Citation: Jia Chen, Ning Yuan, Danni Jiang, Qian Lei, Bei Liu, Weiyang Tang, Kyung Ho Row, Hongdeng Qiu. Octadecylamine and glucose-coderived hydrophobic carbon dots-modified porous silica for chromatographic separation[J]. Chinese Chemical Letters, ;2021, 32(11): 3398-3401. doi: 10.1016/j.cclet.2021.04.052 shu

Octadecylamine and glucose-coderived hydrophobic carbon dots-modified porous silica for chromatographic separation

Jia Chen ^a ,
Ning Yuan ^b ,
Danni Jiang ^b ,
Qian Lei ^c ,
Bei Liu ^a ,
Weiyang Tang ^d ,
Kyung Ho Row ^{d, *,} ,
Hongdeng Qiu ^{a, c, e, **,}

a.
CAS Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
b.
Laboratory on Pollution Monitoring and Control, College of Chemistry and Chemical Engineering, Xinjiang Normal University, Urumqi 830054, China
c.
School of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou 341000, China
d.
Department of Chemistry and Chemical Engineering, Education and Research Center for Smart Energy and Materials, Inha University, Incheon 402-701, Republic of Korea
e.
College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

^**

rowkho@inha.ac.kr

hdqiu@licp.cas.cn

Received Date: 19 January 2021
Revised Date: 11 March 2021
Accepted Date: 27 April 2021
Available Online: 3 May 2021

Figures(4)

