Citation: Xiuying Li, Shuangqiu Huang, Huaihao Xu, Yuepeng Deng, Zhu Wang, Zhao-Qing Liu. Molybdenum phosphide (MoP) with dual active sites for the degradation of diclofenac in Fenton-like system[J]. Chinese Chemical Letters, ;2022, 33(3): 1321-1324. doi: 10.1016/j.cclet.2021.07.058 shu

Molybdenum phosphide (MoP) with dual active sites for the degradation of diclofenac in Fenton-like system

Xiuying Li ^a ,
Shuangqiu Huang ^a ,
Huaihao Xu ^a ,
Yuepeng Deng ^a ,
Zhu Wang ^{a, c, *,} ,
Zhao-Qing Liu ^b

a.
Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Guangzhou Key Laboratory for Clean Energy and Materials, Institute of Environmental Research at Greater Bay, Guangzhou University, Guangzhou 510006, China
b.
School of Chemistry and Chemical Engineering, Institute of Clean Energy and Materials, Guangzhou Key Laboratory for Clean Energy and Materials, Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Guangzhou University, Guangzhou 510006, China
c.
State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210023, China

wangzhu@gzhu.edu.cn

Received Date: 28 April 2021
Revised Date: 23 July 2021
Accepted Date: 26 July 2021
Available Online: 31 July 2021

Figures(4)

