Citation: Liying Shen, Yong Li, Swagata Roy, Xiuping Yin, Wenbo Liu, Shanshan Shi, Xuan Wang, Xuemin Yin, Jiujun Zhang, Yufeng Zhao. A robust carbon coating of Na₃V₂(PO₄)₃ cathode material for high performance sodium-ion batteries[J]. Chinese Chemical Letters, ;2021, 32(11): 3570-3574. doi: 10.1016/j.cclet.2021.03.005 shu

A robust carbon coating of Na₃V₂(PO₄)₃ cathode material for high performance sodium-ion batteries

College of Sciences & Institute for Sustainable Energy, Shanghai University, Shanghai 200444, China

yufengzhao@shu.edu.cn

Received Date: 17 February 2021
Revised Date: 1 March 2021
Accepted Date: 2 March 2021
Available Online: 4 March 2021

Figures(5)

Na₃V₂(PO₄)₃ is a very prospective sodium-ion batteries (SIBs) electrode material owing to its NASICON structure and high reversible capacity. Conversely, on account of its intrinsic poor electronic conductivity, Na₃V₂(PO₄)₃ electrode materials confront with some significant limitations like poor cycle and rate performance which inhibit their practical applications in the energy fields. Herein, a simple two-step method has been implemented for the successful preparation of carbon-coated Na₃V₂(PO₄)₃ materials. As synthesized sample shows a remarkable electrochemical performance of 124.1 mAh/g at 0.1 C (1 C = 117.6 mA/g), retaining 78.5 mAh/g under a high rate of 200 C and a long cycle-performance (retaining 80.7 mAh/g even after 10000 cycles at 20 C), outperforming the most advanced cathode materials as reported in literatures.
- Sodium-ion batteries,
- NASICON,
- Na₃V₂(PO₄)₃,
- Cathode,
- Carbon-coated
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通讯作者: 陈斌, bchen63@163.com

A robust carbon coating of Na₃V₂(PO₄)₃ cathode material for high performance sodium-ion batteries