Citation: Yiwei Zhang, Peng Zhang, Tengfei Xu, Xingguo Wang, Huaning Jiang, Yongji Gong. H₂S-assisted growth of 2D MS₂ (M = Ti, Zr, Nb)[J]. Chinese Chemical Letters, ;2022, 33(3): 1390-1394. doi: 10.1016/j.cclet.2021.07.036 shu

H₂S-assisted growth of 2D MS₂ (M = Ti, Zr, Nb)

Yiwei Zhang ^a ,
Peng Zhang ^{a, *,} ,
Tengfei Xu ^b ,
Xingguo Wang ^a ,
Huaning Jiang ^a ,
Yongji Gong ^{a, *,}

a.
School of Materials Science and Engineering, Beihang University, Beijing 100191, China
b.
State Key Laboratory of Infrared Physics, Shanghai Institute of Technical Physics, Chinese Academy of Sciences, Shanghai 200083, China

x_l_zhang@buaa.edu.cn

yongjigong@buaa.edu.cn

Received Date: 12 June 2021
Revised Date: 7 July 2021
Accepted Date: 13 July 2021
Available Online: 8 September 2021

Figures(6)

2D transition metal dichalcogenides (TMDCs) have drawn an enormous amount of attention due to their fascinating properties and application potential in next-generation information process and storage. However, the lack of proper synthesis approach limits their application. Here, we report a controllable synthesis method to grow ultrathin MS₂ (M = Ti, Nb, Zr) nanosheets with H₂S-assisted chemical vapor deposition (CVD). We found that the presence of H₂S plays an important role to control the morphology of nanosheets including the lateral size and the nucleation density. With the assistance of H₂S, the growth of MS₂ shows much thinner thickness with largely decreased nucleation density, beneficial for the device application, which can be attributed to the kinetics dominated growth. Our method hence opens a new avenue for the CVD growth of 2D TMDCs and the corresponding heterojunction, and paves the way for exploring their intriguing properties and applications.
- Chemical vapor deposition,
- Growth mechanism,
- 2D transition-metal dichalcogenides,
- Titanium disulfide,
- FET properties
1. [1]
  X.F. Qian, J.W. Liu, L. Fu, J. Li, Science. 346 (2014) 1344-1347 doi: 10.1126/science.1256815
2. [2]
  H. Zeng, J. Dai, W. Yao, D. Xiao, X. Cui, Nat. Nano. 7 (2012) 490-493 doi: 10.1038/nnano.2012.95
3. [3]
  H. Que, H. Jiang, X. Wang, et al., Acta Phys. Chim. Sin. 37 (2021) 2010051
4. [4]
  B. Radisavljevic and A. Kis, Nat. Mater. 12 (2013) 815-820 doi: 10.1038/nmat3687
5. [5]
  H. Zhang, ACS Nano. 9 (2015) 9451-9469 doi: 10.1021/acsnano.5b05040
6. [6]
  C. Xie, C. Mak, X. Tao, F. Yan, Adv. Funct. Mater. 27 (2017) 1603886 doi: 10.1002/adfm.201603886
7. [7]
  Q.H. Wang, K. Kalantar-Zadeh, A. Kis, J.N. Coleman, M.S. Strano, Nat. Nano. 7 (2012) 699-712 doi: 10.1038/nnano.2012.193
8. [8]
  X. Wang, L. Meng, B. Li, Y. Gong, Mater. Today. 47 (2021) 108-130 doi: 10.3390/md19020108
9. [9]
  L. Zhang, G. Wang, Y. Zhang, et al., ACS Nano. 14 (2020) 10265-10275 doi: 10.1021/acsnano.0c03665
10. [10]
  L. Meng, Y. Ma, K. Si, et al., Tungsten. 1 (2019) 46-58 doi: 10.1007/s42864-019-00012-x