The leaching and non-recoverability of mental ions have always limited the practical application of Fenton-like processes. For the first time, we synthesized molybdenum phosphide (MoP) with dual active sites for the degradation of diclofenac (DCF) in the Fenton-like process. The DCF degradation rate constant (k) of MoP + H₂O₂ process was calculated to be 0.13 min^-1 within 40 min, indicating a highly efficient catalytic ability of MoP. In addition, this catalyst exhibits a stable structure and good activity, which could apply in a broad pH range, different ions solution and real wastewater condition. Accordingly, this efficient catalytic capability may be attributed to the presence of the metal sites Mo^δ+ and the electron-rich sites P^δ− in MoP, which could induce the generation of hydroxyl radical (^·OH) and superoxide radical (^·O₂⁻) through electron transfer, resulting in the effective removal of DCF. This study provides an idea for the optimization of Fenton-like technologies and environmental remediation.
- MoP,
- Dual active sites,
- Fenton-like,
- Diclofenac degradation
1. [1]
  D. Tiwari, Chem. Eng. J. 263(2015) 364-373. doi: 10.1016/j.cej.2014.10.102
2. [2]
  L. Lonappan, S.K. Brar, R.K. Das, M. Verma, R.Y. Surampalli, Environ. Int. 96(2016) 127-138. doi: 10.1016/j.envint.2016.09.014
3. [3]
  S. González, R. López-Roldán, J.L. Cortina, Environ. Pollut. 161(2012) 83-92. doi: 10.1016/j.envpol.2011.10.002
4. [4]
  R. Triebskorn, H. Casper, V. Scheil, J. Schwaiger, Anal. Bioanal. Chem. 387(2007) 1405-1416. doi: 10.1007/s00216-006-1033-x
5. [5]
  N. Wang, T. Zheng, G. Zhang, P. Wang, J. Environ. Chem. Eng. 4(2016) 762-787. doi: 10.1016/j.jece.2015.12.016
6. [6]
  M. Pereira, L. Oliveira, E. Murad, C. Miner 47(2012) 285-302. doi: 10.1180/claymin.2012.047.3.01
7. [7]
  A.D. Bokare, W. Choi, J. Hazard. Mater. 275(2014) 121-135. doi: 10.1016/j.jhazmat.2014.04.054
8. [8]
  M. Zhang, J. He, Y. Chen, et al., Chin. Chem. Lett. 31(2020) 2721-2724. doi: 10.1016/j.cclet.2020.05.001
9. [9]
  M. Ma, L. Chen, J. Zhao, W. Liu, H. Ji, Chin. Chem. Lett. 30(2019) 2191-2195. doi: 10.1016/j.cclet.2019.09.031
10. [10]
  J. Qi, J. Liu, F. Sun, et al., Chin. Chem. Lett. 32(2021) 1814-1818. doi: 10.1016/j.cclet.2020.11.026
11. [11]
  Y. Zhu, R. Zhu, Y. Xi, et al., Appl. Catal. B: Environ. 255(2019) 117739. doi: 10.1016/j.apcatb.2019.05.041
12. [12]
  M. Sun, H. Liu, J. Qu, J. Li, Adv. Energy. Mater. 6(2016) 1600087. doi: 10.1002/aenm.201600087
13. [13]
  W. Tong, Y. Xie, H. Luo, et al., Chem. Eng. J. 378(2019) 122187. doi: 10.1016/j.cej.2019.122187
14. [14]
  J. Hu, C. Zhai, M. Zhu, Chin. Chem. Lett. 32(2021) 1348-1358. doi: 10.1016/j.cclet.2020.09.049
15. [15]
  W. Cai, Z. Zhou, X. Tan, et al., Chem. Eng. J. 397(2020) 125279. doi: 10.1016/j.cej.2020.125279
16. [16]
  B. Hu, J.Y. Yuan, J.Y. Tian, et al., J. Coll. Interface Sci. 531(2018) 148-159. doi: 10.1016/j.jcis.2018.07.037
17. [17]
  F. Wu, Z. Chen, H. Wu, et al., ACS Sustain. Chem. Eng. 7(2019) 12741-12749. doi: 10.1021/acssuschemeng.9b00998
18. [18]
  R. Luo, C. Liu, J. Li, et al., J. Hazard. Mater. 329(2017) 92-101. doi: 10.1016/j.jhazmat.2017.01.032
19. [19]
  X. Wan, D. Qian, L. Ai, J. Jiang, Ind. Eng. Chem. Res. 59(2020) 22040-22048. doi: 10.1021/acs.iecr.0c04797
20. [20]
  P. Xiao, M.A. Sk, L. Thia, et al., Energy Environ. Sci. 7(2014) 2624-2629. doi: 10.1039/C4EE00957F
21. [21]
  Z. Huang, H. Hou, C. Wang, et al., Chem. Mater. 29(2017) 7313-7322. doi: 10.1021/acs.chemmater.7b02193
22. [22]
  L. Yang, H. Chen, F. Jia, et al., ACS Appl. Mater. Interfaces 13(2021) 14342-14354. doi: 10.1021/acsami.1c03601
23. [23]
  P. Chen, Y. Liang, B. Yang, F. Jia, S. Song, A.C.S. Sustain, ACS Sustain. Chem. Eng. 8(2020) 3673-3680. doi: 10.1021/acssuschemeng.9b06639
24. [24]
