Citation: Siguo Wu, Sukhen Bala, Zeyu Ruan, Guozhang Huang, Zhaoping Ni, Mingliang Tong. Four-step spin-crossover in an oxamide-decorated metal-organic framework[J]. Chinese Chemical Letters, ;2022, 33(3): 1381-1384. doi: 10.1016/j.cclet.2021.08.012 shu

Four-step spin-crossover in an oxamide-decorated metal-organic framework

Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China

nizhp@mail.sysu.edu.cn

Received Date: 31 May 2021
Revised Date: 18 June 2021
Accepted Date: 5 August 2021
Available Online: 11 August 2021

Figures(4)

Spin-crossover (SCO) complexes with multiple spin states are promising candidates for high-order magnetic storage and multiple switches. Here, by employing the N, Nʹ-4-dipyridyloxalamide (dpo) ligand, we synthesize two Hofmann-type metal-organic frameworks (MOFs) [Fe(dpo){Ag(CN)₂}₂]3DMF (1) and [Fe(dpo){Ag(CN)₂}₂]0.5MeCN2DEF (2), which exhibit guest dependent four-step SCO behaviors with the sequences of LS → ~LS_2/3HS_1/3 → LS_1/2HS_1/2 → ~LS_3/10HS_7/10 → HS and LS → ~LS_2/3HS_1/3 → LS_1/2HS_1/2 → ~LS_1/4HS_3/4 → HS, respectively. Therefore, the incorporation of hydrogen-donating/hydrogen-accepting groups into the Hofmann-type MOFs may effectively explore the multi-step SCO materials by tuning hydrogen-bonding interactions.
- Spin crossover,
- Oxamide,
- Metal-organic framework,
- Hofmann-type,
- Host-guest interaction
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