Citation: Wenfang Peng, Shiwen Liu, Xiugang Li, Gang Feng, Jianhui Xia, Zhang-Hui Lu. Robust hydrogen production from HCOOH over amino-modified KIT-6-confined PdIr alloy nanoparticles[J]. Chinese Chemical Letters, ;2022, 33(3): 1403-1406. doi: 10.1016/j.cclet.2021.08.033 shu

Robust hydrogen production from HCOOH over amino-modified KIT-6-confined PdIr alloy nanoparticles

Wenfang Peng ^{a, b} ,
Shiwen Liu ^b ,
Xiugang Li ^a ,
Gang Feng ^c ,
Jianhui Xia ^a ,
Zhang-Hui Lu ^{a, *,}

a.
Key Laboratory of Functional Small Molecules for Ministry of Education, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China
b.
Jiangxi Provincial Center for Disease Control and Prevention, Nanchang 330029, China
c.
College of Chemistry, Nanchang University, Nanchang 330031, China

luzh@jxnu.edu.cn

Received Date: 29 June 2021
Revised Date: 31 July 2021
Accepted Date: 9 August 2021
Available Online: 12 August 2021

Figures(4)

Formic acid (FA), which can be produced via CO₂ reduction and biomass conversion, has received extensive interest as a convenient and safe hydrogen carrier due to its wide range of sources, renewable, high hydrogen content (4.4 wt%), and convenient storage/transportation. Designing highly efficient catalysts is the main challenge to realize the hydrogen production from FA. In this work, well-dispersed and electron-rich PdIr alloy nanoparticles with a size of 1.8 nm are confined in amino-modified 3D mesoporous silica KIT-6 and applied as a highly efficient catalyst for robust hydrogen production from FA at ambient temperature. Small PdIr alloy nanoparticles confined by amino-modified KIT-6 (PdIr/KIT-6-NH₂) lead to better catalytic activity compared to that of Pd/KIT-6-NH₂ and PdIr confined by bare KIT-6, achieving a high turnover frequency (TOF) value of 3533 h⁻¹ at ambient temperature (303 K), 100% H₂ selectivity and conversion toward the dehydrogenation of FA, which is comparable to the best heterogeneous catalysts ever reported. The high catalytic activity of PdIr/KIT-6-NH₂ can be attributed to the synergistic effect between Pd and Ir, strong interaction between PdIr and KIT-6-NH₂, as well as the amino-groups of KIT-6-NH₂ which can act as a proton scavenger to promote the breaking of O-H bond of formic acid.
- Formic acid,
- Hydrogen production,
- Palladium,
- Metal nanoparticle,
- 3D mesoporous silica
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