Citation: Peng-Fei Wang, Wei Yi, Yong Ling, Liang Ming, Gong-Qing Liu, Yu Zhao. Preparation of selenofunctionalized heterocycles via iodosobenzene-mediated intramolecular selenocyclizations of olefins with diselenides[J]. Chinese Chemical Letters, ;2021, 32(8): 2587-2591. doi: 10.1016/j.cclet.2021.02.050 shu

Preparation of selenofunctionalized heterocycles via iodosobenzene-mediated intramolecular selenocyclizations of olefins with diselenides

School of Pharmacy, Nantong University, Nantong 226001, China

gqliu@ntu.edu.cn

zhaoyu@ntu.edu.cn

Received Date: 6 January 2021
Revised Date: 20 February 2021
Accepted Date: 23 February 2021
Available Online: 25 February 2021

Figures(6)

An intramolecular selenocyclizations of olefins mediated by a commercially available hypervalent iodine(III) reagent, PhIO, was developed. This method provided access to a wide range of selenenylated heterocycles under ambient conditions. The striking advantages of this protocol over all previous methods include mild reaction conditions, easy operation, good yields, high levels of functional group compatibility, large–scale application and suitability for the late-stage functionalization of complex molecules of biological importance.
- Selenocyclizations,
- Olefins,
- Heterocycles,
- Iodosobenzene,
- Diselenides
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