Citation: Ping Wang, Bin Guo, Zhi Zhang, Weinan Gao, Wei Zhou, Huaxin Ma, Wenyu Wu, Junfeng Han, Ruijun Zhang. Eco-friendly non-acid intercalation and exfoliation of graphite to graphene nanosheets in the binary-peroxidant system for EMI shielding[J]. Chinese Chemical Letters, ;2021, 32(11): 3469-3473. doi: 10.1016/j.cclet.2021.05.064 shu

Eco-friendly non-acid intercalation and exfoliation of graphite to graphene nanosheets in the binary-peroxidant system for EMI shielding

Ping Wang ^{a, b} ,
Bin Guo ^a ,
Zhi Zhang ^a ,
Weinan Gao ^a ,
Wei Zhou ^a ,
Huaxin Ma ^a ,
Wenyu Wu ^a ,
Junfeng Han ^{b, *,} ,
Ruijun Zhang ^{a, *,}

a.
State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, China
b.
Key Laboratory of Advanced Optoelectronic Quantum Architecture and Measurement, Ministry of Education, School of Physics, Beijing Institute of Technology, Beijing 100081, China

pkuhjf@bit.edu.cn

zhangrj@ysu.edu.cn

Received Date: 13 January 2021
Revised Date: 20 March 2021
Accepted Date: 28 May 2021
Available Online: 1 June 2021

Figures(5)

The development of the preparation strategy for high-quality and large-size graphene via eco-friendly routes is still a challenging issue. Herein, we have successfully developed a novel route to chemically exfoliate natural graphite into high-quality and large-size graphene in a binary-peroxidant system. This system is composed of urea peroxide (CO(NH₂)₂·H₂O₂) and hydrogen peroxide (H₂O₂), where CO(NH₂)₂·H₂O₂ is used in preparing graphene for the first time. Benefiting from the complete decomposition of CO(NH₂)₂·H₂O₂ and H₂O₂ into gaseous species under microwave (MW) irradiation, no water-washing and effluent-treatment are needed in this chemical exfoliation procedure, thus the preparation of graphene in an eco-friendly way is realized. The resultant graphene behaves a large-size, high-quality and few-layer feature with a yield of ~100%. Then 4 µm-thick ultrathin graphene paper fabricated from the as-exfoliated graphene is used as an electromagnetic interference (EMI) shielding material. And its absolute effectiveness of EMI shielding (SSE/t) is up to 34, 176.9 dB cm²/g, which is, to the best of our knowledge, among the highest values so far reported for typical EMI shielding materials. The EMI shielding performance demonstrates a great application potential of graphene paper in meeting the ever-increasingly EMI shielding demands in miniaturized electronic devices.
- Graphene exfoliation,
- Eco-friendly,
- Graphene paper,
- EMI shielding
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