Citation: Chengqian Cui, Guodong Li, Zhiyong Tang. Metal-organic framework nanosheets and their composites for heterogeneous thermal catalysis: Recent progresses and challenges[J]. Chinese Chemical Letters, ;2021, 32(11): 3307-3321. doi: 10.1016/j.cclet.2021.04.001 shu

Metal-organic framework nanosheets and their composites for heterogeneous thermal catalysis: Recent progresses and challenges

Chengqian Cui ^{a, b} ,
Guodong Li ^{a, b, *,} ,
Zhiyong Tang ^{a, b}

a.
CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China
b.
School of Nanoscience and Technology, University of Chinese Academy of Sciences, Beijing 100049, China

liguodong@nanoctr.cn

Received Date: 3 March 2021
Revised Date: 30 March 2021
Accepted Date: 31 March 2021
Available Online: 3 April 2021

Figures(15)

Metal-organic framework nanosheets (MONs) as the emerging materials have been attracting great interest because the nanosheets possess a range of fascinating attributes including high surface areas and sufficient accessible active sites, and their nanoscale thicknesses are favorable for mass diffusion and transfer of substrates and products with respect to bulk metal-organic frameworks (MOFs). This review first summarizes the synthetic methods of various MONs from top-down and bottom-up methods as well as their diverse composites with different components. Then, the catalytic applications of MON based nanocatalysts are discussed and the relationships among the composition, structure and catalytic performances are revealed. Finally, the challenges and future outlook about the synthesis of diverse MONs and their composites for heterogeneous catalysis are prospected.
- Metal-organic framework nanosheet,
- Top-down synthesis,
- Bottom-up synthesis,
- Composite structure,
- Heterogeneous catalysis
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沈阳化工大学材料科学与工程学院沈阳 110142