deng , Maoxia Xu , Haorong Ren , Wenjie Luo , Xudong Cai , Zhenyu Li , Jingyu Chen , Hua Yu . The synergistic effect of A-site cation engineering and phase regulation enables efficient and stable Ruddlesden-Popper perovskite solar cells. Chinese Chemical Letters, 2024, 35(12): 109545-. doi: 10.1016/j.cclet.2024.109545
5. [5]
  Chenghao Ge , Peng Wang , Pei Yuan , Tai Wu , Rongjun Zhao , Rong Huang , Lin Xie , Yong Hua . Tuning hot carrier transfer dynamics by perovskite surface modification. Chinese Chemical Letters, 2024, 35(10): 109352-. doi: 10.1016/j.cclet.2023.109352
6. [6]
  Jingyuan Yang , Xinyu Tian , Liuzhong Yuan , Yu Liu , Yue Wang , Chuandong Dou . Enhancing stability of diradical polycyclic hydrocarbons via P=O-attaching. Chinese Chemical Letters, 2024, 35(8): 109745-. doi: 10.1016/j.cclet.2024.109745
7. [7]
  Ting Wang , Xin Yu , Yaqiang Xie . Unlocking stability: Preserving activity of biomimetic catalysts with covalent organic framework cladding. Chinese Chemical Letters, 2024, 35(6): 109320-. doi: 10.1016/j.cclet.2023.109320
8. [8]
  Qiyan Wu , Ruixin Zhou , Zhangyi Yao , Tanyuan Wang , Qing Li . Effective approaches for enhancing the stability of ruthenium-based electrocatalysts towards acidic oxygen evolution reaction. Chinese Chemical Letters, 2024, 35(10): 109416-. doi: 10.1016/j.cclet.2023.109416
9. [9]
  Hongmei Yu , Baoxi Zhang , Meiju Liu , Cheng Xing , Guorong He , Li Zhang , Ningbo Gong , Yang Lu , Guanhua Du . Theoretical and experimental cocrystal screening of temozolomide with a series of phenolic acids, promising cocrystal coformers. Chinese Chemical Letters, 2024, 35(5): 109032-. doi: 10.1016/j.cclet.2023.109032
10. [10]
  Wenxiang Ma , Xinyu He , Tianyi Chen , De-Li Ma , Hongzheng Chen , Chang-Zhi Li . Near-infrared non-fused electron acceptors for efficient organic photovoltaics. Chinese Chemical Letters, 2024, 35(4): 109099-. doi: 10.1016/j.cclet.2023.109099
11. [11]
  Liang Ming , Dan Liu , Qiyue Luo , Chaochao Wei , Chen Liu , Ziling Jiang , Zhongkai Wu , Lin Li , Long Zhang , Shijie Cheng , Chuang Yu . Si-doped Li₆PS₅I with enhanced conductivity enables superior performance for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109387-. doi: 10.1016/j.cclet.2023.109387
12. [12]
  Yan-Kai Zhang , Yong-Zheng Zhang , Chun-Xiao Jia , Fang Wang , Xiuling Zhang , Yuhang Wu , Zhongmin Liu , Hui Hu , Da-Shuai Zhang , Longlong Geng , Jing Xu , Hongliang Huang . A stable Zn-MOF with anthracene-based linker for Cr(VI) photocatalytic reduction under sunlight irradiation. Chinese Chemical Letters, 2024, 35(12): 109756-. doi: 10.1016/j.cclet.2024.109756
13. [13]
  Jinqiang Gao , Haifeng Yuan , Xinjuan Du , Feng Dong , Yu Zhou , Shengnan Na , Yanpeng Chen , Mingyu Hu , Mei Hong , Shihe Yang . Methanol steam mediated corrosion engineering towards high-entropy NiFe layered double hydroxide for ultra-stable oxygen evolution. Chinese Chemical Letters, 2025, 36(1): 110232-. doi: 10.1016/j.cclet.2024.110232
14. [14]
  Guilong Li , Wenbo Ma , Jialing Zhou , Caiqin Wu , Chenling Yao , Huan Zeng , Jian Wang . A composite hydrogel with porous and homogeneous structure for efficient osmotic energy conversion. Chinese Chemical Letters, 2025, 36(2): 110449-. doi: 10.1016/j.cclet.2024.110449
15. [15]
  Lijun Yan , Shiqi Chen , Penglu Wang , Xiangyu Liu , Lupeng Han , Tingting Yan , Yuejin Li , Dengsong Zhang . Hydrothermally stable metal oxide-zeolite composite catalysts for low-temperature NO_x reduction with improved N₂ selectivity. Chinese Chemical Letters, 2024, 35(6): 109132-. doi: 10.1016/j.cclet.2023.109132
16. [16]
  Xinyu Yu , Fei Wu , Xianglang Sun , Linna Zhu , Baoyu Xia , Zhong'an Li . Low-cost dopant-free fluoranthene-based branched hole transporting materials for efficient and stable n-i-p perovskite solar cells. Chinese Chemical Letters, 2024, 35(10): 109821-. doi: 10.1016/j.cclet.2024.109821
17. [17]
  Chen Lu , Zefeng Yu , Jing Cao . Advancement in porphyrin/phthalocyanine compounds-based perovskite solar cells. Chinese Journal of Structural Chemistry, 2024, 43(3): 100240-100240. doi: 10.1016/j.cjsc.2024.100240
18. [18]
  Chi Li , Peng Gao . Is dipole the only thing that matters for inverted perovskite solar cells?. Chinese Journal of Structural Chemistry, 2024, 43(6): 100324-100324. doi: 10.1016/j.cjsc.2024.100324
19. [19]
  Kangrong Yan , Ziqiu Shen , Yanchun Huang , Benfang Niu , Hongzheng Chen , Chang-Zhi Li . Curing the vulnerable heterointerface via organic-inorganic hybrid hole transporting bilayers for efficient inverted perovskite solar cells. Chinese Chemical Letters, 2024, 35(6): 109516-. doi: 10.1016/j.cclet.2024.109516
20. [20]
  Bo Yang , Pu-An Lin , Tingwei Zhou , Xiaojia Zheng , Bing Cai , Wen-Hua Zhang . Facile surface regulation for highly efficient and thermally stable perovskite solar cells via chlormequat chloride. Chinese Chemical Letters, 2024, 35(10): 109425-. doi: 10.1016/j.cclet.2023.109425

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(720)
HTML views(153)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Low temperature fabrication for high-performance semitransparent CsPbI2Br perovskite solar cells

Metrics

通讯作者: 陈斌, bchen63@163.com

Low temperature fabrication for high-performance semitransparent CsPbI₂Br perovskite solar cells