Citation: Yuquan Qi, Xiaoyu Gu, Xianqiang Huang, Guodong Shen, Bingchuan Yang, Qingpeng He, Zechun Xue, Mengcheng Du, Lilong Shi, Bing Yu. Microwave-assisted controllable synthesis of 2-acylbenzothiazoles and bibenzo[b][1, 4]thiazines from aryl methyl ketones and disulfanediyldianilines[J]. Chinese Chemical Letters, ;2021, 32(11): 3544-3547. doi: 10.1016/j.cclet.2021.05.069 shu

Microwave-assisted controllable synthesis of 2-acylbenzothiazoles and bibenzo[b][1, 4]thiazines from aryl methyl ketones and disulfanediyldianilines

Yuquan Qi ^a ,
Xiaoyu Gu ^a ,
Xianqiang Huang ^{a, *,} ,
Guodong Shen ^{a, *,} ,
Bingchuan Yang ^a ,
Qingpeng He ^a ,
Zechun Xue ^a ,
Mengcheng Du ^c ,
Lilong Shi ^c ,
Bing Yu ^{b, *,}

a.
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry & Chemical Engineering, Liaocheng University, Liaocheng 252059, China
b.
Green Catalysis Center, College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
c.
National Rubber Additive Engineering Technology Center, Liaocheng 252059, China

hxqqxh2008@163.com

shenguodong33@163.com

bingyu@zzu.edu.cn

Received Date: 22 April 2021
Revised Date: 27 May 2021
Accepted Date: 31 May 2021
Available Online: 3 June 2021

Figures(5)

A condition-controlled strategy for selectively synthesis of 2-acylbenzothiazoles and bibenzo[b][1, 4]thiazines from aryl methyl ketones and disulfanediyldianilines was realized using I₂/DMSO or I₂/MeCN systems, respectively. The desired products were synthesized in only 15 min with moderate to excellent yields (50%-90%) under microwave-assisted, metal-free conditions. The strategy provides a great advantage for selective synthetic applications in the efficient synthesis of benzothiazoles and bibenzothiazines heterocycle compounds.
- Selective synthesis,
- Metal-free,
- Microwave-assisted,
- Condition-controlled,
- Heterocycle compounds
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