Citation: Chuang Bai, Fandi Ning, Saifei Pan, Huihui Wang, Yali Li, Min Shen, Xiaochun Zhou. Plasma treated carbon paper electrode greatly improves the performance of iron-hydrogen battery for low-cost energy storage[J]. Chinese Chemical Letters, ;2022, 33(2): 1095-1099. doi: 10.1016/j.cclet.2021.07.008 shu

Plasma treated carbon paper electrode greatly improves the performance of iron-hydrogen battery for low-cost energy storage

Chuang Bai ^{a, b} ,
Fandi Ning ^{a, b} ,
Saifei Pan ^{a, b} ,
Huihui Wang ^b ,
Yali Li ^{a, b} ,
Min Shen ^b ,
Xiaochun Zhou ^{a, b, *,}

a.
School of Nano-Tech and Nano-Bionics, University of Science and Technology of China, Hefei 230026, China
b.
Division of Advanced Nanomaterials, Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences (CAS), Suzhou 215123, China

xczhou2013@sinano.ac.cn

Received Date: 23 April 2021
Revised Date: 26 May 2021
Accepted Date: 2 July 2021
Available Online: 11 July 2021

Figures(4)

A novel iron-hydrogen battery system, whose Fe³⁺/Fe²⁺ cathode circumvents slowly dynamic oxygen reduction reaction and anode is fed with clean and cordial hydrogen, is systematically investigated. The maximum discharge power density of the iron-hydrogen battery reaches to 96.0 mW/cm² under the room temperature. The capacity reaches to 17.2 Ah/L and the coulombic and energy efficiency are achieved to 99% and 86%, respectively, during the galvanostatic charge-discharge test. Moreover, stable cycling test is observed for more than 240 h and 100 cycles with the iron sulfate in the sulfuric acid solutions. It is found that air plasma treatment onto the cathode carbon paper can generate the oxygen-containing groups and increase the hydrophilic pores proportion to ca. 40%, enlarging nearly 6-fold effective diffusion coefficient and improving the mass transfer in the battery performance. The simple iron-hydrogen energy storage battery design offers us a new strategy for the large-scale energy storage and hydrogen involved economy.
- Plasma modification,
- Carbon paper,
- Iron ion,
- Hydrogen,
- Hybrid battery
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