Citation: Zepeng Lei, Francisco W.S. Lucas, Enrique Canales Moya, Shaofeng Huang, Yicheng Rong, Aaron Wesche, Patrick Li, Lauren Bodkin, Yinghua Jin, Adam Holewinski, Wei Zhang. Highly stable dioxin-linked metallophthalocyanine covalent organic frameworks[J]. Chinese Chemical Letters, ;2021, 32(12): 3799-3802. doi: 10.1016/j.cclet.2021.04.047 shu

Highly stable dioxin-linked metallophthalocyanine covalent organic frameworks

a.
Department of Chemistry, University of Colorado Boulder, Boulder, CO 80309, United States
b.
Renewable and Sustainable Energy Institute, and Department of Chemical and Biological Engineering, University of Colorado Boulder, Boulder, CO 80309, United States

adam.holewinski@colorado.edu

wei.zhang@colorado.edu

Received Date: 11 March 2021
Revised Date: 10 April 2021
Accepted Date: 21 April 2021
Available Online: 28 April 2021

Figures(4)

We report a series of highly stable metallophthalocyanine-based covalent organic frameworks (MPc-dx-COFs) linked by robust 1, 4-dioxin bonds constructed through nucleophilic aromatic substitution (S_NAr) reaction. The chemical structures and crystallinity of the COFs largely remain unchanged even after treating with boiling water (90 ℃), concentrated acids (12 mol/L HCl) or bases (12 mol/L NaOH), oxidizing (30% H₂O₂) or reducing agents (1 mol/L NaBH₄) for three days due to their stable M-Pc building blocks and resilient dioxin linkers. With metallated phthalocyanine active sites regularly arranged in the stable framework structures, MPc-dx-COFs can be directly used as efficient electrocatalysts for the oxygen reduction reaction (ORR) without pyrolysis treatment that has commonly been used in previous studies.
- Covalent organic framework,
- Metallophthalocyanine,
- Nucleophilic aromatic substitution,
- Dioxin linkage,
- Electrocatalysis,
- Oxygen reduction reaction
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沈阳化工大学材料科学与工程学院沈阳 110142