11. [11]
  Y. Chen, S. Lan, M. Zhu, Chin. Chem. Lett. 32 (2021) 2052-2056 doi: 10.1016/j.cclet.2020.11.016
12. [12]
  J. Tan, J. Hu, J. Ren, et al., Chin. Chem. Lett. 31 (2020) 2103-2108 doi: 10.1016/j.cclet.2020.03.060
13. [13]
  Y. Feng, L. Ding, D. Ji, L. Wang, W. Guo, Chin. Chem. Lett. 29 (2018) 892-894 doi: 10.1016/j.cclet.2018.01.053
14. [14]
  M.S. Whittingham, Science. 192 (1976) 1126-1127 doi: 10.1126/science.192.4244.1126
15. [15]
  J. Ĉaja, R.B. Kaner, A.G. MacDiarmid, J. Electrochem. Soc. 131 (2019) 2744-2750
16. [16]
  C. Xu, P.A. Brown, K.L. Shuford, RSC Adv. 5 (2015) 83876-83879 doi: 10.1039/C5RA16877E
17. [17]
  Y. Zhang, L. Yin, J. Chu, et al., Adv. Mater. (2018) 1803665 doi: 10.1002/adma.201803665
18. [18]
  P. Zhang, C. Bian, J. Ye, et al., Sci. China Mater. 63 (2020) 1548-1559 doi: 10.1007/s40843-020-1355-2
19. [19]
  Z. Zhu, Y. Zou, W. Hu, et al., Adv. Funct. Mater. 26 (2016) 1793-1802 doi: 10.1002/adfm.201504884
20. [20]
  H. Zhai, Z. Qin, D. Sun, et al., Phys. Chem. Chem. Phys. 20 (2018) 23656-23663 doi: 10.1039/c8cp04271c
21. [21]
  Y. Zhu, X. Wang, M. Zhang, C. Cai, L. Xie, Nano Res. 9 (2016) 2931-2937 doi: 10.1007/s12274-016-1178-7
22. [22]
  X. Wang, L. Huang, X. -W. Jiang, et al., J. Mater. Chem. C. 4 (2016) 3143-3148 doi: 10.1039/C6TC00254D
23. [23]
  M. Mattinen, G. Popov, M. Vehkamäki, et al., Chem. Mater. 31 (2019) 5713-5724 doi: 10.1021/acs.chemmater.9b01688
24. [24]
  Y. Wang and Z. Geng, RSC Adv. 6 (2016) 58325-58328 doi: 10.1039/C6RA05366A
25. [25]
  G.H. Lee, Y.J. Yu, X. Cui, et al., ACS Nano. 7 (2013) 7931-7936 doi: 10.1021/nn402954e
26. [26]
  X. Sun, B. Shi, H. Wang, et al., Adv. Opt. Mater. 8 (2019) 1901181
27. [27]
  Y. Liu, X. Li, E. Wang, et al., Appl. Surf. Sci. 541 (2021) 148371 doi: 10.1016/j.apsusc.2020.148371
28. [28]
  X. Cai, Y. Luo, B. Liu, H.M. Cheng, Chem. Soc. Rev. 47 (2018) 6224-6266 doi: 10.1039/c8cs00254a
29. [29]
  P.C. Sherrell, K. Sharda, C. Grotta, et al., ACS Omega. 3 (2018) 8655-8662 doi: 10.1021/acsomega.8b00766
30. [30]
  A. Chaturvedi, P. Hu, V. Aravindan, C. Kloc, S. Madhavi, J. Mater. Chem. A. 5 (2017) 9177-9181 doi: 10.1039/C7TA01594A
31. [31]
  Y. Li, A. Singh, K. Reidy, et al., Adv. Funct. Mater. 30 (2020) 2003617 doi: 10.1002/adfm.202003617
32. [32]
  Z. Li, W. Yang, Y. Losovyj, et al., Nano Res. 11 (2018) 5978-5988 doi: 10.1007/s12274-018-2111-z
33. [33]
  H. Bark, Y. Choi, J. Jung, et al., Nanoscale. 10 (2018) 1056-1062 doi: 10.1039/C7NR07593F
34. [34]
  J. Zhou, J. Lin, X. Huang, et al., Nature. 556 (2018) 355-359 doi: 10.1038/s41586-018-0008-3
35. [35]
  B. Zhao, W. Dang, Y. Liu, et al., J. Am. Chem. Soc. 140 (2018) 14217-14223 doi: 10.1021/jacs.8b08124
36. [36]
  L. Meng, Z. Zhou, M. Xu, et al., Nat. Commun. 12 (2021) 809 doi: 10.1038/s41467-021-21072-z
37. [37]
  X. Wang, Z. Zhou, P. Zhang, et al., Chem. Mater. 32 (2020) 2321-2329 doi: 10.1021/acs.chemmater.9b04416
38. [38]
