Citation: Zhiwei Wang, Qishun Liu, Ruisheng Liu, Zhongyin Ji, Yan Li, Xiaohui Zhao, Wei Wei. Visible-light-initiated 4CzIPN catalyzed multi-component tandem reactions to assemble sulfonated quinoxalin-2(1H)-ones[J]. Chinese Chemical Letters, ;2022, 33(3): 1479-1482. doi: 10.1016/j.cclet.2021.08.036 shu

Visible-light-initiated 4CzIPN catalyzed multi-component tandem reactions to assemble sulfonated quinoxalin-2(1H)-ones

Zhiwei Wang ^a ,
Qishun Liu ^a ,
Ruisheng Liu ^a ,
Zhongyin Ji ^a ,
Yan Li ^a ,
Xiaohui Zhao ^b ,
Wei Wei ^{a, *,}

a.
School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China
b.
Qinghai Provincial Key Laboratory of Tibetan Medicine Research and Key Laboratory of Tibetan Medicine Research, Northwest Institute of Plateau Biology, Chinese Academy of Sciences, Qinghai 810008, China

weiweiqfnu@163.com

Received Date: 9 June 2021
Revised Date: 6 August 2021
Accepted Date: 8 August 2021
Available Online: 12 August 2021

Figures(7)

A mild and efficient photochemical multi-component tandem reaction of quinoxalin-2(1H)-ones, alkenes and sulfinic acids is reported. This tandem reaction could be conveniently carried out at room temperature by employing 4CzIPN as the metal-free photocatalyst and dioxygen (air) as the environmentally benign oxidant. A number of sulfonated quinoxalin-2(1H)-ones were obtained in satisfactory yields with favorable functional group tolerance. Radical trapping experiment and fluorescence quenching experiments were performed to elucidate this visible-light mediated radical reaction process.
- Visible-light,
- Multi-component reaction,
- Radical process,
- Sulfonated quinoxalin-2(1H)-ones
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