Citation: Peng Jing, Boyuan Wu, Zongsu Han, Wei Shi, Peng Cheng. An efficient Ag/MIL-100(Fe) catalyst for photothermal conversion of CO₂ at ambient temperature[J]. Chinese Chemical Letters, ;2021, 32(11): 3505-3508. doi: 10.1016/j.cclet.2021.04.007 shu

An efficient Ag/MIL-100(Fe) catalyst for photothermal conversion of CO₂ at ambient temperature

Peng Jing ^a ,
Boyuan Wu ^a ,
Zongsu Han ^a ,
Wei Shi ^{a, *,} ,
Peng Cheng ^{a, b}

a.
Key Laboratory of Advanced Energy Materials Chemistry (MOE), College of Chemistry, Nankai University, Tianjin 300071, China
b.
Renewable Energy Conversion and Storage Center, Nankai University, Tianjin 300071, China

shiwei@nankai.edu.cn

Received Date: 21 February 2021
Revised Date: 24 March 2021
Accepted Date: 25 March 2021
Available Online: 3 April 2021

Figures(6)

The conversion of CO₂ under mild condition is of great importance because these reactions involving CO₂ can not only produce value-added chemicals from abundant and inexpensive CO₂ feedstock but also close the carbon cycle. However, the chemical inertness of CO₂ requires the development of high-performance catalysts. Herein, Ag nanoparticles/MIL-100(Fe) composites were synthesized by simple impregnation-reduction method and employed as catalysts for the photothermal carboxylation of terminal alkynes with CO₂. MIL-100(Fe) could stabilize Ag nanoparticles and prevent them from aggregation during catalytic process. Taking the advantages of photothermal effects and catalytic activities of both Ag nanoparticles and MIL-100(Fe), various aromatic alkynes could be converted to corresponding carboxylic acid products (86%–92% yields) with 1 atm CO₂ at room temperature under visible light irradiation when using Ag nanoparticles/MIL-100(Fe) as photothermal catalysts. The catalysts also showed good recyclability with almost no loss of catalytic activity for three consecutive runs. More importantly, the catalytic performance of Ag nanoparticles/MIL-100(Fe) under visible light irradiation at room temperature was comparable to that upon heating, showing that the light source could replace conventional heating method to drive the reaction. This work provided a promising strategy of utilizing solar energy for achieving efficient CO₂ conversion to value-added chemicals under mild condition.
- Ag nanoparticles,
- Metal-organic frameworks,
- Photothermal catalysis,
- CO₂ conversion,
- Carboxylation
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

An efficient Ag/MIL-100(Fe) catalyst for photothermal conversion of CO2 at ambient temperature

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通讯作者: 陈斌, bchen63@163.com

An efficient Ag/MIL-100(Fe) catalyst for photothermal conversion of CO₂ at ambient temperature