A hydrophobic carbon dots (Glc-OCDs) derived from octadecylamine and glucose were successfully synthesized for the first time and then grafted onto the porous silica surface by the "Nano-on-Micro" strategy, which was served as a new stationary phase (Sil-Glc-OCDs) for reversed-phase liquid chromatography. The structure of this stationary phase was carefully verified by laser scanning confocal microscope, Fourier transform infrared spectrometry, elemental analysis, contact angle measurement, etc. Several analytes including seven polycyclic aromatic hydrocarbons, eight alkylbenzenes, eight phenols and seven sulfonamides can be well separated on this stationary phase. Better separation performance for certain analytes over commercial C₁₈ column was obtained. Interestingly, this stationary phase exhibited excellent chromatographic selectivity in the separation of the isomers of tert‑butylbenzene, sec‑butylbenzene, isobutylbenzene and n-butylbenzene. In addition, this new Sil-Glc-OCDs column was also applied for detection of calycosin-7-glucoside, ononin, calycosin, formononetin, genistein and isorhamnetin in the extract of Radix Astragali, which were found that the concentration was 0.15 g/L, 0.088 g/L, 0.14 g/L, 0.086 g/L, 0.18 g/L and 0.29 g/L, respectively. We believe that this CDs-grafted silica materials are promising for chromatographic separation.
- Carbon dots,
- Stationary phase,
- Chromatographic separation,
- Liquid chromatography,
- Deep eutectic solvents
1. [1]
  N. Hamada, Y. Hashi, S. Yamaki, et al., Chin. Chem. Lett. 30(2019) 99-102. doi: 10.1016/j.cclet.2018.10.029
2. [2]
  C. Qi, H. Jiang, J. Xiong, B. Yuan, Y. Feng, Chin. Chem. Lett. 30(2019) 553-557. doi: 10.1016/j.cclet.2018.11.029
3. [3]
  J. Chen, Z. Gong, W. Tang, K.H. Row, H. Qiu, TrAC Trends Anal. Chem. 134(2021) 116135. doi: 10.1016/j.trac.2020.116135
4. [4]
  A.H. Duan, S.M. Xie, L.M. Yuan, TrAC Trends Anal. Chem. 30(2011) 484-491. doi: 10.1016/j.trac.2011.01.007
5. [5]
  M. Zhang, H. Qiu, TrAC Trends Anal. Chem. 65(2015) 107-121. doi: 10.1016/j.trac.2014.10.008
6. [6]
  A. Speltini, D. Merli, A. Merli, Anal. Chim. Acta 783(2013) 1-16. doi: 10.1016/j.aca.2013.03.041
7. [7]
  Q. Wu, H. Lv, L. Zhao, TrAC Trends Anal. Chem. 129(2020) 115941. doi: 10.1016/j.trac.2020.115941
8. [8]
  L. Song, H. Zhang, T. Cai, J. Chen, H. Qiu, Chin. Chem. Lett. 30(2019) 863-866. doi: 10.1016/j.cclet.2018.10.040
9. [9]
  X. Zhang, S. Chen, Q. Han, M. Ding, J. Chromatogr. A 1307(2013) 135-143. doi: 10.1016/j.chroma.2013.07.106
10. [10]
  Z. Xue, J.C. Vinci, L.A. Colón, ACS Appl. Mater. Inter. 8(2016) 4149-4157. doi: 10.1021/acsami.5b11871
11. [11]
  T. Cai, H. Zhang, Z. Li, A.F.M.M. Rahman, H. Qiu, RSC Adv. 6(2016) 32757-32760. doi: 10.1039/C6RA04824B
12. [12]
  C.X. Yang, X.P. Yan, Anal. Chem. 83(2011) 7144-7150. doi: 10.1021/ac201517c
13. [13]
  X. Li, B. Li, M. Liu, et al., ACS Appl. Mater. Interfaces 11(2019) 10320-10327. doi: 10.1021/acsami.9b00285
14. [14]
  T. Si, J. Ma, X. Lu, et al., ACS Appl. Nano Mater. 3(2020) 351-356. doi: 10.1021/acsanm.9b01987
15. [15]
  J. Huang, X. Han, S. Yang, et al., J. Am. Chem. Soc. 141(2019) 8996-9003. doi: 10.1021/jacs.9b03075
16. [16]
  H.L. Qian, C.X. Yang, W.L. Wang, C. Yang, X.P. Yan, J. Chromatogr. A 1542(2018) 1-18. doi: 10.1016/j.chroma.2018.02.023
17. [17]
  L. Chen, Q. Wu, J. Gao, et al., TrAC Trends Anal. Chem. 113(2019) 182-193. doi: 10.1016/j.trac.2019.01.016
18. [18]
  J. Chen, Y. Huang, X. Wei, et al., Chem. Commun. 55(2019) 10908-10911. doi: 10.1039/C9CC05307G
19. [19]
  Q. Luo, X. Ren, S. Wei, et al., Anal. Bioanal. Chem. 412(2020) 1365-1374. doi: 10.1007/s00216-019-02363-3
20. [20]
  Y. Liu, H. Huang, W. Cao, et al., Mater. Chem. Front. 4(2020) 1586-1613. doi: 10.1039/D0QM00090F
21. [21]
  G. Han, J. Zhao, R. Zhang, et al., Angew. Chem. Int. Ed. 58(2019) 7087-7091. doi: 10.1002/anie.201903005
22. [22]
  Z. Kang, S. -. T. Lee, Nanoscale 11(2019) 19214-1924. doi: 10.1039/C9NR05647E
23. [23]
  C. Hu, M. Li, J. Qiu, Y.P. Sun, Chem. Soc. Rev. 48(2019) 2315-2337. doi: 10.1039/C8CS00750K
24. [24]
  M.L. Liu, B.B. Chen, C.M. Li, C.Z. Huang, Green Chem. 21(2019) 449-471. doi: 10.1039/C8GC02736F
25. [25]
  H. Zhang, X. Qiao, T. Cai, et al., Anal. Bioanal. Chem. 409(2017) 2401-2410. doi: 10.1007/s00216-017-0187-z
26. [26]
  T. Cai, H. Zhang, A.F.M.M. Rahman, Y.P. Shi, H. Qiu, Microchim. Acta 184(2017) 2629-2636. doi: 10.1007/s00604-017-2277-1
27. [27]
  Y. Yang, H. Zhang, J. Chen, et al., Analyst 145(2020) 1056-1061. doi: 10.1039/C9AN02246E
28. [28]
  L. Song, H. Zhang, J. Chen, et al., Talanta 209(2020) 120518. doi: 10.1016/j.talanta.2019.120518
29. [29]
  T. Cai, H. Zhang, J. Chen, Z. Li, H. Qiu, J. Chromatogr. A 1597(2019) 142-148. doi: 10.1016/j.chroma.2019.03.026
30. [30]
  N. Yuan, J. Chen, T. Cai, et al., J. Chromatogr. A 1619(2020) 460930. doi: 10.1016/j.chroma.2020.460930
31. [31]
  N. Yuan, J. Chen, H. Zhou, et al., Talanta 218(2020) 121140. doi: 10.1016/j.talanta.2020.121140
32. [32]
  H. Liu, Y. Guo, X. Wang, et al., RSC Adv. 4(2014) 17541-17548. doi: 10.1039/C4RA01408A
33. [33]
  B. Yang, H. Liu, J. Chen, M. Guan, H. Qiu, J. Chromatogr. A 1468(2016) 79-85. doi: 10.1016/j.chroma.2016.09.021
34. [34]
  M. Zhang, J. Chen, T. Gu, H. Qiu, S. Jiang, Talanta 126(2014) 177-184. doi: 10.1016/j.talanta.2014.03.057
35. [35]
  N. Tanaka, Y. Tokuda, K. lwaguchi, M. Araki, J. Chromatogr. A 239(1982) 761-772. doi: 10.1016/S0021-9673(00)82036-1
36. [36]
  W. Zhao, J. Chu, F. Xie, et al., J. Chromatogr. A 1485(2017) 44-51. doi: 10.1016/j.chroma.2016.12.019
37. [37]
  E. Lesellier, C. West, J. Chromatogr. A 1574(2018) 71-81. doi: 10.1016/j.chroma.2018.09.004
38. [38]
  G.E. Berendsen, L.D. Galan, J. Chromatogr. A 196(1980) 21-37. doi: 10.1016/S0021-9673(00)80356-8
39. [39]
  Q. Wu, L. Chen, J. Gao, et al., Talanta 194(2019) 105-113. doi: 10.1016/j.talanta.2018.10.005
40. [40]
  M. Czok, H. Engelhardt, Chromatographia 27(1989) 5-14. doi: 10.1007/BF02290396
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