  L. Zhu, J. Ji, J. Liu, et al., Angew. Chem. Int. Ed. 59(2020) 13968-13976. doi: 10.1002/anie.202006059
25. [25]
  Y. Chen, S. Lan, M. Zhu, Chin. Chem. Lett. 32(2021) 2052-2056. doi: 10.1016/j.cclet.2020.11.016
26. [26]
  H. Zhang, J. He, C. Zhai, M. Zhu, Chin. Chem. Lett. 30(2019) 2338-2342. doi: 10.1016/j.cclet.2019.07.021
27. [27]
  R. Ge, J. Huo, T. Liao, et al., Appl. Catal. B: Environ. 260(2020) 118196. doi: 10.1016/j.apcatb.2019.118196
28. [28]
  J. Yang, F. Zhang, X. Wang, et al., Angew. Chem. Int. Ed. 55(2016) 12854-12858. doi: 10.1002/anie.201604315
29. [29]
  L.W. Matzek, K.E. Carter, Chem. Eng. J. 307(2017) 650-660. doi: 10.1016/j.cej.2016.08.126
30. [30]
  S. Zhu, X. Li, J. Kang, X. Duan, S. Wang, Environ. Sci. Technol. 53(2018) 307-315.
31. [31]
  H. Kim, J. Lim, S. Lee, et al., Environ. Sci. Technol. 53(2019) 2918-2925. doi: 10.1021/acs.est.8b06353
32. [32]
  T.P. Nguyen, Q.B. Tran, Q.V. Ly, et al., Arab. J. Chem. 13(2020) 8361-8371. doi: 10.1016/j.arabjc.2020.05.023
33. [33]
  D. Liu, J. Wang, J. Zhou, et al., Chem. Eng. J. 369(2019) 968-978. doi: 10.1016/j.cej.2019.03.140
34. [34]
  M. Tong, F. Liu, Q. Dong, Z. Ma, W. Liu, J. Hazard. Mater. 385(2020) 121604. doi: 10.1016/j.jhazmat.2019.121604
35. [35]
  Z. Chen, S. He, M. Zhu, C. Wei, Chemosphere 245(2020) 125678. doi: 10.1016/j.chemosphere.2019.125678
36. [36]
  W. Liu, Y. Li, F. Liu, et al., Water Res. 151(2019) 8–19. doi: 10.1016/j.watres.2018.11.084
1. [1]
  Ruiying Liu , Li Zhao , Baishan Liu , Jiayuan Yu , Yujie Wang , Wanqiang Yu , Di Xin , Chaoqiong Fang , Xuchuan Jiang , Riming Hu , Hong Liu , Weijia Zhou . Modulating pollutant adsorption and peroxymonosulfate activation sites on Co3O4@N,O doped-carbon shell for boosting catalytic degradation activity. Chinese Journal of Structural Chemistry, 2024, 43(8): 100332-100332. doi: 10.1016/j.cjsc.2023.100332
2. [2]
  Mengxiang Zhu , Tao Ding , Yunzhang Li , Yuanjie Peng , Ruiping Liu , Quan Zou , Leilei Yang , Shenglei Sun , Pin Zhou , Guosheng Shi , Dongting Yue . Graphene controlled solid-state growth of oxygen vacancies riched V₂O₅ catalyst to highly activate Fenton-like reaction. Chinese Chemical Letters, 2024, 35(12): 109833-. doi: 10.1016/j.cclet.2024.109833
3. [3]
  Tao Ban , Xi-Yang Yu , Hai-Kuo Tian , Zheng-Qing Huang , Chun-Ran Chang . One-step conversion of methane and formaldehyde to ethanol over SA-FLP dual-active-site catalysts: A DFT study. Chinese Chemical Letters, 2024, 35(4): 108549-. doi: 10.1016/j.cclet.2023.108549
4. [4]
  Chi Zhang , Ning Ding , Yuwei Pan , Lichun Fu , Ying Zhang . The degradation pathways of contaminants by reactive oxygen species generated in the Fenton/Fenton-like systems. Chinese Chemical Letters, 2024, 35(10): 109579-. doi: 10.1016/j.cclet.2024.109579
5. [5]
  Yiqian Jiang , Zihan Yang , Xiuru Bi , Nan Yao , Peiqing Zhao , Xu Meng . Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation. Chinese Chemical Letters, 2024, 35(8): 109331-. doi: 10.1016/j.cclet.2023.109331
6. [6]
  Shiyu Pan , Bo Cao , Deling Yuan , Tifeng Jiao , Qingrui Zhang , Shoufeng Tang . Complexes of cupric ion and tartaric acid enhanced calcium peroxide Fenton-like reaction for metronidazole degradation. Chinese Chemical Letters, 2024, 35(7): 109185-. doi: 10.1016/j.cclet.2023.109185
7. [7]
  Ming-Zhen Li , Yang Zhang , Kun Li , Ya-Nan Shang , Yi-Zhen Zhang , Yu-Jiao Kan , Zhi-Yang Jiao , Yu-Yuan Han , Xiao-Qiang Cao . In situ regeneration of catalyst for Fenton-like degradation by photogenerated electron transportation: Characterization, performance and mechanism comparison. Chinese Chemical Letters, 2025, 36(1): 109885-. doi: 10.1016/j.cclet.2024.109885
8. [8]
  Weichen Zhu , Wei Zuo , Pu Wang , Wei Zhan , Jun Zhang , Lipin Li , Yu Tian , Hong Qi , Rui Huang . Fe-N-C heterogeneous Fenton-like catalyst for the degradation of tetracycline: Fe-N coordination and mechanism studies. Chinese Chemical Letters, 2024, 35(9): 109341-. doi: 10.1016/j.cclet.2023.109341