  S.J. Varma, J. Kumar, Y. Liu, et al., Adv. Opt. Mater. 5 (2017) 1700713 doi: 10.1002/adom.201700713
39. [39]
  Z. Gao, Q. Ji, P.C. Shen, et al., ACS Appl. Mater. Interfaces. 10 (2018) 34401-34408 doi: 10.1021/acsami.8b13428
40. [40]
  G.H. Han, D.L. Duong, D.H. Keum, S.J. Yun, Y.H. Lee, Chem. Rev. 118 (2018) 6297-6336 doi: 10.1021/acs.chemrev.7b00618
1. [1]
  Yan Wang , Jiaqi Zhang , Xiaofeng Wu , Sibo Wang , Masakazu Anpo , Yuanxing Fang . Elucidating oxygen evolution and reduction mechanisms in nitrogen-doped carbon-based photocatalysts. Chinese Chemical Letters, 2025, 36(2): 110439-. doi: 10.1016/j.cclet.2024.110439
2. [2]
  Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 100016-. doi: 10.3866/PKU.WHXB202310029
3. [3]
  Wenzhong Zhang , Zirui Yan , Lingcheng Chen , Yi Xiao . Sn-fused perylene diimides: Synthesis, mechanism, and properties. Chinese Chemical Letters, 2024, 35(10): 109582-. doi: 10.1016/j.cclet.2024.109582
4. [4]
  Ping Wang , Ting Wang , Ming Xu , Ze Gao , Hongyu Li , Bowen Li , Yuqi Wang , Chaoqun Qu , Ming Feng . Keplerate polyoxomolybdate nanoball mediated controllable preparation of metal-doped molybdenum disulfide for electrocatalytic hydrogen evolution in acidic and alkaline media. Chinese Chemical Letters, 2024, 35(7): 108930-. doi: 10.1016/j.cclet.2023.108930
5. [5]
  Chuyu Huang , Zhishan Liu , Linping Zhao , Zuxiao Chen , Rongrong Zheng , Xiaona Rao , Yuxuan Wei , Xin Chen , Shiying Li . Metal-coordinated oxidative stress amplifier to suppress tumor growth combined with M2 macrophage elimination. Chinese Chemical Letters, 2024, 35(12): 109696-. doi: 10.1016/j.cclet.2024.109696
6. [6]
  Boqiang Wang , Yongzhuo Xu , Jiajia Wang , Muyang Yang , Guo-Jun Deng , Wen Shao . Transition-metal free trifluoromethylimination of alkenes enabled by direct activation of N-unprotected ketimines. Chinese Chemical Letters, 2024, 35(9): 109502-. doi: 10.1016/j.cclet.2024.109502
7. [7]
  Yang Liu , Yan Liu , Kaiyin Yang , Zhiruo Zhang , Wenbo Zhang , Bingyou Yang , Hua Li , Lixia Chen . A selective HK2 degrader suppresses SW480 cancer cell growth by degrading HK2. Chinese Chemical Letters, 2024, 35(8): 109264-. doi: 10.1016/j.cclet.2023.109264
8. [8]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
9. [9]
  Liyong Ding , Zhenhua Pan , Qian Wang . 2D photocatalysts for hydrogen peroxide synthesis. Chinese Chemical Letters, 2024, 35(12): 110125-. doi: 10.1016/j.cclet.2024.110125
10. [10]
  Ping Wang , Tianbao Zhang , Zhenxing Li . Reconstruction mechanism of Cu surface in CO2 reduction process. Chinese Journal of Structural Chemistry, 2024, 43(8): 100328-100328. doi: 10.1016/j.cjsc.2024.100328
11. [11]
  Dong-Ling Kuang , Song Chen , Shaoru Chen , Yong-Jie Liao , Ning Li , Lai-Hon Chung , Jun He . 2D Zirconium-based metal-organic framework/bismuth(III) oxide nanorods composite for electrocatalytic CO2-to-formate reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100301-100301. doi: 10.1016/j.cjsc.2024.100301
