Citation: Ping Li, Yi Liu, Ziang Wang, Xuemei Xiao, Guozhe Meng, Xiaolin Wang, Hong-Lei Guo, Hui Guo. Dry-regulated hydrogels with anisotropic mechanical performance and ionic conductivity[J]. Chinese Chemical Letters, ;2022, 33(2): 871-876. doi: 10.1016/j.cclet.2021.08.010 shu

Dry-regulated hydrogels with anisotropic mechanical performance and ionic conductivity

Ping Li ^a ,
Yi Liu ^a ,
Ziang Wang ^a ,
Xuemei Xiao ^a ,
Guozhe Meng ^a ,
Xiaolin Wang ^{b, *,} ,
Hong-Lei Guo ^a, ,
Hui Guo ^{a, *,}

a.
School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai 519082, China
b.
School of Pharmacy and State Key Laboratory of Quality Research in Chinese Medicine, Macau University of Science and Technology, Macao, China

xilwang@must.edu.mo

guohonglei@mail.sysu.edu.cn

guoh37@mail.sysu.edu.cn

Received Date: 14 May 2021
Revised Date: 4 August 2021
Accepted Date: 5 August 2021
Available Online: 10 August 2021

Figures(6)

Nature consists of various soft tissues with well-ordered hierarchical anisotropic structures, which play essential roles in biological systems to exhibit particular functions. Mimicking bio-tissues, synthetic hydrogels with anisotropic structures have received considerable attention in recent years. However, existing approaches to fabricate anisotropic hydrogels often require complicated procedures, which are time-consuming and labor-demanding. Inspired by the dry-induced crystallization phenomenon, we report a simple yet effective prestretching-drying-swelling method to afford anisotropic crystalline polyvinyl alcohol hydrogels. Owing to the distinct anisotropic microstructure, the hydrogels demonstrate excellent mechanical properties with noticeable directional distinction. It is revealed that both the enhancing of pre-orientation strain and the extending of heating time make the hydrogels with better mechanical properties and more remarkable anisotropicity. Owing to the anisotropically aligned structure, the hydrogels exhibit remarkably differential ionic conductivity: the difference between the parallel and vertical conductivity of the same sample can reach as high as 6.6 times, making the materials possible candidates as nano-conductive materials. We anticipate that this simple yet effective approach may become highly useful for fabricating oriented hydrogels and endow the materials with more promising application prospects in the future.
- Crystalline hydrogels,
- Anisotropicity,
- Dry process,
- Mechanical performance,
- Differential conductivity
1. [1]
  G. Su, S. Yin, Y. Guo, et al., Mater. Horiz. 8(2021) 1795-1804. doi: 10.1039/D1MH00085C
2. [2]
  X. Pei, H. Zhang, Y. Zhou, L. Zhou, J. Fu, Mater. Horiz. 7(2020) 1872-1882. doi: 10.1039/D0MH00361A
3. [3]
  S. Xiao, M. Zhang, X. He, et al., ACS Appl. Mater. Interfaces 10(2018) 21642-21653. doi: 10.1021/acsami.8b06169
4. [4]
  X. Wang, O. Ronsin, B. Gravez, et al., Adv. Sci. 8(2021) 2004213. doi: 10.1002/advs.202004213
5. [5]
  H. Guo, N. Sanson, A. Marcellan, D. Hourdet, Macromolecules 49(2016) 9568-9577. doi: 10.1021/acs.macromol.6b02188
6. [6]
  H. Guo, C. Mussault, A. Marcellan, D. Hourdet, N. Sanson, Macromol. Rapid Commun. 38(2017) 1700287. doi: 10.1002/marc.201700287
7. [7]