9. [9]
  Xun Zhu , Chenchen Zhang , Yingying Li , Yin Lu , Na Huang , Dawei Wang . Degradation of perfluorooctanoic acid by inductively heated Fenton-like process over the Fe₃O₄/MIL-101 composite. Chinese Chemical Letters, 2024, 35(12): 109753-. doi: 10.1016/j.cclet.2024.109753
10. [10]
  Kexin Yin , Jingren Yang , Yanwei Li , Qian Li , Xing Xu . Metal-free diatomaceous carbon-based catalyst for ultrafast and anti-interference Fenton-like oxidation. Chinese Chemical Letters, 2024, 35(12): 109847-. doi: 10.1016/j.cclet.2024.109847
11. [11]
  Yanhua Peng , Xin Yu , Ting Wang . Adaptive nanoconfined Fenton-like reactions: Tailoring carbon pathways for sustainable water treatment and energy harvesting. Chinese Chemical Letters, 2024, 35(12): 110198-. doi: 10.1016/j.cclet.2024.110198
12. [12]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
13. [13]
  Bin Dong , Ning Yu , Qiu-Yue Wang , Jing-Ke Ren , Xin-Yu Zhang , Zhi-Jie Zhang , Ruo-Yao Fan , Da-Peng Liu , Yong-Ming Chai . Double active sites promoting hydrogen evolution activity and stability of CoRuOH/Co₂P by rapid hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109221-. doi: 10.1016/j.cclet.2023.109221
14. [14]
  Jiaqi Lin , Pupu Yang , Yimin Jiang , Shiqian Du , Dongcai Zhang , Gen Huang , Jinbo Wang , Jun Wang , Qie Liu , Miaoyu Li , Yujie Wu , Peng Long , Yangyang Zhou , Li Tao , Shuangyin Wang . Surface decoration prompting the decontamination of active sites in high-temperature proton exchange membrane fuel cells. Chinese Chemical Letters, 2024, 35(11): 109435-. doi: 10.1016/j.cclet.2023.109435
15. [15]
  Weiping Xiao , Yuhang Chen , Qin Zhao , Danil Bukhvalov , Caiqin Wang , Xiaofei Yang . Constructing the synergistic active sites of nickel bicarbonate supported Pt hierarchical nanostructure for efficient hydrogen evolution reaction. Chinese Chemical Letters, 2024, 35(12): 110176-. doi: 10.1016/j.cclet.2024.110176
16. [16]
  Yun-Xin Huang , Lin-Qian Yu , Ke-Yu Chen , Hao Wang , Shou-Yan Zhao , Bao-Cheng Huang , Ren-Cun Jin . Biochar with self-doped N to activate peroxymonosulfate for bisphenol-A degradation via electron transfer mechanism: The active edge graphitic N site. Chinese Chemical Letters, 2024, 35(9): 109437-. doi: 10.1016/j.cclet.2023.109437
17. [17]
  Ruru Li , Qian Liu , Hui Li , Fengbin Sun , Zhurui Shen . Rational design of dual sites induced local electron rearrangement for enhanced photocatalytic oxygen activation. Chinese Chemical Letters, 2024, 35(11): 109679-. doi: 10.1016/j.cclet.2024.109679
18. [18]
  Zhenchun Yang , Bixiao Guo , Zhenyu Hu , Kun Wang , Jiahao Cui , Lina Li , Chun Hu , Yubao Zhao . Molecular engineering towards dual surface local polarization sites on poly(heptazine imide) framework for boosting H₂O₂ photo-production. Chinese Chemical Letters, 2024, 35(8): 109251-. doi: 10.1016/j.cclet.2023.109251
19. [19]
  Gengchen Guo , Tianyu Zhao , Ruichang Sun , Mingzhe Song , Hongyu Liu , Sen Wang , Jingwen Li , Jingbin Zeng . Au-Fe₃O₄ dumbbell-like nanoparticles based lateral flow immunoassay for colorimetric and photothermal dual-mode detection of SARS-CoV-2 spike protein. Chinese Chemical Letters, 2024, 35(6): 109198-. doi: 10.1016/j.cclet.2023.109198
20. [20]
  Xiaotao Jin , Yanlan Wang , Yingping Huang , Di Huang , Xiang Liu . Percarbonate activation catalyzed by nanoblocks of basic copper molybdate for antibiotics degradation: High performance, degradation pathways and mechanism. Chinese Chemical Letters, 2024, 35(10): 109499-. doi: 10.1016/j.cclet.2024.109499

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(610)
HTML views(90)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142