12. [12]
  Weichen WANG , Chunhua GONG , Junyong ZHANG , Yanfeng BI , Hao XU , Jingli XIE . Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed-ligands and their catalytic properties for CO₂ cycloaddition reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1377-1386. doi: 10.11862/CJIC.20230415
13. [13]
  Ruonan Yang , Jiajia Li , Dongmei Zhang , Xiuqi Zhang , Xia Li , Han Yu , Zhanhu Guo , Chuanxin Hou , Gang Lian , Feng Dang . Grain-refining Co_0.85Se@CNT cathode catalyst with promoted Li₂O₂ growth kinetics for lithium-oxygen batteries. Chinese Chemical Letters, 2024, 35(12): 109595-. doi: 10.1016/j.cclet.2024.109595
14. [14]
  Mengxiang Zhu , Tao Ding , Yunzhang Li , Yuanjie Peng , Ruiping Liu , Quan Zou , Leilei Yang , Shenglei Sun , Pin Zhou , Guosheng Shi , Dongting Yue . Graphene controlled solid-state growth of oxygen vacancies riched V₂O₅ catalyst to highly activate Fenton-like reaction. Chinese Chemical Letters, 2024, 35(12): 109833-. doi: 10.1016/j.cclet.2024.109833
15. [15]
  Yubang Li , Xixi Hu , Daiqian Xie . The microscopic formation mechanism of O + H2 products from photodissociation of H2O. Chinese Journal of Structural Chemistry, 2024, 43(5): 100274-100274. doi: 10.1016/j.cjsc.2024.100274
16. [16]
  Xin Li , Wanting Fu , Ruiqing Guan , Yue Yuan , Qinmei Zhong , Gang Yao , Sheng-Tao Yang , Liandong Jing , Song Bai . Nucleophiles promotes the decomposition of electrophilic functional groups of tetracycline in ZVI/H₂O₂ system: Efficiency and mechanism. Chinese Chemical Letters, 2024, 35(10): 109625-. doi: 10.1016/j.cclet.2024.109625
17. [17]
  Yuan Teng , Zichun Zhou , Jinghua Chen , Siying Huang , Hongyan Chen , Daibin Kuang . Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs₃Bi₂Br₉/BiOBr epitaxial heterojunction for efficient photocatalysis. Chinese Chemical Letters, 2025, 36(2): 110430-. doi: 10.1016/j.cclet.2024.110430
18. [18]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
19. [19]
  Feng Cui , Fangman Chen , Xiaochun Xie , Chenyang Guo , Kai Xiao , Ziping Wu , Yinglu Chen , Junna Lu , Feixia Ruan , Chuanxu Cheng , Chao Yang , Dan Shao . Scalable production of mesoporous titanium nanoparticles through sequential flash nanocomplexation. Chinese Chemical Letters, 2024, 35(4): 108681-. doi: 10.1016/j.cclet.2023.108681
20. [20]
  Haijing Cui , Weihao Zhu , Chuning Yue , Ming Yang , Wenzhi Ren , Aiguo Wu . Recent progress of ultrasound-responsive titanium dioxide sonosensitizers in cancer treatment. Chinese Chemical Letters, 2024, 35(10): 109727-. doi: 10.1016/j.cclet.2024.109727

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(548)
HTML views(67)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

H2S-assisted growth of 2D MS2 (M = Ti, Zr, Nb)

Metrics

通讯作者: 陈斌, bchen63@163.com

H₂S-assisted growth of 2D MS₂ (M = Ti, Zr, Nb)