  C. Xian, Q. Yuan, Z. Bao, G. Liu, J. Wu, Chin. Chem. Lett. 31(2020) 19-27. doi: 10.1016/j.cclet.2019.03.052
8. [8]
  G. Liu, Z. Bao, J. Wu, Chin. Chem. Lett. 31(2020) 1817-1821. doi: 10.1016/j.cclet.2020.03.005
9. [9]
  X. Lin, X. Wang, L. Zeng, et al., Chem. Mater. 33(2021) 7633-7656. doi: 10.1021/acs.chemmater.1c01019
10. [10]
  J.L. Drury, D.J. Mooney, Biomaterials 24(2003) 4337-4351. doi: 10.1016/S0142-9612(03)00340-5
11. [11]
  S. Sharma, R. Kumar, P. Kumari, et al., Int. J. Biol. Macromol. 125(2019) 109-115. doi: 10.1016/j.ijbiomac.2018.12.018
12. [12]
  K. Sano, Y. Ishida, T. Aida, Angew. Chem. Int. Ed. 57(2018) 2532-2543. doi: 10.1002/anie.201708196
13. [13]
  X.Y. Lin, Z.J. Wang, P. Pan, Z.L. Wu, Q. Zheng, RSC Adv. 6(2016) 95239-95245. doi: 10.1039/C6RA17103F
14. [14]
  M.A. Haque, G. Kamita, T. Kurokawa, K. Tsujii, J.P. Gong, Adv. Mater. 22(2010) 5110-5114. doi: 10.1002/adma.201002509
15. [15]
  L. Wu, M. Ohtani, M. Takata, et al., ACS Nano 8(2014) 4640-4649. doi: 10.1021/nn5003908
16. [16]
  M. Liu, Y. Ishida, Y. Ebina, et al., Nature 517(2015) 68-72. doi: 10.1038/nature14060
17. [17]
  M.T.I. Mredha, Y.Z. Guo, T. Nonoyama, et al., Adv. Mater. 30(2018) 1704937. doi: 10.1002/adma.201704937
18. [18]
  P. Lin, T. Zhang, X. Wang, B. Yu, F. Zhou, Small 12(2016) 4386-4392. doi: 10.1002/smll.201601893
19. [19]
  L.E. Millon, H. Mohammadi, W.K. Wan, J. Biomed. Mater. Res. B: Appl. Biomater. 79B (2006) 305-311. doi: 10.1002/jbm.b.30543
20. [20]
  H. Bai, A. Polini, B. Delattre, A.P. Tomsia, Chem. Mater. 25(2013) 4551-4556. doi: 10.1021/cm4025827
21. [21]
  H. Guo, T. Nakajima, D. Hourdet, et al., Adv. Mater. 31(2019) 1900702. doi: 10.1002/adma.201900702
22. [22]
  J. Zhu, J. Wang, Q. Liu, et al., J. Mater. Chem. B 1(2013) 978-986. doi: 10.1039/C2TB00288D
23. [23]
  X. Peng, C. He, J. Liu, H. Wang, J. Mater. Sci. 51(2016) 5901-5911. doi: 10.1007/s10853-016-9891-x
24. [24]
  H. Arslan, A. Nojoomi, J. Jeon, K. Yum, Adv. Sci. 6(2019) 1800703. doi: 10.1002/advs.201800703
25. [25]
  Y. Wang, S. Liu, W. Yu, ACS Appl. Bio Mater. 3(2020) 6959-6966. doi: 10.1021/acsabm.0c00828
26. [26]
  S. Choi, Y. Choi, J. Kim, Adv. Funct. Mater. 29(2019) 1904342. doi: 10.1002/adfm.201904342
27. [27]
  Y. Nagakawa, M. Kato, S. Suye, S. Fujita, RSC Adv. 10(2020) 38045-38054. doi: 10.1039/D0RA07322A
28. [28]
  Q. Sun, S. Ma, P. Lin, et al., ACS Appl. Polym. Mater. 2(2020) 2142-2150. doi: 10.1021/acsapm.0c00096
29. [29]
  E. Otsuka, A. Suzuki, J. Appl. Polym. Sci. 114(2009) 10-16. doi: 10.1002/app.30546
30. [30]
  P. Li, Z. Wang, X. Lin, X. Wang, H. Guo, Sci. China Mater. (2021), doi:10.1007/s40843-021-1722-0. doi: 10.1007/s40843-021-1722-0
31. [31]
  L. Zhang, J. Zhao, J. Zhu, C. He, H. Wang, Soft Matter 8(2012) 10439-10447. doi: 10.1039/c2sm26102b
32. [32]
  S.P. Obukhov, M. Rubinstein, R.H. Colby, Macromolecules 27(1994) 3191-3198. doi: 10.1021/ma00090a012
33. [33]
  E. Otsuka, S. Komiya, S. Sasaki, et al., Soft Matter 8(2012) 8129-8136. doi: 10.1039/c2sm25513h
34. [34]
  H. Guo, N. Sanson, D. Hourdet, A. Marcellan, Adv. Mater. 28(2016) 5857-5864. doi: 10.1002/adma.201600514
35. [35]
  H. Guo, C. Mussault, A. Brûlet, et al., Macromolecules 49(2016) 4295-4306. doi: 10.1021/acs.macromol.6b00798
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