Citation: Jianghua Fang, Xiaoyang Zhu, Wendi Luo, Jianxun Shi, Lejia Wang, Bin Tu, Qingdao Zeng, Xunwen Xiao. Self-assemblies of TTF derivatives with fluorinated phenyls and pyridine group[J]. Chinese Chemical Letters, ;2022, 33(2): 1100-1104. doi: 10.1016/j.cclet.2021.08.030 shu

Self-assemblies of TTF derivatives with fluorinated phenyls and pyridine group

Jianghua Fang ^{a, 1} ,
Xiaoyang Zhu ^{b, 1} ,
Wendi Luo ^{b, 1} ,
Jianxun Shi ^c ,
Lejia Wang ^a ,
Bin Tu ^b ,
Qingdao Zeng ^{b, *,} ,
Xunwen Xiao ^a

a.
College of Material Science and Chemical Engineering, Ningbo University of Technology, Ningbo 315211, China
b.
CAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology (NCNST), Beijing 100190, China
c.
Zhejiang Pharmaceutical College, Ningbo 315100, China

zengqd@nanoctr.cn

Received Date: 26 June 2021
Revised Date: 28 July 2021
Accepted Date: 7 August 2021
Available Online: 12 August 2021

Figures(5)

The self-assembly characteristics of tetrathiafulvalene (TTF) derivatives molecules 1–3 at the 1-phenyloctane/HOPG (HOPG = highly oriented pyrolytic graphite) interface had been carefully studied by scanning tunneling microscopy (STM) method. The number of F atoms on the phenyl group had significantly affected the self-assembly structures. High-resolution STM images make clear the different assembly structures between the molecules 1–3, which attribute to the different F atom numbers and pyridine group in the molecule. Density functional theory (DFT) calculations have been performed to reveal the formation mechanism.
- TTF,
- Self-assembly,
- STM,
- DFT calculation,
- Hydrogen bonds
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沈阳化工大学材料科学与工程学院沈阳 110142